2022 Fiscal Year Final Research Report
Development of catalytic oxidation of alkanes using water as an oxygen source
| Project/Area Number |
20H02734
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Review Section |
Basic Section 33020:Synthetic organic chemistry-related
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| Research Institution | University of Hyogo (2021-2022)
Nagoya University (2020) |
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Principal Investigator |
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| Project Period (FY) |
2020-04-01 – 2023-03-31
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| Keywords | 酸化反応 / ジアザポルフィリン |
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| Outline of Final Research Achievements |
In this project, C-H bond oxidation of alkanes catalyzed by diazaporphyrin metal complexes was performed. It was found that the diazaporphyrin metal complexes exhibit higher reactivity than conventional porphyrin metal complexes, and the difference in reactivity was attributed to the electron acceptivity of the main skeleton. The reactivity was further exploited to catalyze the C-H bond fluorination of alkanes.
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| Free Research Field |
有機合成化学
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| Academic Significance and Societal Importance of the Research Achievements |
得られた成果はポルフィリンの主骨格にsp2-窒素原子を導入することで金属錯体の電子受容性を向上させるという手法が触媒の反応性を向上させる有効な戦略となり得るということを示した点で意義がある。
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