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2012 Fiscal Year Final Research Report

Study on treatment and disposal form for used uranium catalyst for organic synthesis

Research Project

  • PDF
Project/Area Number 21246143
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Nuclear engineering
Research InstitutionNagoya University

Principal Investigator

ENOKIDA Youichi  名古屋大学, 工学研究科, 教授 (40168795)

Co-Investigator(Kenkyū-buntansha) SAWADA Kayo  名古屋大学, エコトピア科学研究所, 准教授 (90372531)
Project Period (FY) 2009 – 2012
Keywords原子力化学工学 / ウラン廃棄物 / 超臨界流体抽出 / ガラス固化 / アンチモン / 塩化揮発
Research Abstract

For several decades, catalysts containing depleted U and Sb as a composite oxide were used for organic synthesis of acrylonitrile, and the spent catalysts are stored securely as uranium waste in Japan. A safe and economical disposal should be performed in the future. Unfortunately, however, uranium isotopes have long half lives to decay, and chemical and radioactive toxities of several daughter nuclides are too significant to dispose directly in a shallow land. We should take account of chemical toxity of antimony, too. Then we are proposing a method of decontaminating uranium and antimony and vitrifying the spent catalysts into a glass matrix by making use of the SiO2 supports of the catalyst. The goals of our study are recoveries of uranium and antimony with high yields from the tiny pores in sub-microns in diameter of SiO2 supports of the catalysts, and conditioning into a proper waste form for the shallow land disposal. In order to achieve these goals, treatment of the catalysts utilizing phase segregation phenomena of borosilicate glass was proposed and experimentally tested in a laboratory scale using a real specimen of the catalyst. The recovery yields achieved by the experiments were greater than 99.3% for uranium and 97.0% for antimony, and concentrations of uranium and antimony leached with de-ionized water for the final vitrified solids were below the detection limits by inductively coupled plasma spectrometer, 0.1 mg dm^<-3>.

  • Research Products

    (9 results)

All 2013 2011 2010 2009 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (4 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Chlorination of Antimony and Its Volatilization Treatment for Waste Antimony-Uranium Composite Oxide Catalyst2011

    • Author(s)
      K.Sawada, Y.Enokida
    • Journal Title

      Proceedings in Radiochemistry - A Supplement to Radiochimica Acta

      Volume: 1 Pages: 97-100

    • Peer Reviewed
  • [Journal Article] Decontamination of uranium and antimony from the spent catalyst for the Sohio acrylonitrile process2010

    • Author(s)
      Y. Enokida, K. Sawada, H. Sugai
    • Journal Title

      Proceedings of Decommissioning, Decontamination & Reutilization

      Pages: 77-78

    • Peer Reviewed
  • [Journal Article] Decontamination of uranium and antimony from the spent catalyst for acrylonitrile synthesis by utilizing phase segregation of borosilicate glass2010

    • Author(s)
      Y. Enokida, K. Sawada, T. Yamada, H. Sugai
    • Journal Title

      Proceedings of the Waste Management Symposia 2010

      Volume: CD-ROM 38F

    • Peer Reviewed
  • [Presentation] Reaction of Antimony-Uranium Composite Oxide in the Chlorination Treatment of Waste Catalyst2013

    • Author(s)
      K. Sawada. D. Hirabayashi, Y. Enokida
    • Organizer
      廃棄物管理シンポジア 2013, 一般ポスター発表
    • Place of Presentation
      米国 Arizona 州 Phoenix市会議場
    • Year and Date
      2013-02-26
  • [Presentation] Decontamination of uranium and antimony from the spent catalyst for acrylonitrile synthesis by utilizing phase segregation of borosilicate glass2010

    • Author(s)
      Y. Enokida, K. Sawada, T. Yamada, H. Sugai
    • Organizer
      廃棄物管理シンポジア, 一般ポスター発表
    • Place of Presentation
      米国 Arizona 州 Phoenix 市会議場
    • Year and Date
      2010-03-08
  • [Presentation] Chlorination of Antimony and Its Volatilization Treatment for Waste Antimony-Uranium Composite Oxide Catalyst2009

    • Author(s)
      K. Sawada, Y. Enokida
    • Organizer
      放射化学国際会議 APSORC 09, 一般ポスター発表
    • Place of Presentation
      米国 california 州Napa 市会議場, 米国
    • Year and Date
      2009-11-30
  • [Presentation] Treatment and vitrification of spent catalyst for organic synthesis containing uranium and antimony2009

    • Author(s)
      Y. Enokida, T. Yamada, K. Uruga, K. Sawada
    • Organizer
      The R'09 Twin World Congress 一般ポスター発表
    • Place of Presentation
      愛知県名古屋市名古屋大学
    • Year and Date
      2009-09-15
  • [Remarks]

    • URL

      http://www.exrespo.provost.nagoya-u.ac.jp/research/dat/029sawada/sawada.pdfresearch/dat/sawada.pdf

  • [Patent(Industrial Property Rights)] ウラン・アンチモン複合酸化物を含む触媒からのウランの回収を容易にする方法2009

    • Inventor(s)
      榎田洋一,澤田佳代他1名
    • Industrial Property Rights Holder
      名古屋大学,(株)スリー・アール
    • Industrial Property Number
      特願 2009-253466
    • Filing Date
      2009-10-14

URL: 

Published: 2014-08-29  

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