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2011 Fiscal Year Final Research Report

Removal of phosphorus and boron from molten silicon

Research Project

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Project/Area Number 21246115
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Metal making engineering
Research InstitutionThe University of Tokyo

Principal Investigator

MAEDA Masafumi  東京大学, 生産技術研究所, 教授 (70143386)

Co-Investigator(Kenkyū-buntansha) OKABE Toru  東京大学, 生産技術研究所, 教授 (00280884)
NAGAI Takashi  千葉工業大学, 工学部, 准教授 (40533633)
OKURA Takahiko  東京大学, 生産技術研究所, 特任教授 (00400523)
SASAKI Hideaki  東京大学, 生産技術研究所, 特任助教 (10581746)
Project Period (FY) 2009 – 2011
Keywords高純度化 / 太陽電池 / シリコン
Research Abstract

A process to remove phosphorus and boron from molten silicon was studied in order to produce solar-grade silicon at lower energy cost. Oxygen and water vapor were injected into silicon melted with electron beam under high vacuum. Evaporative removal of phosphorus was enhanced by injection of the reactive gases, and evaporation of oxidized boron was also indicated. The mechanism of the reactions was studied by development of a double Knudsen cell mass spectrometer equipped with a gas-injection apparatus. Evaporated species from Si-P alloys and boron were identified and evaluated quantitatively.

  • Research Products

    (10 results)

All 2013 2012 2011 2010

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (9 results)

  • [Journal Article] Removal Rate of Phosphorus from Molten Silicon2011

    • Author(s)
      T. Kemmotsu, T. Nagai and M. Maeda;
    • Journal Title

      High Temperature Materials and Processes

      Volume: Vol.1-2 Pages: 17-22

    • DOI

      DOI:10.1515/htmp.2011.002

    • Peer Reviewed
  • [Presentation] シリコンからの脱リンのための熱力学2013

    • Author(s)
      永井崇, 山下智司, 前田正史;
    • Organizer
      質量分析学会高温質量分析部会
    • Place of Presentation
      東京
    • Year and Date
      2013-03-11
  • [Presentation] Thermodynamic Study for Removal of Phosphorus from Molten Silicon2012

    • Author(s)
      T. Nagai and M. Maeda
    • Organizer
      The 7th Workshop on Reactive Metal Processing
    • Place of Presentation
      Cambridge, MA, USA.
    • Year and Date
      2012-03-16
  • [Presentation] Thermodynamic Study for Removal of Phosphorus from Molten Silicon2012

    • Author(s)
      Takashi Nagai, Hideaki Sasaki, Masafumi Maeda
    • Organizer
      2012 TMS Annual Meeting & Exhibition
    • Place of Presentation
      Orlando, FL, USA.
    • Year and Date
      2012-03-14
  • [Presentation] シリコンからの脱 リン のための熱力 学2011

    • Author(s)
      永井崇, 前田正史
    • Organizer
      日本金属学会秋季大会
    • Place of Presentation
      沖縄
    • Year and Date
      2011-11-07
  • [Presentation] Removal of Phosphorus from Molten Silicon by Electron Beam Melting Technique2011

    • Author(s)
      Takashi Nagai and Masafumi Maeda
    • Organizer
      European Metallurgical Conference EMC 2011(6th European Metallurgical Conference)
    • Place of Presentation
      Dusseldorf, Germany.
    • Year and Date
      2011-06-28
  • [Presentation] Purification of Silicon by Electron Beam Melting Technique2011

    • Author(s)
      T. Kageyama, T. Nagai and M. Maeda
    • Organizer
      The 6th Workshop on Reactive Metal Processing
    • Place of Presentation
      Pasadena, CA, USA (ポスター発表)
    • Year and Date
      2011-03-17
  • [Presentation] Purification of Silicon by Electron Beam Melting Technique2011

    • Author(s)
      T. Nagai, T. Kageyama and M. Maeda
    • Organizer
      2011 TMS Annual Meeting & Exhibition
    • Place of Presentation
      San Diego, CA, USA.
    • Year and Date
      2011-03-03
  • [Presentation] 電子ビーム溶解法による溶融 Si からの P の 除去2010

    • Author(s)
      永井崇,見持貴之,前田正史;
    • Organizer
      日本金属学会
    • Place of Presentation
      札幌.
    • Year and Date
      2010-09-26
  • [Presentation] 溶融シリコンからの不純物除去2010

    • Author(s)
      景山友喜, 永井 崇, 木村久雄, 前田正史
    • Organizer
      資源・素材学会関東支部, 第7回「資源・素材・環境」技術と研究の交流会
    • Place of Presentation
      東京 (ポスター)
    • Year and Date
      2010-08-02

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Published: 2014-08-29  

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