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2013 Fiscal Year Final Research Report

Single Molecule Spectroscopy using Probe Microscope

Research Project

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Project/Area Number 21225001
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Physical chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

KAWAI Maki  東京大学, 新領域創成科学研究科, 特任教授 (70177640)

Co-Investigator(Kenkyū-buntansha) KIM Yousoo  独立行政法人理化学研究所, Kim 表面界面研究室, 准主任研究員 (50373296)
TAKAGI Noriaki  東京大学, 大学院新領域創成科学研究科, 准教授 (50252416)
UEBA Hiromu  富山大学, 理工学研究部(工学), 教授 (70019214)
SHIRAKI Susumu  東北大学, 原子分子材料科学高等研究機構, 講師 (80342799)
Project Period (FY) 2009-05-11 – 2014-03-31
Keywords表面・界面 / 単分子操作 / 走査プローブ / 分子分光
Research Abstract

Scanning Tunneling Microscopy (STM) is not only a microscope to observe surface structure in atomic scale but also a point source of electrons of both high spatial and energy resolutions. Action spectroscopy with STM (STM-AS) is to analyze the reactions of a single molecule excited by electrons emitted from a sharp STM tip. We have successfully established the mechanism on inelastic excitation processes by tunneling electrons and the subsequent dynamics of a single molecule by using well-designed experiments and theoretical model calculations.

  • Research Products

    (47 results)

All 2014 2013 2012 2011 2010 Other

All Journal Article (25 results) (of which Peer Reviewed: 25 results) Presentation (19 results) (of which Invited: 19 results) Book (2 results) Remarks (1 results)

  • [Journal Article] Dissociation pathways of a single dimethyl disulfide on Cu(111) : reaction induced by simultaneous excitation of two vibrational modes2014

    • Author(s)
      K. Motobayashi, Y. Kim, R. Arafune, M. Ohara, H. Ueba, M. Kawai
    • Journal Title

      J. Chem. Phys

      Volume: 140 Pages: 194705(1-8)

    • Peer Reviewed
  • [Journal Article] Theory of action spectroscopy for single-molecule reactions induced by vibrational excitations with STM2014

    • Author(s)
      T. Frederiksen, M. Paulsson, H. Ueba
    • Journal Title

      Phys.Rev. B

      Volume: 89 Pages: 035427

    • Peer Reviewed
  • [Journal Article] Isotope effect in acetylene C_2H_2 and C_2D_2 rotations on Cu(001)2014

    • Author(s)
      Y. E. Shchadilova, S. G. Tikhodeev, M. Paulsson, H. Ueba
    • Journal Title

      Phys. Rev. B

      Volume: 89 Pages: 165418

    • Peer Reviewed
  • [Journal Article] Direct observation of adsorption geometry for the van der Waals adsorption of a single π-conjugated hydrocarbon molecule on Au(111)2014

    • Author(s)
      J.-H. Kim, J. Jung, K. Tahara, Y. Tobe, Y. Kim, M. Kawai
    • Journal Title

      J. Chem. Phys

      Volume: 140 Pages: 074709(1-5)

    • Peer Reviewed
  • [Journal Article] Lateral hopping and desorption of a single CO molecule on a Cu(110) surface induced by femtosecond laser pulses2013

    • Author(s)
      H. Ueba, Y. Ootsuka
    • Journal Title

      Phys. Rev. B

      Volume: 87 Pages: 205403

    • Peer Reviewed
  • [Journal Article] Rotation of a Single Acetylene Molecule on Cu(001) by Tunneling Electrons in STM2013

    • Author(s)
      Y. E. Shchadilova, S. G. Tikhodeev, M. Paulsson, H. Ueba
    • Journal Title

      Phys. Rev. Lett

      Volume: 111 Pages: 186102

    • Peer Reviewed
  • [Journal Article] Enhancement of inelastic Electron Tunneling Conductance caused by Electronic Decoupling in Iron Phthalocyanine Bilayer on Ag(111)2013

    • Author(s)
      N. Ohta, R. Arafune, N. Tsukahara, M. Kawai,N. Takagi
    • Journal Title

      J. Phys. Chem. C

      Volume: 117 Pages: 21832-21837

    • Peer Reviewed
  • [Journal Article] STM investigation of CO ordering on Pt(111) : From an isolated molecule to high-coverage superstructure2013

