Investigations on multi-phase gas hydrate formations in Lake Baikal

2012 Fiscal Year Final Research Report

• Project/Area Number: 21254006
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 海外学術
• Research Field: Energy engineering
• Research Institution: Kitami Institute of Technology
• Principal Investigator: TAKAHASHI Nobuo 北見工業大学, 工学部, 教授 (20108187)
• Co-Investigator(Renkei-kenkyūsha): SHOJI Hitoshi 北見工業大学, 工学部, 教授 (50201562) ; YAMASHITA Satoshi 北見工業大学, 工学部, 教授 (00174673) ; MINAMI Hirotsugu 北見工業大学, 工学部, 教授 (40241426) ; HACHIKUBO Akihiro 北見工業大学, 工学部, 准教授 (50312450) ; SAKAGAMI Hirotoshi 北見工業大学, 工学部, 助教 (70271757)
• Project Period (FY): 2009 – 2012
• Keywords: 国際研究者交流 / 日本・ロシア・ベルギー / バイカル湖 / メタンハイドレート / メタンシープ / 湖底堆積物 / 溶存ガス / 間隙水化学

Research Abstract

Lake Baikal is the only fresh-water lake in the world where gas hydrates were discovered in the bottom sediments. Twenty-six areas were found forshallow gas hydrate formations near the lake bottom until now. Fifteen of them werefound during the field operations of this study. A wide range of characteristic features on GH composition, gas origin, crystal structure and others have been revealed by thisinvestigation. Shallow gas hydrates were retrieved from 18 mud volcano areas, one pockmark area and 7 methane seep areas.

Research Products

• [Journal Article] Chemical Shift Changes and Line Narrowing in <13>^C NMR Spectra of Hydrocarbon Clathrate Hydrates (2013)
  • Author(s): Kida, Masato; Sakagami, Hirotoshi;Takahashi, Nobuo; Nagao, Jiro
  • Journal Title: J. Phys. A, J. Phys. Chem. A Volume: 117 (20) Pages: 4108-4114
  • DOI: DOI:10.1021/jp312130c
  • Peer Reviewed
• [Journal Article] Gas hydrate of Lake Baikal (2013)
  • Author(s): O. Khlystov, M. De Batist, H. Shoji, A. Hachikubo, S. Nishio, L. Naudts, J. Poort, A. Khabuev, O. Belousov, A. Manakov, G. Kalmychkov
  • Journal Title: Discovery and varieties. Journal of Asian Earth Sciences Volume: 62 Pages: 162-166
  • DOI: doi.org/10.1016/j.jseaes
  • Peer Reviewed
• [Journal Article] 表層型ガスハイドレート賦存海底・湖底地盤から採取した堆積土の土質特性-間隙水溶存ガスの気泡化に伴う堆積土の試料乱れ評価- (2012)
  • Author(s): 山下 聡、出羽寛信、八久保晶弘、南尚嗣、片岡沙都紀、川口貴之、坂上寛敏、高橋信夫、庄子仁
  • Journal Title: 地盤工学ジャーナル Volume: Vol.7,No.4 Pages: 503-516
  • Peer Reviewed
• [Journal Article] Molecular and isotopic composition of hydrate-bound and dissolved gases in the southern basin of Lake Baikal (2012)
  • Author(s): Sakagami, H., N. Takahashi, A. Hachikubo, H. Minami, S. Yamashita, H. Shoji, O. Khlystov, G. Kalmychkov, M. Grachev, M. De Batist
  • Journal Title: based on an improved headspace gas method, Geo-Marine Letters Volume: 32(5-6) Pages: 465-472
  • DOI: doi:10.1007/s00367-012-0294-y
  • Peer Reviewed
• [Journal Article] Raman spectroscopic and calorimetric observations on natural gas hydrates obtained from southern and central Lake Baikal (2012)
