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2013 Fiscal Year Annual Research Report

マイクロ・ナノ熱流体複合センシングと界面制御デバイスの開発

Research Project

Project/Area Number 21226006
Research InstitutionKeio University

Principal Investigator

菱田 公一  慶應義塾大学, 理工学部, 教授 (40156592)

Co-Investigator(Kenkyū-buntansha) 佐藤 洋平  慶應義塾大学, 理工学部, 教授 (00344127)
堀田 篤  慶應義塾大学, 理工学部, 准教授 (30407142)
三木 則尚  慶應義塾大学, 理工学部, 准教授 (70383982)
柿沼 康弘  慶應義塾大学, 理工学部, 准教授 (70407146)
Project Period (FY) 2009-05-11 – 2014-03-31
Keywords熱流体センシング / 熱流動制御 / ポリマー / MEMS・NEMS / ナノ・マイクロ切削加工 / 気体選択的透過デバイス / マイクロPIV/LIF / マイクロコンタクトプリント
Research Abstract

マイクロ・ナノ基盤要素技術のシステム統合化を目指して,ナノPIV/LIFを駆使し,界面熱流動現象を支配する電位形成メカニズムの解明を行った.次に液体窒素下切削加工によるデバイス作成の際に,加工面品位を一層高めるために,無回転の単結晶ダイヤモンド工具を用いたシェーパ加工を適用し,その加工特性解析に基づき有効性を評価した.これまでのマイクロエンドミル加工のような微細工具を高速回転させて流路を製作する方法に比べ,提案した加工手法は低エネルギで,かつ表面粗さ40 nmRaの高品位な表面を再現性高く加工可能とした.そしてナノ・マイクロ加工を活かしたデバイス内の界面創製および制御技術に関する研究を行った.エレクトロスピニングによるガラスナノ粒子パターニング技術を発展させ,ステンシルマスクを用い基板上の特定領域にのみガラスナノ粒子をパターニングする技術を開発した.これにより,マイクロ流路内の特定の箇所にのみ界面修飾が可能となる.また,局所的な表面エネルギ制御に有効なマイクロコンタクトプリント技術について,プリント用のスタンプ,基板,そしてインクとなる自己組織単分子膜の親和性が,プリント精度に及ぼす影響を実験的に評価し,特に短い接触時間においては精度に大きく影響することを明らかにした.更に配向性と径を制御した硬質シリコーンファイバーを,汎用シリコーンポリマーにコンポジットし,力学物性とガス透過性を評価した.力学物性は,配向性を付与したファイバーをコンポジットした場合は,配向性を付与しないファイバーをコンポジットした場合に比べて,弾性率が約1.3倍に向上することがわかった.またガス透過性に関しては,配向性を付与したファイバーをコンポジットした場合は,配向性のないファイバーをコンポジットした場合に比べてCO2透過性が約1.4倍に向上し,CO2/N2分離性が維持されていることが明らかとなった.

Current Status of Research Progress
Reason

25年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

25年度が最終年度であるため、記入しない。

  • Research Products

    (39 results)

All 2014 2013

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (27 results) (of which Invited: 1 results) Book (2 results)

  • [Journal Article] Combined laser-based measurements for micro- and nanoscale transport phenomena2014

    • Author(s)
      Hishida, K., Ichiyanagi, M., Kazoe, Y. & Sato, Y
    • Journal Title

      Heat Transfer Engineering

      Volume: Vol.35, No.2 Pages: 125-141

    • DOI

      10.1080/01457632.2013.812481

    • Peer Reviewed
  • [Journal Article] Micropatterning of silica nanoparticles by electrospray deposition through a stencil mask2014

    • Author(s)
      Higashi, K., Uchida, K., Hotta, A., Hishida, K. & Miki, N.
    • Journal Title

      Journal of Laboratory Automation

      Volume: 19 Pages: 75-81

    • DOI

      10.1177/2211068213495205

    • Peer Reviewed
  • [Journal Article] Preparation and characterization of 2-methacryloyloxyethyl phosphorylcholine polymer nanofibers prepared via electrospinning for biomedical materials2014

