Development of Highly Selective Deuteration Reaction Using Quantum Molecular Sieving Effect Enhanced in Nanospace Fields

2011 Fiscal Year Final Research Report

• Project/Area Number: 21241026
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Nanomaterials/Nanobioscience
• Research Institution: Shinshu University (2010-2011); Chiba University (2009)
• Principal Investigator: KANEKO Katsumi 信州大学, エキゾチック・ナノカーボンの創成と応用プロジェクト拠点, 特別特任教授 (20009608)
• Co-Investigator(Kenkyū-buntansha): OHBA Tomonori 千葉大学, 大学院・理学研究科, 助教 (80406884) ; ITOH Tsutomu 信州大学, エキゾチック・ナノカーボンの創成と応用プロジェクト拠点, 助教 (40586822) ; FUJIMORI Toshihiko 信州大学, エキゾチック・ナノカーボンの創成と応用プロジェクト拠点, 助教 (60586824)
• Project Period (FY): 2009 – 2011
• Keywords: 量子分子篩効果 / ミクロポアフィリング / ナノ細孔 / 低温吸着 / カーボンナノチューブ / 水素 / メタン / 同位体分離

Research Abstract

We elucidated the effect of the nanopore structure and temperature on quantum adsorption for hydrogen isotopes using well-defined single wall carbon nanotube. Also an explicit quantum molecular sieving effect for methane isotopes for nanoporous carbons was firstly shown. In this study, the quantum molecular sieving is evidenced with pure isotope gas adsorption and the mixed isotope gas adsorption.