  • Author(s): Hachikubo, A., O. Khlystov, M. Kida, H. Sakagami, H. Minami, S. Yamashita, N. Takahashi, H. Shoji, G. Kalmychkov, J. Poort
  • Journal Title: Geo-Marine Letters Volume: 32(5-6) Pages: 419-426
  • DOI: doi:10.1007/s00367-012-0285-z
  • Peer Reviewed
• [Journal Article] Low thermal anomalies associated with double structure gas hydrates in K-2 mud volcano (2012)
  • Author(s): Poort, J., O. M. Khlystov, L. Naudts, A. D. Duchkov, H. Shoji, S. Nishio, M. De Batist, A. Hachikubo, M. Kida, H. Minami, A. Y. Manakov, M. V. Kulikova, A. A. Krylov
  • Journal Title: Lake Baikal, Geo-Marine Letters Volume: 32(5-6) Pages: 407-417
  • DOI: doi:10.1007/s00367-012-0292-0
  • Peer Reviewed
• [Journal Article] <13>^C Chemical Shifts of Propane Molecules Encaged in Structure II Clathrate Hydrate (2011)
  • Author(s): Masato Kida, Akira Hori, Hirotoshi Sakagami, Satoshi Takeya, Yasushi Kamata, Nobuo Takahashi, Takao Ebinuma, and Hideo Narita
  • Journal Title: J. Phys. Chem. A Volume: 115(5) Pages: 643-647
  • DOI: DOI:10.1021/jp106115d
  • Peer Reviewed
• [Journal Article] Dissociation Behavior of Methane-Ethane Mixed Gas Hydrate Coexisting Structures I and II (2010)
  • Author(s): M. Kida, Y. Jin, N. Takahashi, J. Nagao, and H. Narita
  • Journal Title: J. Phys. Chem. A Volume: 114(35) Pages: 9456-9461
  • DOI: DOI:10.1021/jp1055667
  • Peer Reviewed
• [Journal Article] Molecular and isotopic characteristics of gas hydrate-bound hydrocarbons in southern and central Lake Baikal (2010)
  • Author(s): Hachikubo, A., O. Khlystov, A. Krylov, H. Sakagami, H. Minami, Y. Nunokawa, S. Yamashita, N. Takahashi, H. Shoji, S. Nishio, M. Kida, T. Ebinuma, G, Kalmychkov and J. Poort
  • Journal Title: Geo-Marine Letters
  • DOI: DOI:10.1007/s00367-010-0203-1
  • Peer Reviewed
• [Journal Article] Isotopic composition of dissolved inorganic carbon in the subsurface sediments of gas hydrate-bearing mud volcanoes Lake Baikal: Implications for methane and carbonate origin (2010)
  • Author(s): Krylov, A. A., O. M. Khlystov, A. Hachikubo, H. Minami, Y. Nunokawa, H. Shoji, T. I. Zemskaya, L. Naudts, T. V. Pogodaeva, M. Kida, G. V. Kalmychkov and J. Poort
  • Journal Title: Geo-Marine Letters
  • DOI: DOI:10.1007/s00367-010-0190-2
  • Peer Reviewed
• [Journal Article] メタンを含む混合ガスハイドレートのゲスト分子のケージ占有性とガス組成の関係 (2009)
  • Author(s): 木田 真人、坂上 寛敏、高橋 信夫、鎌田 慈、大山 裕之、竹谷 敏、海老沼孝郎、成田英夫
  • Journal Title: 雪氷 Volume: 71(5) Pages: 329-339
  • Peer Reviewed
• [Journal Article] メタン・エタンからなる混合ガスハイドレートの解離熱 (2009)
  • Author(s): 八久保 晶弘、木田 真人、奥田 充、坂上寛敏、庄子仁
  • Journal Title: 雪氷 Volume: 71巻5号 Pages: 341-351
  • Peer Reviewed
• [Journal Article] Characteristics of Natural Gas Hydrates Occurring in Pore-Spaces of Marine Sediments Collected from the Eastern Nankai Trough off Japan (2009)
