2011 Fiscal Year Final Research Report
Development of Highly Selective Deuteration Reaction Using Quantum Molecular Sieving Effect Enhanced in Nanospace Fields
Project/Area Number |
21241026
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Research Category |
Grant-in-Aid for Scientific Research (A)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Nanomaterials/Nanobioscience
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Research Institution | Shinshu University (2010-2011) Chiba University (2009) |
Principal Investigator |
KANEKO Katsumi 信州大学, エキゾチック・ナノカーボンの創成と応用プロジェクト拠点, 特別特任教授 (20009608)
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Co-Investigator(Kenkyū-buntansha) |
OHBA Tomonori 千葉大学, 大学院・理学研究科, 助教 (80406884)
ITOH Tsutomu 信州大学, エキゾチック・ナノカーボンの創成と応用プロジェクト拠点, 助教 (40586822)
FUJIMORI Toshihiko 信州大学, エキゾチック・ナノカーボンの創成と応用プロジェクト拠点, 助教 (60586824)
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Project Period (FY) |
2009 – 2011
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Keywords | 量子分子篩効果 / ミクロポアフィリング / ナノ細孔 / 低温吸着 / カーボンナノチューブ / 水素 / メタン / 同位体分離 |
Research Abstract |
We elucidated the effect of the nanopore structure and temperature on quantum adsorption for hydrogen isotopes using well-defined single wall carbon nanotube. Also an explicit quantum molecular sieving effect for methane isotopes for nanoporous carbons was firstly shown. In this study, the quantum molecular sieving is evidenced with pure isotope gas adsorption and the mixed isotope gas adsorption.
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[Journal Article] Effect of Nanoscale Curvature Sign and Bundle Structure on Supercritical H_2 and CH_4 Adsorptivity of Single Wall Carbon Nanotube2011
Author(s)
M. Yamamoto, T. Itoh, H. Sakamoto, T. Fujimori, K. Urita, Y. Hattori, T. Ohba, H. Kagita, H. Kanoh, S. Niimura, K. Hata, K. Takeuchi, M. Endo, F. Rodriguez-Reinoso, K. Kaneko
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Journal Title
Adsorption
Volume: 17
Pages: 643-651
DOI
Peer Reviewed
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[Journal Article] Confinement in Carbon Nanospace-Induced Production of KI Nanocrystals of High Pressure Phase2011
Author(s)
K. Urita, Y. Shiga, T. Fujimori, Y. Hattori, H, Kanoh, T. Ohba, H. Tanaka, M. Yudasaka, S. Iijima, I, Moriguchi, F. Okino, M. Endo, K. Kaneko, J
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Journal Title
Am. Chem. Soc.
Volume: 133
Pages: 10344-10347
DOI
Peer Reviewed
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[Journal Article] Anomaly of CH_4 Molecular Assembly Confined in Single Wall Carbon Nanohorn Spaces2011
Author(s)
S. Hashimoto, T. Fujimori, H. Tanaka, K. Urita, T. Ohba, H. Kanoh, T. Itoh, M. Asai, H. Sakamoto, S. Niimura, M. Endo, F. Rodoriguez-Reinoso, K. Kaneko, J
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Journal Title
Am. Chem. Soc. 133
Pages: 2022-2024
DOI
Peer Reviewed
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[Journal Article] Selective D_2 Adsorption Enhanced by the Quantum Sieving Effect on Entangled Single-Wall Carbon Nanotubes2010
Author(s)
D. Noguchi, H. Tanaka, T. Fujimori, T. Kagita, Y. Hattori, H. Honda, K. Urita, S. Utsumi, Z.-M. Wang, T. Ohba, H. Kanoh, K. Hata, K. Kaneko
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Journal Title
J. Phys.: Condens. Matter
Volume: 22
Pages: 334207-334221
DOI
Peer Reviewed
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[Journal Article] Enhanced Hydrogen Adsorptivity of Single-Wall Carbon Nanotube Bundles by One-Step C_60-Pillaring Method2009
Author(s)
M. Arai, S. Utsumi, M. Kanamaru, K. Urita, T. Fujimori, N. Yoshizawa, D. Noguchi, K. Nishiyama, Y. Hattori, F. Okino, T. Ohba, H. Tanaka, H. Kanoh, K. Kaneko
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Journal Title
Nano Lett.
Volume: 9
Pages: 3694-3698
DOI
Peer Reviewed
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