    • Author(s)
      H. J. Yang, T. Minato, M. Kawai, Y. Kim
    • Journal Title

      J. Phys. Chem. C

      Volume: 117 Pages: 16429-16437

    • Peer Reviewed
  • [Journal Article] Tailoring electronic states of a single molecule using adamantane-based molecular tripods2013

    • Author(s)
      S. Katano, Y. Kim, T. Kitagawa, M. Kawai
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: 15 Pages: 14229-14233

    • Peer Reviewed
  • [Journal Article] Orbital-selective single molecule reactions on a metal surface studied by low-temperature scanning tunneling microscopy2013

    • Author(s)
      S. Katano, Y. Kim, M. Trenary, M. Kawai
    • Journal Title

      Chem. Commun

      Volume: 49 Pages: 4679-4681

    • Peer Reviewed
  • [Journal Article] Substrate-induced symmetry breaking in silicene2013

    • Author(s)
      C.-L. Lin, R. Arafune, K. Kawahara, M. Kanno, N. Tsukahara, E. Minamitani, Y. Kim, M. Kawai, N. Takagi
    • Journal Title

      Phys. Rev. Lett

      Volume: 110 Pages: 076801(1-5)

    • Peer Reviewed
  • [Journal Article] 分子骨格と吸着構造が生み出す新奇な近藤効果 (最近の研究から)2013

    • Author(s)
      南谷英美、塚原規志、金有洙、高木紀明
    • Journal Title

      日本物理学会誌

      Volume: 68 Pages: 162-166

    • Peer Reviewed
  • [Journal Article] Identification at the Single Molecule Level of C_2H_x Moieties Derived from Acetylene on the Pt(111) Surface2012

    • Author(s)
      T. Okada, Y. Kim, M. Trenary, M. Kawai
    • Journal Title

      J. Phys. Chem. C

      Volume: 116 Pages: 18372-18381

    • Peer Reviewed
  • [Journal Article] Combined scanning tunneling microscopy and high-resolution electron energy loss spectroscopy study on the adsorption state of CO on Ag(001)2012

    • Author(s)
      R. Arafune, H.-J. Shin, J. Jung, E. Minamitani, N. Takagi, Y. Kim, M. Kawai
    • Journal Title

      Langmuir

      Volume: 28 Pages: 13249-13252

    • Peer Reviewed
  • [Journal Article] Ordering of molecules with π-conjugated triangular core by switching hydrogen bonding and van der Waals interactions2012

    • Author(s)
      J.-H. Kim, K. Tahara, J. Jung, S. De Feyter, Y. Tobe, Y. Kim, M.Kawai
    • Journal Title

      J. Phys. Chem. C

      Volume: 116 Pages: 17082-17088

    • Peer Reviewed
  • [Journal Article] Symmetry-driven novel Kondo effect in a molecule2012

    • Author(s)
      E. Minamitani, N. Tsukahara, D. Matsunaka, Y. Kim, N. Takagi, M. Kawai
    • Journal Title

      Phys. Rev. Lett

      Volume: 109 Pages: 086602(1-5)

    • Peer Reviewed
  • [Journal Article] Ligand field effect at oxide-metal interface on the chemical reactivity of ultrathin oxide film surface2012

    • Author(s)
      J. Jung, H.-J. Shin, Y. Kim, M. Kawai
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 10554-10561

    • Peer Reviewed
  • [Journal Article] Two dimensional superstructure formation of fluorinated fullerene on Au(111) : A scanning tunneling microscopy study2012

    • Author(s)
      T. K. Shimizu, J. Jung, T. Otani, Y.-K. Han, M. Kawai, Y. Kim
    • Journal Title

      ACS Nano

      Volume: 6 Pages: 2679-2685

    • Peer Reviewed
  • [Journal Article] Spectral fitting of action spectra for motions and reactions of single molecules on metal surfaces2011

    • Author(s)
      K. Motobayashi, S. Katano, Y. Kim, M. Kawai
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: 86 Pages: 75-79

    • Peer Reviewed
  • [Journal Article] STMを用いた表面吸着分子のアクションスペクトル―定量解析から得られる新知見―2011

