2012 Fiscal Year Final Research Report
Ion intercalation and functionality at Prussian blue interface
Project/Area Number |
21244052
|
Research Category |
Grant-in-Aid for Scientific Research (A)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Condensed matter physics II
|
Research Institution | University of Tsukuba |
Principal Investigator |
|
Co-Investigator(Renkei-kenkyūsha) |
KAMIOKA Hayato 筑波大学, 数理物質系, 助教 (40431671)
|
Project Period (FY) |
2009 – 2012
|
Keywords | プルシャンブルー類似体 / リチウムイオン二次電池 / ナトリウムイオン二次電池 / Cs除染 / 量子ビーム |
Research Abstract |
Prussian blue analogues consists of jungle-gym-type host framework due to covalent bonding between transition metal ion and cyano group and guest alkali ions. We obtained following results: (1) all-solid ion device (2) determination of the ion conduction path (3) ion distribution analysis based on depth-resolved X-ray absorption spectroscopy (4) determination of the Na site (5) excellent cathode properties in lithium-ion secondary battery (6) ultra-rapid discharge process (7) structural and electronic properties against lithium-ion concentration (8) highly-efficient decontamination of radioactive Cesium-ion, and (9) excellent cathode properties in sodium-ion secondary battery. Thus obtained results are far beyond the original proposal.
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Research Products
(37 results)