Research Products

• [Journal Article] Collective Interactions of Molecules with an Interfacial Solid (2012)
  • Author(s): K. Kaneko, T. Itoh, T. Fujimori
  • Journal Title: Chem. Phys. Lett. Volume: 41 Pages: 466-475
  • DOI: DOI:10.1246/cl.2012.466.
  • Peer Reviewed
• [Journal Article] Formation of CO_x Free H_2 and Cup-stacked Carbon Nanotubes over Nano-Ni Dispersed Single Wall Carbon Nanohorns (2012)
  • Author(s): S. Wang, T. Itoh, T. Fujimori, M. M. Castro, A. S. Albero, F. Rodriguez-Reinoso, T. Ohba, H. Kanoh, K. Kaneko
  • Journal Title: Langmuir Volume: 28 Pages: 7564-7571
  • DOI: DOI:10.1021/la3006986.
  • Peer Reviewed
• [Journal Article] Selective Probe of the Morphology and Local Vibrations at Carbon Nanoasperities (2012)
  • Author(s): T. Fujimori, K. Urita, D. Tomanek, T. Ohba, I. Moriguchi, M. Endo, K. Kaneko
  • Journal Title: J. Chem. Phys. Volume: 136 Pages: 064505-1-5
  • DOI: DOI:10.1063/1.3682771.
  • Peer Reviewed
• [Journal Article] Effect of Nanoscale Curvature Sign and Bundle Structure on Supercritical H_2 and CH_4 Adsorptivity of Single Wall Carbon Nanotube (2011)
  • Author(s): M. Yamamoto, T. Itoh, H. Sakamoto, T. Fujimori, K. Urita, Y. Hattori, T. Ohba, H. Kagita, H. Kanoh, S. Niimura, K. Hata, K. Takeuchi, M. Endo, F. Rodriguez-Reinoso, K. Kaneko
  • Journal Title: Adsorption Volume: 17 Pages: 643-651
  • DOI: DOI:10.1007/s10450-011-9538-y
  • Peer Reviewed
• [Journal Article] Confinement in Carbon Nanospace-Induced Production of KI Nanocrystals of High Pressure Phase (2011)
  • Author(s): K. Urita, Y. Shiga, T. Fujimori, Y. Hattori, H, Kanoh, T. Ohba, H. Tanaka, M. Yudasaka, S. Iijima, I, Moriguchi, F. Okino, M. Endo, K. Kaneko, J
  • Journal Title: Am. Chem. Soc. Volume: 133 Pages: 10344-10347
  • DOI: DOI:10.1021/ja202565r
  • Peer Reviewed
• [Journal Article] Electronically Modified Single Wall Carbon Nanohorns with Iodine Adsorption (2011)
  • Author(s): F. Khoerunnisa, T. Fujimori, T. Itoh, H. Kanoh, T. Ohba, M. Yudasaka, S. Iijima, K. Kaneko
  • Journal Title: Chem. Phys. Lett. Volume: 501 Pages: 485-490
  • DOI: DOI:10.1016/j.cplett.2010.11.086.
  • Peer Reviewed
• [Journal Article] Anomaly of CH_4 Molecular Assembly Confined in Single Wall Carbon Nanohorn Spaces (2011)
  • Author(s): S. Hashimoto, T. Fujimori, H. Tanaka, K. Urita, T. Ohba, H. Kanoh, T. Itoh, M. Asai, H. Sakamoto, S. Niimura, M. Endo, F. Rodoriguez-Reinoso, K. Kaneko, J
  • Journal Title: Am. Chem. Soc. 133 Pages: 2022-2024
  • DOI: DOI:10.1021/ja1086886
  • Peer Reviewed
• [Journal Article] Selective D_2 Adsorption Enhanced by the Quantum Sieving Effect on Entangled Single-Wall Carbon Nanotubes (2010)
  • Author(s): D. Noguchi, H. Tanaka, T. Fujimori, T. Kagita, Y. Hattori, H. Honda, K. Urita, S. Utsumi, Z.-M. Wang, T. Ohba, H. Kanoh, K. Hata, K. Kaneko
  • Journal Title: J. Phys.: Condens. Matter Volume: 22 Pages: 334207-334221
  • DOI: DOI:10.1088/0953-8984/22/33/334207
  • Peer Reviewed
• [Journal Article] Evidence of Dynamic Pentagon-Heptagon Pairs in Single-Wall Carbon Nanotubes using Surface-Enhanced Raman Scattering (2010)
  • Author(s): T. Fujimori, K. Urita, T. Ohba, H. Kanoh, K. Kaneko
  • Journal Title: J. Am. Chem. Soc. Volume: 132 Pages: 6764-6767
  • DOI: DOI:10.1021/ja100760m
  • Peer Reviewed
• [Journal Article] Enhanced Hydrogen Adsorptivity of Single-Wall Carbon Nanotube Bundles by One-Step C_60-Pillaring Method (2009)
  • Author(s): M. Arai, S. Utsumi, M. Kanamaru, K. Urita, T. Fujimori, N. Yoshizawa, D. Noguchi, K. Nishiyama, Y. Hattori, F. Okino, T. Ohba, H. Tanaka, H. Kanoh, K. Kaneko
  • Journal Title: Nano Lett. Volume: 9 Pages: 3694-3698
  • DOI: DOI:10.1021/nl9015733
  • Peer Reviewed
• [Journal Article] Quantum Effects on Hydrogen Isotopes Adsorption in Nanopores (2009)
  • Author(s): H. Tanaka, D. Noguchi, A. Yuzawa, T. Kodaira, K. Kaneko
  • Journal Title: J. Low Temp. Phys. Volume: 157 Pages: 352-373
  • DOI: DOI:10.1007/s10909-009-9917-8
  • Peer Reviewed
• [Presentation] QUANTUM MOLECULAR SIEVING OF NANOPOROUS MATERIALS FOR HYDROGEN AND METHANE ISOTOPES (2012)
  • Author(s): K. Kaneko
  • Organizer: 6th Pacific Basin Conference on Adsorption Science and Technology(PBAST6)
  • Place of Presentation: Taiwan, Taipei
  • Year and Date: 20120520-23
• [Presentation] MICROPORE FILLING OF QUANTUM MOLECULES (2011)
  • Author(s): K. Kaneko
  • Organizer: The International Conference dedicated to the 50th anniversary of Academician M. M. Dubinin : MODERN PROBLEMS OF ADSORPTION
  • Place of Presentation: Moscow, Russia
  • Year and Date: 20111024-28
• [Presentation] QUANTUM MOLECULAR SIEVING OF ISOTOPIC HYDROGEN AND METHANE : APPLICATION POTENTIAL TO CONTROL OF RADIOACTIVE ELEMENTS (2011)
  • Author(s): K. Kaneko
  • Organizer: 2011 AIChE Annual Meeting
  • Place of Presentation: Minneapolis, USA
  • Year and Date: 20111016-21
• [Presentation] QUANTUM MOLECULAR SIEVING OF ISOTOPIC HYDROGEN AND METHANE (2011)
  • Author(s): K. Kaneko
  • Organizer: Annual International World Conference on Carbon(Carbon2011)
  • Place of Presentation: Shanghai, China
  • Year and Date: 20110724-29
• [Presentation] NONOENVIRONMENT-SENSITIVE SOLID PORE WALLS (2011)
  • Author(s): K. Kaneko
  • Organizer: International Workshop on Adsorption in Compliant Nanoporous Solids : Theory, Simulation, and Experiments
  • Place of Presentation: Paris, France
  • Year and Date: 20110609-0611
• [Presentation] NOVEL CHEMICAL FUNCTIONS OF CARBON NANOPACES AND THEIR APPLICATION POTENTIAL (2010)
  • Author(s): K. Kaneko
  • Organizer: The 5th International Symposium on Novel Carbon Resource Sciences
  • Place of Presentation: Perth, Australia
  • Year and Date: 20100422-23
• [Book] Hydrogen Adsorptivity of Bundle-Structure Controlled Single-Wall Carbon Nanotubes, Carbon Nanotubes-From Research to Applications (2011)
  • Author(s): S. Utsumi and K. Kaneko
  • Total Pages: 37-54
  • Publisher: InTech Open Access Publisher, Rijeka, Croatia
• [Book] Modeling, and Processing (2011)
  • Author(s): S. Utsumi and K. Kaneko
  • Total Pages: 353-386
  • Publisher: (Ed. N. Kane llopous) CRC Press
• [Book] ガス貯蔵・分離,炭素学 (2011)
  • Author(s): 金子克美、坂本裕俊
  • Total Pages: 471-490
  • Publisher: 化学同人
• [Book] 二面性ナノカーボンの環境鋭敏構造性,界面の分子科学-界面デザインと界面計測(日本化学会編) (2011)
  • Author(s): 藤森利彦、伊藤努武、金子克美
  • Total Pages: 151-155
  • Publisher: 化学同人
• [Book] 水素貯蔵材料:炭素材料,「水素エネルギー技術の展開(秋葉悦男監修)」 (2010)
  • Author(s): 田中秀樹、金子克美
  • Total Pages: 139-156
  • Publisher: シーエムシー出版
• [Remarks] ホームページにて研究活動を公開している。
  • URL: http://www.shinshu-u.ac.jp/project/encs/