2014 Fiscal Year Final Research Report
Creation of Supramolecular Complex Systems based on Dynamic Chemistry
| Project/Area Number |
21225003
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| Research Category |
Grant-in-Aid for Scientific Research (S)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | The University of Tokyo |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
MIYAKE Ryosuke お茶の水女子大学, 大学院人間文化創成科学研究科, 助教 (30509542)
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| Co-Investigator(Renkei-kenkyūsha) |
TASHIRO Shohei 東京大学, 大学院理学系研究科, 助教 (80420230)
UBE Hitoshi 東京大学, 大学院理学系研究科, 助教 (00512138)
TAKEZAWA Yusuke 東京大学, 大学院理学系研究科, 助教 (70508598)
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| Project Period (FY) |
2009-04-01 – 2015-03-31
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| Keywords | 超分子錯体 / 金属錯体 / 金属配列 / 分子認識 / 分子配列 / 動的解析 / 配位空間 |
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| Outline of Final Research Achievements |
We started this research project with the aim of achieving the rational design of organic molecules containing self-assembly information, using metal ions to establish a constructive method for 10 nm-sized multi-component supramolecules, and thereby developing supramolecular systems which perform diverse functions related to “energy transformation”, “motional control”, and “material transformation”. For this purpose, we have developed a supramolecular space which allows precise arrangement and transformation of a variety of molecules (reactive organic molecules and metal complexes). We could also show the world’s first visualization of a transient state of molecular arrangement. Moreover, novel supramolecular structural and functional motives have been achieved directed toward controllable metal array, light-driven control of rotary motions and multi-electron reactions.
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| Free Research Field |
化学
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