  • Author(s): Masato Kida, Kiyofumi Suzuki, Taro Kawamura, Hiroyuki Oyama, Jiro Nagao, Takao Ebinuma, Hideo Narita, Hiroyuki Suzuki, Hirotoshi Sakagami and Nobuo Takahashi
  • Journal Title: Energy Fuels Volume: 23(11) Pages: 5580-5586
  • DOI: DOI:10.1021/ef900612f
  • Peer Reviewed
• [Journal Article] Model of formation of double structure gas hydrates in Lake Baikal based on isotopic data (2009)
  • Author(s): Hachikubo, A., O. Khlystov, A. Manakov, M. Kida, A. Krylov, H. Sakagami, H. Minami, N. Takahashi, H. Shoji, G. Kalmychkov, J. Poort
  • Journal Title: Geophysical Research Letters Volume: 36
  • DOI: doi:10.1029/2009GL039805
  • Peer Reviewed
• [Journal Article] Natural gas hydrates with locally different cage occupancies and hydration numbers in Lake Baikal (2009)
  • Author(s): Kida, M., A. Hachikubo, H. Sakagami, H. Minami, A. Krylov, S. Yamashita, N. Takahashi, H. Shoji, O. Khlystov, J. Poort and H. Narita
  • Journal Title: Geochemistry Geophysics Geosystems (G3) Volume: 10(5)
  • DOI: doi:10.1029/2009GC002473
  • Peer Reviewed
• [Journal Article] バイカル湖天然ガスハイドレートのゲストガス同位体比バイカル湖天然ガスハイドレートのゲストガス同位体比 (2009)
  • Author(s): 八久保晶弘、小関貴弘、坂上寛敏、南 尚嗣、山下聡、高橋信夫、庄子 仁、O. Khlystov、J. Poort
  • Journal Title: 月刊地球 Volume: 31(9) Pages: 486-492
• [Journal Article] ガスハイドレート生成時のゲストガス同位体分別～バイカル湖の天然ガスハイドレートの例～ (2009)
  • Author(s): 八久保晶弘、小関貴弘、中畑良紹、坂上寛敏、南 尚嗣、庄子 仁、O. Khlystov
  • Journal Title: 北海道の雪氷 Volume: 第28号 Pages: 61-64
• [Journal Article] メタンハイドレート.雪氷研究の系譜-北海道の雪氷から世界の雪氷圏まで- (2008)
  • Author(s): 庄子 仁、南尚嗣、八久保晶弘
  • Journal Title: 日本雪氷学会北海道支部 Pages: 191-194
• [Presentation] バイカル湖天然ガスハイドレートのゲストガスの多様性 (2011)
  • Author(s): 八久保晶弘、巽和也、坂上寛敏、南尚嗣、山下聡、高橋信夫、庄子仁、O. Khlyst ov、G. Kalmy chkov、M. De Batist
  • Organizer: 雪氷研究大会(2011・長岡) JSSI & JSSE Joint Conference on Snow and Ice Research-2011/Nagaok a
  • Place of Presentation: 長岡市、ハイブ長岡
  • Year and Date: 20110919-23
• [Presentation] バイカル湖南湖盆・中央湖盆の天然ガスハイドレートの水和数 (2011)
  • Author(s): 朝倉武士、八久保晶弘、坂上寛敏、南尚嗣、山下聡、高橋信夫、庄子仁、O. Khlystov、M. De Batist
  • Organizer: 雪氷研究大会(2011・長岡) JSSI & JSSE Joint Conference on Snow and Ice Research-2011/Nagaok a
  • Place of Presentation: 長岡市、ハイブ長岡
  • Year and Date: 20110919-23
• [Presentation] バイカル湖南湖盆・中央湖盆の天然ガスハイドレートの解離熱 (2011)
  • Author(s): 大村聖弥、八久保晶弘、坂上寛敏、南尚嗣、山下聡、高橋信夫、庄子仁、O. Khlystov、M. De Batist
  • Organizer: 雪氷研究大会(2011・長岡) JSSI & JSSE Joint Conference on Snow and Ice Research-2011/Nagaok a
  • Place of Presentation: 長岡市、ハイブ長岡
  • Year and Date: 20110919-23
• [Presentation] Traces of original gas hydrate-forming fluid observed in subsurface gas hydrates retrieved from Lake Baikal (2010)
  • Author(s): Minami, H., Pogodaeva, T., Sakagami, H., Hachikubo, A., Krylov, A., Harada, D., Saito C., Tatsumi K., Hyakutake, K., Yamashita, S., Nishio, S., Takahashi, N., Shoji, H., Khlystov, O., Zemskaya, T., Grachev, M, Naudts, L., H., Poort, J.