    • Author(s)
      本林健太,金有洙,上羽弘,川合眞紀
    • Journal Title

      表面科学

      Volume: 32 Pages: 597-602

    • Peer Reviewed
  • [Journal Article] Activation of ultrathin oxide films for chemical reaction by interface defects2011

    • Author(s)
      J. Jung, H.-J. Shin, Y. Kim, and M. Kawai
    • Journal Title

      J. Am. Chem. Soc

      Volume: 133 Pages: 6142-6145

    • Peer Reviewed
  • [Journal Article] Evolution of Kondo resonance from a single impurity molecule to the two-dimensional lattice2011

    • Author(s)
      N. Tsukahara, S. Shiraki, S. Itou, N. Ohta, N. Takagi, M. Kawai
    • Journal Title

      Phys. Rev. Lett

      Volume: 106 Pages: 187401(4)

    • Peer Reviewed
  • [Journal Article] 表面に吸着した鉄(II)フタロシアニンの磁性-スピン、磁気異方性、近藤効果-2011

    • Author(s)
      高木紀明、塚原規志、川合眞紀
    • Journal Title

      表面科学

      Volume: 32 Pages: 629-634

    • Peer Reviewed
  • [Journal Article] Insights into action spectroscopy for single molecule motion and reactions through inelastic electron tunneling2010

    • Author(s)
      K. Motobayashi, Y. Kim, H. Ueba, M. Kawai
    • Journal Title

      Phys. Rev. Lett

      Volume: 105 Pages: 076101

    • Peer Reviewed
  • [Journal Article] State-selective dissociation of a single water molecule on an ultrathin MgO film2010

    • Author(s)
      H. -J. Shin, J. Jung, K. Motobayashi, S. Yanagisawa, Y. Morikawa, Y. Kim, M. Kawai
    • Journal Title

      Nat. Mater

      Volume: 9 Pages: 442-447

    • Peer Reviewed
  • [Presentation] XMCDによる3d 遷移金属ナノ構造の磁性研究2014

    • Author(s)
      白木 將
    • Organizer
      「放射光を用いたナノ・ミクロの表面・バルク解析」~ソフト・ハードX 線による極限評価~
    • Place of Presentation
      仙台
    • Year and Date
      2014-01-27
    • Invited
  • [Presentation] Electronic property control of 2-D molecular systems2013

    • Author(s)
      Y. Kim
    • Organizer
      2013 International Symposium on Additive Manufacturing and Printed Electronics
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2013-11-29
    • Invited
  • [Presentation] STMを用いた単分子分光2013

    • Author(s)
      川合 眞紀、上羽 弘、金 有洙
    • Organizer
      第33回表面科学学術講演会
    • Place of Presentation
      茨城県つくば市
    • Year and Date
      2013-11-26
    • Invited
  • [Presentation] Single molecule chemistry2013

    • Author(s)
      Y. Kim
    • Organizer
      3rd Asia-Korea Conference on Science and Technology 2013 (AKC 2013)
    • Place of Presentation
      Singapore
    • Year and Date
      2013-11-23
    • Invited
  • [Presentation] Single molecule chemistry with a STM and reactions at surfaces2013

    • Author(s)
      M. Kawai, Y. Kim, N. Takagi
    • Organizer
      AVS 60th International Symposium and Exhibition
    • Place of Presentation
      Long beach, California U.S.A
    • Year and Date
      2013-10-31
    • Invited
  • [Presentation] Single Molecule Spectroscopy at Surfaces2013

    • Author(s)
      M. Kawai
    • Organizer
      19th International Vacuum Congress(IVC-19)
    • Place of Presentation
      Paris, France
    • Year and Date
      2013-09-10
    • Invited
  • [Presentation] Local Symmetry Rules Spin Ground State : FePc on Au(111)2013

    • Author(s)
      N. Tsukahara ,N. Takagi, M. Kawai, E. Minamitani, Y. Kim
    • Organizer
      Controlled atomic dynamics on solid surfaces : Atom and Molecular Manipulation
    • Place of Presentation
      San Sebastian, Spain
    • Year and Date
      2013-05-15
    • Invited
  • [Presentation] Single molecule spectroscopy of spin state at surfaces2013

