2011 Fiscal Year Final Research Report
Assembly of Reaction Place by Using High Valent Metal Hydride Complexes
| Project/Area Number |
21245015
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
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| Project Period (FY) |
2009 – 2011
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| Keywords | 金属錯体化学 / ヒドリド錯体 / 金属間結合 / 2核錯体 / 多座配位子 / アリールオキシド錯体 / アニリド錯体 |
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| Research Abstract |
In this project, we have planned to explore the chemistry of high valent metal hydride complexes. The use of aryloxide-derived multidentate supporting ligands allows us to isolate a variety of hydride complexes of early transition metals in high oxidation states. We found that these electron-deficient hydride complexes are capable of activating small molecules. For example, a tantalum hydride complex undergo C-O bond cleavage of CO followed by C-C and C-H bond formation, resulting in formation of an ynolate complex.
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Research Products
(8 results)
