2009 Fiscal Year Final Research Report
The creation of functional materials based on novel chiral polymers
| Project/Area Number |
20850023
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| Research Category |
Grant-in-Aid for Young Scientists (Start-up)
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| Allocation Type | Single-year Grants |
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| Research Field |
Polymer chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
FUKUHARA Gaku Osaka University, 工学研究科, 助教 (30505996)
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| Project Period (FY) |
2008 – 2009
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| Keywords | キラル高分子 / キラル光化学 / 超分子化学 / 不斉認識化学 / 多糖化学 |
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| Research Abstract |
In the ground state, a newly synthesized polythiophene possessing an optically active binaphthyl tethered by an oxyethylene linker is capable of recognizing various amino acid derivatives as chiral cationic guests. In sharp contrast to the ground-state polymer chemistry, photoirradiation of anthracenecarboxylate-appended cellulose gave the cyclodimers with high stereoselectivities, examined the detailed diastereodifferentiating mechanism.
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[Journal Article] Bio-Supramolecular Photochirogenesis with Molecular Chaperone: Enantiodifferentiating Photocyclodimerization of 2-Anthracenecarboxylate Mediated by Prefoldin
Author(s)
播戸一樹, 座古保, 迫野昌文, 前田瑞夫, 和田健彦, 西嶋政樹, 福原学, 楊成, 森直T.C.S. Pace, C. Bohne, 井上佳久
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Journal Title
Photochemical & Photobiological Sciences (in press)
Peer Reviewed
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