    • Author(s)
      Maeda, T., Hagiwara, K., Yoshida, S., Hasebe, T. & Hotta, A.
    • Journal Title

      Journal of Applied Polymer Science

      Volume: 131 Pages: -

    • DOI

      DOI:10.1002/app.40606

    • Peer Reviewed
  • [Journal Article] Effects of salt concentrations on the structural transitions of peptide-amphiphile solution2014

    • Author(s)
      Otsuka, T. & Hotta, A.
    • Journal Title

      Materials Research Society Symposia Proceedings

      Volume: 1622 Pages: -

    • DOI

      DOI:10.1557/opl.2014.40

    • Peer Reviewed
  • [Journal Article] The structure and the mechanical properties of a newly fabricated cellulose-nanofiber/polyvinyl-alcohol composite2014

    • Author(s)
      Oishi, Y. & Hotta, A.
    • Journal Title

      Materials Research Society Symposia Proceedings

      Volume: 1621 Pages: -

    • DOI

      DOI:10.1557/opl.2014.141

    • Peer Reviewed
  • [Journal Article] Velocity measurement of sub-millimeter-scale gas flow by spark tracing method2013

    • Author(s)
      Ichiyanagi, M., Koyama, Y., Sato, Y. & Hishida, K.
    • Journal Title

      Journal of Thermal Science and Technology

      Volume: 83 Pages: 517-532

    • DOI

      10.1299/jtst.8.5.17

    • Peer Reviewed
  • [Journal Article] Non-intrusive measurement of microscale temperature distribution by spontaneous Raman imaging2013

    • Author(s)
      Kuriyama, R. & Sato, Y.
    • Journal Title

      Microfluidics and Nanofluidics

      Volume: 14 Pages: 1031-1037

    • DOI

      10.1007/s10404-012-1110-8

    • Peer Reviewed
  • [Journal Article] Hydrophobicity and non-thrombogenicity of nanoscale dual rough surface coated with fluorine-incorporated diamond-like carbon films: Biomimetic surface for blood-contacting medical devices2013

    • Author(s)
      Hasebe, T., Nagashima, S., Kamijo, A., Moon, M.W., Kashiwagi, Y., Hotta, A., Lee, K.R., Takahashi, K., Yamagami, T. & Suzuki, T.
    • Journal Title

      Diamond and Related Materials

      Volume: 38 Pages: 14-18

    • DOI

      10.1016/j.diamond.2013.06.001

    • Peer Reviewed
  • [Journal Article] Basic fibroblast growth factor as a potential stent coating material inducing endothelial cell proliferation2013

    • Author(s)
      Kitamura, N., Hasebe, T., Matsumoto, T, Hotta, A., Suzuki, T., Yamagami, T. & Terada, H.
    • Journal Title

      Journal of Atherosclerosis and Thrombosis

      Volume: 21 Pages: -

    • DOI

      DOI: 10.5551/jat.20404

    • Peer Reviewed
  • [Journal Article] Fabrication of super absorbent polymer micro structures by nanoimprinting and post swelling process2013

    • Author(s)
      Inaba, T., Kano, T., & Miki, N.
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 52 Pages: UNSP 06GL11

    • DOI

      10.7567/JJAP.52.06GL11

    • Peer Reviewed
  • [Presentation] Structure and mechanical properties of dried syndiotactic polypropylene gels formed at different cooling temperatures2014

    • Author(s)
      Mizuno, S. & Hotta, A.
    • Organizer
      APS March Meeting 2014
    • Place of Presentation
      Colorado, USA
    • Year and Date
      20140303-20140307
  • [Presentation] A new method for the alignment of electrospun nanofibers by oxygen plasma treatment2014

    • Author(s)
      Kobayashi, N., Miki, N., Hishida, K. & Hotta, A.
    • Organizer
      APS March Meeting 2014
    • Place of Presentation
      Colorado, USA
    • Year and Date
      20140303-20140307
  • [Presentation] Biodegradability and mechanical properties of poly(butylene succinate) composites with finely dispersed hydrophilic poly(acrylic acid)2014