  • Organizer: Russia. 10th International Conference on Gas in Marine Sediments, Limnological Institute SB RAS
  • Place of Presentation: Listvyanka (Lake Baikal), Russia
  • Year and Date: 20100906-12
• [Presentation] On board measurement of hydrate-bound and sediment gases at Lake Baikal. 10th International Conference on Gas in Marine Sediments (2010)
  • Author(s): Sakagami, H., Takahashi, N., Hachikubo, A., Minami, H., Yamashita, S., Shoji, H.,Khlystov, O., Kalmychkov, G., Grachev, M, De Batist, M
  • Organizer: Limnological Institute SB RAS
  • Place of Presentation: Listvyanka (Lake Baikal), Russia
  • Year and Date: 20100906-12
• [Presentation] Crystallographic properties of natural gas hydrate in the southern and central Lake Baikal 10th International Conference on Gas in Marine Sediments (2010)
  • Author(s): Hachikubo, A., Khlystov, O., Sakagami, H., Minami, H., Yamashita, S., Takahashi, N., Shoji, H., Kalmychkov, G., Poort, J
  • Organizer: Limnological Institute SB RAS
  • Place of Presentation: Listvyanka (Lake Baikal), Russia
  • Year and Date: 20100906-12
• [Presentation] バイカル湖南湖盆メタンハイドレート含有湖底表層堆積物コア間隙水及びハイドレート水の化学分析 (2010)
  • Author(s): 斉藤 千裕、原田 大資、鈴木 健二、八久保晶弘、坂上寛敏、南 尚嗣、山下 聡、高橋 信夫、庄子仁、O. Khlystov、M. Grachev
  • Organizer: 2010年化学系学協会北海道支部冬季研究発表会
  • Place of Presentation: 北大
  • Year and Date: 20100126-27
• [Presentation] オホーツク海・バイカル湖天然ガスハイドレートのガス組成不均一性 (2009)
  • Author(s): 八久保晶弘、山崎拓哉、奥田 充、坂上寛敏、南 尚嗣、山下 聡、高橋信夫、庄子 仁、Y. K. Jin, A. Obzhirov, O. Khlystov
  • Organizer: 第32回極域気水圏シンポジウム
  • Place of Presentation: 国立極地研究所(立川市)
  • Year and Date: 20091117-18
• [Presentation] ラマン分光法による天然および人工ガスハイドレートの結晶構造推定の試みJSSI & JSSE Joint Conference on Snow and Ice Research -2009/Sappo ro (2009)
  • Author(s): 山崎拓哉、八久保晶弘、奥田 充、坂上寛敏、南 尚嗣、山下 聡、高橋信夫、庄子仁、Oleg Khlystov
  • Organizer: 雪氷研究大会(2009 ・札幌)
  • Place of Presentation: 札幌、北海道大学学術交流会館
  • Year and Date: 20090929-1003
• [Presentation] バイカル湖Goloustnoye Flare の天然ガスハイドレートのゲストガス同位体比JSSI & JSSE Joint Conference on Snow and Ice Research -2009/Sappo ro (2009)
  • Author(s): 中畑良紹、八久保晶弘、小関貴弘、坂上寛敏、南 尚嗣、山下 聡、高橋信夫、庄子仁、Oleg Khlystov
  • Organizer: 雪氷研究大会(2009 ・札幌)
  • Place of Presentation: 札幌、北海道大学学術交流会館
  • Year and Date: 20090929-1003
• [Presentation] バイカル湖天然ガスハイドレートの解離時の解離ガス組成の経時変化JSSI & JSSE Joint Conference on Snow and Ice Research -2009/Sappo ro (2009)
  • Author(s): 遠藤晃人、八久保晶弘、奥田 充、坂上寛敏、南 尚嗣、山下 聡、高橋信夫、庄子仁、Oleg Khlystov
  • Organizer: 雪氷研究大会(2009 ・札幌)
  • Place of Presentation: 札幌、北海道大学学術交流会館
  • Year and Date: 20090929-1003
• [Book] New Energy Resources Research Center, Kitami Institute of Technology, Kitami (2013)
  • Author(s): Minami, H., H. Shoji, O. Khlystov, M. DeBatist, N. Takahashi and M. Grachev
  • Total Pages: 226
  • Publisher: Operation Report of Multi-phase Gas Hydrate Project 2012 (MHP-12), R/V G. U. Vereshchagin Cruise VER-12-03
• [Book] New Energy Resources Research Center, Kitami Institute of Technology, Kitami (2012)
  • Author(s): Shoji, H., O. Khlystov, M. DeBatist, N. Takahashi and M. Grachev
  • Total Pages: 226
  • Publisher: Operation Report of Multi-phase Gas Hydrate Project 2011 (MHP-11), R/V G. U. Vereshchagin Cruise VER-11-01
• [Book] New Energy Resources Research Center, Kitami Institute of Technology, Kitami (2011)
  • Author(s): Shoji, H., O. Khlystov, M. DeBatist, N. Takahashi and M. Grachev
  • Total Pages: 50
  • Publisher: Operation Report of Multi-phase Gas Hydrate Project 2010 (MHP-10), R/V G. U. Vereshchagin Cruise VER-10-03
• [Book] New Energy Resources Research Center, Kitami Institute of Technology, Kitami (2010)
  • Author(s): Shoji, H., O. Khlystov, M. DeBatist, N. Takahashi and M. Grachev
  • Total Pages: 84
  • Publisher: Operation report of multi-phase gas hydrate project 2009 (MHP-09), R/V G. U. Vereshchagin cruise