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2020 Fiscal Year Annual Research Report

SiGe Channel FETs for High-Performance CMOS with Advanced High-K/SiGe Gate Stack

Research Project

Project/Area Number 20J10380
Research InstitutionThe University of Tokyo

Principal Investigator

李 宗恩  東京大学, 工学系研究科, 特別研究員(DC2)

Project Period (FY) 2020-04-24 – 2022-03-31
KeywordsSiGe / MOS interface / high-k / interface trap states / EOT
Outline of Annual Research Achievements

1. We have demonstrated the record-low Dit and small hysteresis over a wide range of Ge contents from 13 to 63% by a combination of PMA at 450C and the optimum pre-cleaning process using TMA pre-treatment by TiN/ALD Y2O3/SiGe gate stacks
2. The record-low minimum D it with EOT down to 1nm is demonstrated among high-k/SiGe MOS interfaces with various Ge contents
3. 24% improvement in gm/Cox peak of Y2O3-based Si0.8Ge0.2 p-FinFET, compared to Si p-FinFET under the same EOT, is demonstrated
4. We have proposed a revised conductance method based on our new equivalent circuit for evaluating Dit at MFIS interfaces, and the ferroelectric responses in MFIS can effectively be subtracted by measuring that of a MFM capacitor

Current Status of Research Progress
Current Status of Research Progress

2: Research has progressed on the whole more than it was originally planned.

Reason

1. The physical origins of reduction in Dit has been verified by the impacts of PMA temperature, oxidized IL, metal electrode, ALD high-k, TMA treatment and Ge contents, which is attributable to following two mechanisms:
(1) Reduction of the amount of sub-GeOx at MOS interfaces by the scavenging effect during PMA and TMA treatment
(2) Healing the distorted Ge-O bonds incorporating Y by high temperature PMA
2. A possible origin of the slow traps in the Y2O3/SiGe MOS interfaces can be oxygen-vacancy-related defects in ILs with the energy positions close to Ec and Ev, formed by incorporation of Ge-O bonds in ILs
3. The stress-induced degradation at SiGe interfaces after applying constant oxide electrical field can be suppressed by scaling of thickness of Y2O3

Strategy for Future Research Activity

1. Study the time constant of electron trapping and detrapping in (Si,SiGe,Ge) MFIS interface by retention tests
2. Fabricate (Si,SiGe,Ge) p-FeFET and n-FeFET and hall devices
3. Understand the physical origins of the dependency of channel materials (Si,SiGe,Ge) on memory characteristics of FeFETs, including memory window, retention and endurance

  • Research Products

    (11 results)

All 2021 2020

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (9 results) (of which Int'l Joint Research: 3 results,  Invited: 2 results)

  • [Journal Article] Reduction of MOS Interface Defects in TiN/Y2O3/Si0.78Ge0.22 Structures by Trimethylaluminum Treatment2020

    • Author(s)
      Lee Tsung-En、Ke Mengnan、Toprasertpong Kasidit、Takenaka Mitsuru、Takagi Shinichi
    • Journal Title

      IEEE Transactions on Electron Devices

      Volume: 67 Pages: 4067~4072

    • DOI

      10.1109/TED.2020.3014563

    • Peer Reviewed
  • [Journal Article] Metal-oxide-semiconductor interface properties of TiN/Y2O3/Si0.62Ge0.38 gate stacks with high temperature post-metallization annealing2020

    • Author(s)
      Lee Tsung-En、Ke Mengnan、Kato Kimihiko、Takenaka Mitsuru、Takagi Shinichi
    • Journal Title

      Journal of Applied Physics

      Volume: 127 Pages: 185705~185705

    • DOI

      10.1063/1.5144198

    • Peer Reviewed
  • [Presentation] Characterization of slow traps properties in SiGe MOS interfaces by TiN/Y2O3 gate stacks2021

    • Author(s)
      T.-E. Lee, M. Ke, K. Toprasertpong, M. Takenaka, and S. Takagi
    • Organizer
      2021 IEEE International Reliability Physics Symposium (IRPS)
    • Int'l Joint Research
  • [Presentation] Defect control of Y2O3-based SiGe MOS interfaces properties2021

    • Author(s)
      T.-E. Lee, K. Toprasertpong, M. Takenaka and S. Takagi
    • Organizer
      2021 年第 68 回応用物理学会春季学術講演会
    • Invited
  • [Presentation] Characterization of slow traps in MOS interfaces of TiN/Y2O3/SiGe gate stacks2021

    • Author(s)
      T.-E. Lee, K. Toprasertpong, M. Takenaka and S. Takagi
    • Organizer
      2021 年第 68 回応用物理学会春季学術講演会
  • [Presentation] Revision of conductance method for evaluating interface state density at MFIS interfaces2020

    • Author(s)
      T.-E. Lee, Z. -Y. Lin, K. Toprasertpong, M. Takenaka, and S. Takagi
    • Organizer
      51st IEEE Semiconductor Interface Specialists Conference (SISC)
    • Int'l Joint Research
  • [Presentation] Asymmetric Polarization Response of Electrons and Holes in Si FeFETs: Demonstration of Absolute Polarization Hysteresis Loop and Inversion Hole Density over 2x1013 cm-22020

    • Author(s)
      K. Toprasertpong, Z. -Y. Lin, T. -E. Lee, M. Takenaka, and S. Takagi
    • Organizer
      2020 Symposia on VLSI Technology and Circuits
    • Int'l Joint Research
  • [Presentation] 強誘電体FETにおける分極・電荷のカップリングとメモリ特性への影響2020

    • Author(s)
      トープラサートポン カシディット, 林早陽;, 李宗恩, 竹中充, 高木信一
    • Organizer
      シリコン材料・デバイス(SDM)研究会
    • Invited
  • [Presentation] Si強誘電体FETにおける強誘電分極に誘起される反転層電荷の振る舞い2020

    • Author(s)
      Kasidit Toprasertpong, Zaoyang Lin, Tsung-En Lee, Mitsuru Takenaka, Shinichi Takagi
    • Organizer
      2019 第81回 応用物理学会 秋季学術講演会
  • [Presentation] Impact of ALD high-k materials on SiGe MOS interface properties with TiN gate2020

    • Author(s)
      T.-E. Lee, K. Toprasertpong, M. Takenaka and S. Takagi
    • Organizer
      2020 第81回 応用物理学会 秋季学術講演会
  • [Presentation] Improvement of ferroelectric properties of TiN/Hf0.5Zr0.5O2/Si gate stacks by inserting Al2O3 interfacial layers2020

    • Author(s)
      Z.-Y. Lin, T.-E. Lee, H.-Z. Tang, K. Toprasertpong, M. Takenaka and S. Takagi
    • Organizer
      2020年第67回応用物理学会春季学術講演会

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Published: 2021-12-27  

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