    • Author(s)
      Mizuno, S. & Hotta, A.
    • Organizer
      APS March Meeting 2014
    • Place of Presentation
      Colorado, USA
    • Year and Date
      20140303-20140307
  • [Presentation] Effects of O2 plasma treatment of PDMS on the deposition of electrospun PVA nanofibers2014

    • Author(s)
      Kobayashi, N., Miki, N., Hishida, K. & Hotta, A.
    • Organizer
      APS March Meeting 2014
    • Place of Presentation
      Colorado, USA
    • Year and Date
      20140303-20140307
  • [Presentation] Ultra-precision machining focusing on material property2014

    • Author(s)
      Kakinuma, Y.
    • Organizer
      International Workshop on the Fabrication and Application of Microstructured Optical Devices
    • Place of Presentation
      横浜
    • Year and Date
      20140227-20140228
  • [Presentation] Newly developed drug-eluting stent (DES) system for cardiovascular diseases2013

    • Author(s)
      Hasebe, T., Kitagawa, T., Nagashima, S., Matsumoto, T., Kitamura, N., Hotta, A. & Suzuki, T.
    • Organizer
      International Symposium on Atomic Level Characterizations for New Materials and Devices
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      20131202-20131206
  • [Presentation] Effects of salt concentrations on the structural transitions of peptide-amphiphile solution2013

    • Author(s)
      Otsuka T. & Hotta, A.
    • Organizer
      2013 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, USA
    • Year and Date
      20131201-20131206
  • [Presentation] The gelation behavior observed in aqueous solutions of peptide amphiphile at different NaCl2013

    • Author(s)
      Otsuka T. & Hotta, A.
    • Organizer
      2013 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, USA
    • Year and Date
      20131201-20131206
  • [Presentation] Effects of alcohol on the rheology and the dispersion state of aqueous silica suspension2013

    • Author(s)
      Murano, A. & Hotta, A.
    • Organizer
      2013 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, USA
    • Year and Date
      20131201-20131206
  • [Presentation] Solvent and temperature dependence of the one-dimensional assembly and the 3D network formation observed in silica-nanoparticle solutions2013

    • Author(s)
      Murano, A. & Hotta, A.
    • Organizer
      2013 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, USA
    • Year and Date
      20131201-20131206
  • [Presentation] The solution properties and the structures of newly fabricated cellulose nanofibers2013

    • Author(s)
      Oishi, Y. & Hotta, A.
    • Organizer
      2013 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, USA
    • Year and Date
      20131201-20131206
  • [Presentation] The structure and the mechanical properties of a newly fabricated cellulose-nanofiber/polyvinyl-alcohol composite2013

    • Author(s)
      Oishi, Y. & Hotta, A.
    • Organizer
      2013 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, USA
    • Year and Date
      20131201-20131206
  • [Presentation] Elastomeric block-copolymer nanofibers fabricated by electrospinning2013

    • Author(s)
      Maeda, T. & Hotta, A.
    • Organizer
      2013 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, USA
    • Year and Date
      20131201-20131206
  • [Presentation] Gelation behavior of SIS triblock-copolymer solution controlled by Mixed Solvents2013

    • Author(s)
      Maeda, T. & Hotta, A.
    • Organizer
      2013 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, USA
    • Year and Date
      20131201-20131206
  • [Presentation] The sol-gel behavior of triblock-copolymer solution in controlling the solvent selectivity2013

    • Author(s)
      Maeda, T. & Hotta, A.
    • Organizer
      The 13th Pacific Polymer Conference
    • Place of Presentation
      Kaohsiung, Taiwan
    • Year and Date
      20131117-20131122
  • [Presentation] The role of sol-gel behavior of copolymer solution in the formation of elastomeric block-copolymer nanofibers2013

    • Author(s)
      Maeda, T. & Hotta, A.
    • Organizer
      The 13th Pacific Polymer Conference
    • Place of Presentation
      Kaohsiung, Taiwan
    • Year and Date
      20131117-20131122
  • [Presentation] Preparation and characterization of phospholipid polymer nanofibers via electrospinning for tissue-engineered vascular grafts2013

    • Author(s)
      Hagiwara, K. & Hotta, A.
    • Organizer
      The 13th Pacific Polymer Conference
    • Place of Presentation
      Kaohsiung, Taiwan
    • Year and Date
      20131117-20131122
  • [Presentation] Human umbilical vein endothelial cell interaction with phospholipid polymer nanofibers2013