    • Author(s)
      M. Kawai
    • Organizer
      American Chemical Society 245th National Meeting & Exposition
    • Place of Presentation
      New Orleans, U.S.A.
    • Year and Date
      2013-04-08
    • Invited
  • [Presentation] 表面界面の単分子分光2013

    • Author(s)
      川合 眞紀
    • Organizer
      CREST「ナノ界面技術の基盤構築」研究領域第2回シンポジウム
    • Place of Presentation
      市ヶ谷
    • Year and Date
      2013-02-10
    • Invited
  • [Presentation] Evolution of Kondo Resonance from a Single Impurity Molecule to the Two-Dimensional Kondo Lattice2012

    • Author(s)
      N. Takagi
    • Organizer
      APS march Meeting (Invited Session : "Spin Coupling and Kondo Screening Individual Magnetic Spins")
    • Place of Presentation
      Boston, USA
    • Year and Date
      20120227-0302
    • Invited
  • [Presentation] Single Molecular Spectroscopy at Surfaces using STM2012

    • Author(s)
      M. Kawai
    • Organizer
      39th Conference on the Physics and Chemistry of Surfaces and Interfaces(PCSI-39)
    • Place of Presentation
      Santafe, U.S.A.
    • Year and Date
      20120122-26
    • Invited
  • [Presentation] Single molecule spectroscopy of Spins on Metals2012

    • Author(s)
      M. Kawai
    • Organizer
      The 13th International Conference on Desorption and Dynamics Induced by Electronic Transitions(DIET13)
    • Place of Presentation
      Strartford-upon-Avo n, UK
    • Year and Date
      2012-07-04
    • Invited
  • [Presentation] 分子の声を聞く2012

    • Author(s)
      川合 眞紀
    • Organizer
      第21回向井賞記念科学講演会
    • Place of Presentation
      川崎市
    • Year and Date
      2012-06-05
    • Invited
  • [Presentation] Molecular magnetism at surfaces explored by single molecule spectroscopy2011

    • Author(s)
      N. Takagi
    • Organizer
      28th European Conference on Surface Science (ECOSS 28)
    • Place of Presentation
      Wroclaw, Poland
    • Year and Date
      20110828-0902
    • Invited
  • [Presentation] From local to single molecular spectroscopy at heterogeneous surfaces - Scanning tunneling spectroscopy -2011

    • Author(s)
      M. Kawai
    • Organizer
      International Max Planck Research School for Complex Surfaces in Materials Science
    • Place of Presentation
      Schloss Ringberg, Germany
    • Year and Date
      20110221-25
    • Invited
  • [Presentation] Listen to the action of individual molecules-Single molecular spectroscopy at surfaces2011

    • Author(s)
      M. Kawai
    • Organizer
      Marie Curie Symposium in the course of the Science forum of the German Chemical Society
    • Place of Presentation
      Bremen, Germany
    • Year and Date
      2011-09-05
    • Invited
  • [Presentation] Lesson from the action of individual molecules-Single molecular spectroscopy at surfaces-2011

    • Author(s)
      M. Kawai
    • Organizer
      The Fundamentals of Photocatalysis Symposium
    • Place of Presentation
      Hefei, China
    • Year and Date
      2011-07-11
    • Invited
  • [Presentation] 有機金属界面のスピン状態2010

    • Author(s)
      高木 紀明
    • Organizer
      日本化学会講演会「有機金属界面と電気伝導」
    • Place of Presentation
      東京
    • Year and Date
      2010-11-01
    • Invited
  • [Presentation] Mode-selective and stateselective chemistry of a single molecule with STM2010

    • Author(s)
      Y. Kim
    • Organizer
      XIII International Conference on Vibrations at Surfaces(VAS13)
    • Place of Presentation
      Orlando, USA
    • Year and Date
      2010-03-02
    • Invited
  • [Book] マイクロビームアナリシス・ハンドブック2014

    • Author(s)
      白木 將
    • Total Pages
      303-308, 407-410
    • Publisher
      オーム社
  • [Book] 問題と解説で学ぶ表面科学2013

    • Author(s)
      白木 將
    • Total Pages
      92-92
    • Publisher
      共立出版
  • [Remarks]

    • URL

      http://www.surfchem.k.u-tokyo.ac.jp/

URL: 

Published: 2015-06-25  

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