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2011 Fiscal Year Final Research Report

Fabrication of novel tribomaterials and their structure/property studies

Research Project

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Project/Area Number 21245031
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer chemistry
Research InstitutionKyoto University

Principal Investigator

TSUJII Yoshinobu  京都大学, 化学研究所, 教授 (00217308)

Co-Investigator(Kenkyū-buntansha) OHNO Kohji  京都大学, 化学研究所, 准教授 (00335217)
GOTO Atsushi  京都大学, 化学研究所, 准教授 (20335219)
Co-Investigator(Renkei-kenkyūsha) KISHIDA Akio  東京医科歯科大学, 生体材料工学研究所, 教授 (60224929)
Project Period (FY) 2009 – 2011
Keywordsトライボマテリアル / ポリマーブラシ / リビングラジカル重合 / 階層構造 / ソフトマテリアル / ボトルブラシ / ナノファイバー / 潤滑機構
Research Abstract

For developing new soft & wet materials with excellent functions based on the concentrated polymer brush(CPB), we have successfully synthesized thick layers of CPB as well as a variety of building blocks with CPB, controlled their hierarchical structures, and finally demonstrated their excellent lubricating properties. It should be especially noted that we have succeeded in incorporating the CPB effect onto a sheet of cellulosic nanofibers and in achieving novel lubricating as well as mechanical properties, suggesting new material design bio-inspired by the articular cartilage.

  • Research Products

    (17 results)

All 2012 2011 2010 2009 Other

All Journal Article (6 results) (of which Peer Reviewed: 5 results) Presentation (10 results) Remarks (1 results)

  • [Journal Article] Lubrication Mechanism of Concentrated Polymer Brushes in Solvents : Effect of Solvent Viscosity2012

    • Author(s)
      A. Nomura, K. Ohno, T. Fukuda, T. Sato, Y. Tsujii
    • Journal Title

      Polym. Chem

      Volume: 3 Pages: 148-153

    • Peer Reviewed
  • [Journal Article] Controlled Synthesis of Hydrophilic Concentrated Polymer Brushes and Their Friction/Lubrication Properties in Aqueous Solutions2011

    • Author(s)
      A. Nomura, A. Goto, K. Ohno, E. Kayahara, S. Yamago, Y. Tsujii
    • Journal Title

      Polym. Chem.

      Volume: 49 Pages: 5284-5292

    • Peer Reviewed
  • [Journal Article] Lubrication Mechanism of Concentrated Polymer Brushes in Solvents : Effect of Solvent Quality and Thereby Swelling State2011

    • Author(s)
      A. Nomura, K. Okayasu, K. Ohno, T. Fukuda, Y. Tsujii
    • Journal Title

      Macromolecules

      Volume: 44 Pages: 5013-5019

    • Peer Reviewed
  • [Journal Article] Phenols and Carbon Compounds as Efficient Organic Catalysts for Reversible Chain Transfer Catalyzed Living Radical Polymerization(RTCP)2010

    • Author(s)
      A. Goto, N. Hirai, K. Nagasawa, Y. Tsujii, T. Fukuda, H. Kaji
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 7971-7978

    • Peer Reviewed
  • [Journal Article] リビングラジカル重合による精密材料設計2010

    • Author(s)
      辻井敬亘、大野工司
    • Journal Title

      高分子

      Volume: 59 Pages: 420-424

  • [Journal Article] Use of Alcohol as Initiator for Reversible Chain Transfer Catalyzed Polymerization(RTCP)2010

    • Author(s)
      J. Kim, A. Nomura, T. Fukuda, A. Goto, Y. Tsujii
    • Journal Title

      Macromol. React. Eng

      Volume: 4 Pages: 272-277

    • Peer Reviewed
  • [Presentation] 制御ラジカル重合による表面設計-濃厚ポリマーブラシの基礎と応用2012

    • Author(s)
      辻井敬亘
    • Organizer
      接着界面科学研究会第8回例会
    • Place of Presentation
      大阪
    • Year and Date
      2012-03-13
  • [Presentation] 濃厚ポリマーブラシによる表面潤滑制御2011

    • Author(s)
      辻井敬亘
    • Organizer
      第42回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      長野
    • Year and Date
      2011-11-05
  • [Presentation] 高密度グラフト型ゲルの創製と低摩擦材料への応用2011

    • Author(s)
      前田圭史
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-29
  • [Presentation] Novel Tribomaterials Newly Designed/Synthesized by Living Radical Polymerization2011

    • Author(s)
      Y. Tsujii
    • Organizer
      ACS Fall 2011 National Meeting & Exposition
    • Place of Presentation
      USA
    • Year and Date
      2011-08-31
  • [Presentation] ポリマーブラシ付与微粒子の精密設計と機能2011

    • Author(s)
      大野工司
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-26
  • [Presentation] ボトルブラシ型ゲルの精密構造制御と濃厚ブラシ効果2011

    • Author(s)
      中原亮
    • Organizer
      第14回高分子表面研究討論会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-26
  • [Presentation] Entropically driven super-lubrication of concentrated polymer brushes in solvents2010

    • Author(s)
      辻井敬亘
    • Organizer
      International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      USA
    • Year and Date
      2010-12-16
  • [Presentation] リビングラジカル重合によるポリマーブラシの創成と機能2010

    • Author(s)
      辻井敬亘
    • Organizer
      第19回ポリマー材料フォーラム
    • Place of Presentation
      名古屋
    • Year and Date
      2010-12-02
  • [Presentation] New Development of Concentrated Polymer Brushes as Novel Interfaces2009

    • Author(s)
      Y. Tsujii
    • Organizer
      NSYU-KU Bilateral Symposium on Materials Chemistry
    • Place of Presentation
      Taiwan
    • Year and Date
      2009-09-23
  • [Presentation] 高圧原子移動ラジカル重合法による厚膜濃厚ポリマーブラシの合成2009

    • Author(s)
      許書堯
    • Organizer
      第58回高分子学会討論会
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-16
  • [Remarks]

    • URL

      http://www.cpm.kuicr.kyoto-u.ac.jp/

URL: 

Published: 2013-07-31  

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