    • Author(s)
      Hagiwara, K. & Hotta, A.
    • Organizer
      The 13th Pacific Polymer Conference
    • Place of Presentation
      Kaohsiung, Taiwan
    • Year and Date
      20131117-20131122
  • [Presentation] マイクロコンタクトプリンティング法におけるスタンプとインク分子間の親和性の影響2013

    • Author(s)
      稲葉知美,ジャン・トマ,三木則尚
    • Organizer
      第30回センサ・マイクロマシンと応用システムシンポジウム
    • Place of Presentation
      仙台
    • Year and Date
      20131105-20131107
  • [Presentation] Non-intrusive measurement of chemical specificity with micro resolution using CARS microscopy2013

    • Author(s)
      Noguchi, T., Kuriyama, R., Ozawa, K. & Sato, Y.
    • Organizer
      The 17th International Conference on Miniaturized Systems for Chemistry and Life Sciences
    • Place of Presentation
      Freiburg, Germany
    • Year and Date
      20131028-20131031
  • [Presentation] Raman imaging technique for non-intrusive visualization of scalar distribution in microfluidics2013

    • Author(s)
      Kuriyama, R., Ito, A., Noguchi, T., Ozawa, K. & Sato, Y.
    • Organizer
      The 17th International Conference on Miniaturized Systems for Chemistry and Life Sciences
    • Place of Presentation
      Freiburg, Germany
    • Year and Date
      20131028-20131031
  • [Presentation] Effect of affinity between the stamp and ink molecules on micro contact printing2013

    • Author(s)
      Inaba, T., Jean, T. & Miki, N.
    • Organizer
      The 17th International Conference on Miniaturized Systems for Chemistry and Life Sciences
    • Place of Presentation
      Freiburg, Germany
    • Year and Date
      20131028-20131031
  • [Presentation] OH-吸着による液液界面電位のナノLIF計測2013

    • Author(s)
      佐藤悠, 田部井祐, 佐藤洋平, 菱田公一
    • Organizer
      日本機械学会熱工学コンファレンス2013
    • Place of Presentation
      弘前
    • Year and Date
      20131019-20131020
  • [Presentation] ダイヤモンドバイトを用いた粘弾性樹脂材の極低温微細切削加工2013

    • Author(s)
      吉川竣,田部井佑,柿沼康弘,佐藤洋平,青山藤詞郎
    • Organizer
      2013年度精密工学会秋季大会
    • Place of Presentation
      大阪
    • Year and Date
      20130912-20130914
  • [Presentation] Controlling the biodegradability of poly(butylene succinate) by photoinduced graft polymerization2013

    • Author(s)
      Maeda, T., Kanemura, C. & Hotta, A.
    • Organizer
      ACS March Meeting 2013
    • Place of Presentation
      New Orleans, USA
    • Year and Date
      20130908-20130912
  • [Presentation] Syndiotactic polypropylene nanofibers fabricated by a solution electrospinning method with single solvent at ambient temperature2013

    • Author(s)
      Maeda, T., Takaesu, K. & Hotta, A.
    • Organizer
      ACS March Meeting 2013
    • Place of Presentation
      New Orleans, USA
    • Year and Date
      20130908-20130912
  • [Presentation] Laser-based measurement techniques for interfacial transport phenomena in microchannels2013

    • Author(s)
      Hishida, K., Ichiyanagi, M., Kazoe, K. & Sato, Y.
    • Organizer
      ASME 2013 The 11th International Conference on Nanochannels, Microchannels, and Minichannels
    • Place of Presentation
      札幌
    • Year and Date
      20130616-20130619
    • Invited
  • [Book] Thin Films and Coatings in Biology2013

    • Author(s)
      Hotta, A. & Hasebe, T.
    • Total Pages
      365
    • Publisher
      Springer
  • [Book] 次世代ポリオレフィン総合研究2013

    • Author(s)
      前田知貴,堀田篤
    • Total Pages
      174
    • Publisher
      三恵社

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Published: 2015-05-28  

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