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2012 Fiscal Year Final Research Report

Creation of Environmentally Friendly Hybrid Thermoelectric MaterialsComposed of Conducting Polymers and Nanoparticles

Research Project

  • PDF
Project/Area Number 21310077
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionTokyo University of Science, Yamaguchi

Principal Investigator

TOSHIMA Naoki  山口東京理科大学, 工学部, 教授 (50011010)

Co-Investigator(Kenkyū-buntansha) HOJO Makoto  山口東京理科大学, 工学部, 教授 (50229150)
ANNO Hiroaki  山口東京理科大学, 工学部, 教授 (60279106)
Co-Investigator(Renkei-kenkyūsha) AKAGI Fumio  山口東京理科大学, 工学部, 助教 (80513126)
Project Period (FY) 2009 – 2012
Keywordsナノ機能材料 / 熱電変換材料
Research Abstract

Hybridization of electroconducting polyaniline with bismuth telluride nanoparticles improved the thermoelectric performance of polyaniline by one order of magnitude. Dispersion of Pt or Au nanoparticles, which are environmentally more friendly than bismuth telluride ones, into polyaniline or PEDOT/PSS enhanced the electrical conductivity of the conducting polymers as well. It was first reported that the dispersion of enough small Au nanoparticles into PEDOT/PSS increased not only electrical conductivity but also Seebeck coefficient. We also succeeded in the preparation of n-type thermoelectric materials composed of polymer complexes although the performance was still low.

  • Research Products

    (42 results)

All 2013 2012 2011 2010 2009 Other

All Journal Article (21 results) (of which Peer Reviewed: 10 results) Presentation (9 results) Book (5 results) Remarks (1 results) Patent(Industrial Property Rights) (6 results)

  • [Journal Article] Thermoelectric Properties and Their Stability of (±)-10-Camphorsulfonic Acid Doped Polyaniline Films on flexible Substrate2013

    • Author(s)
      M. Hokazono, H. Anno, F. Akagi, M. Hojo, N. Toshima
    • Journal Title

      Trans. Materials Research Society of Japan (MRS-J)

      Volume: (in press)

    • Peer Reviewed
  • [Journal Article] Thermoelectric Properties of Polyaniline Films with Different Doping Concentrations of (±)-10-Comphorsulfonic Acid2013

    • Author(s)
      H. Anno, M. Hokaozno, F. Akagi, M. Hojo, N. Toshima
    • Journal Title

      J. Electronic Materials

      Volume: (in press)

    • DOI

      DOI: 10.1007/S11664-012-2368-z

    • Peer Reviewed
  • [Journal Article] Improvement of Thermoelectric Properties of PEDOT/PSS Films with Addition of Gold Nanoparticles: Enhancement of SeebeckCoefficient2013

    • Author(s)
      N. Toshima, N. Jiravanichanun
    • Journal Title

      J. Electronic Materials

      Volume: (in press)

    • DOI

      DOI:10.1007/S11665-012-2458-y

    • Peer Reviewed
  • [Journal Article] Metal Nanoparticles for Energy Conversion2013

    • Author(s)
      N. Toshima
    • Journal Title

      Pure and Applied Chemistry

      Volume: 85(2) Pages: 437-451

    • DOI

      DOI:10.1351/PAC-CON-12-08-17

    • Peer Reviewed
  • [Journal Article] 新熱電変換材料としての導電性高分子2012

    • Author(s)
      戸嶋直樹
    • Journal Title

      パターンダイナミクス紀要

      Volume: 7(1) Pages: 44-50

    • URL

      http://www7a.biglobe.ne.jp/~PatternDynamics/index1.html

  • [Journal Article] 新しい熱電変換材料としての導電性高分子-省エネルギーのための有機エレクトロデバイス-(化学レビュー)2012

    • Author(s)
      戸嶋直樹
    • Journal Title

      化学

      Volume: 67(6) Pages: 37-41

    • URL

      http://www.kagakudojin.co.jp/search/g2271.html

  • [Journal Article] Organic Thermoelectric Materials Composed of Conducting Polymers and Metal Nanoparticles2012

    • Author(s)
      N. Toshima, N. Jiravanichanun, H. Marutani
    • Journal Title

      J. Electronic Materials

      Volume: 41(6) Pages: 1735-1742

    • DOI

      DOI: 10.1007/s11664-012-2041-6

    • Peer Reviewed
  • [Journal Article] ナノによる融合で新分野を!(巻頭言)2011

    • Author(s)
      戸嶋直樹
    • Journal Title

      高分子

      Volume: 60(6) Pages: 373

    • URL

      http://www.spsj.or.jp/

  • [Journal Article] Organic-Inorganic Nanohybrids as Novel Thermoelectric Materials: Hybrids of Polyaniline and Bismuth(III) Telluride Nanoparticles2011

    • Author(s)
      N. Toshima, M. Imai, S. Ichikawa
    • Journal Title

      J. Electronic Materials

      Volume: 40(5) Pages: 56-60

    • DOI

      DOI: 10.1007/s116644-010-1403

    • Peer Reviewed
  • [Journal Article] 有機熱電材料-廃熱利用のための新技術の提案-2011

    • Author(s)
      戸嶋直樹
    • Journal Title

      理大科学フォーラム(化学教養講座)

      Volume: 28(7) Pages: 56-60

    • URL

      http://www.tus.ac.jp/info/publish/kagakuforum/

  • [Journal Article] Polyaniline-Nanoparticle Hybrid Thermoelectric Materials(Hot Topics)2011

    • Author(s)
      N.Toshima
    • Journal Title

      Kobunshi

      Volume: 60(8) Pages: 499

    • URL

      http://www.spsj.or.jp/

  • [Journal Article] 金属ナノ粒子での展開:異分野との交流を通して発展し続ける新分野(私の自慢)2011

    • Author(s)
      戸嶋直樹
    • Journal Title

      化学と工業

      Volume: 64(8) Pages: 622-624

    • URL

      http://www.chemistry.or.jp/

  • [Journal Article] ThermoelectricProperties of Conducting Polaniline/BaTiO3 Nanoparticle Composite Films2011

    • Author(s)
      H. Anno, K. Yamaguchi, T. Nakabayashi, H. Kurokawa, F. Akagi, M. Hojo, N. Toshima
    • Journal Title

      Materials Science and Engineering

      Volume: 18 Pages: 142003

    • DOI

      DOI:10.1088/1757-899X/18/14/142003

    • Peer Reviewed
  • [Journal Article] Thermal Conductivity of Oxide-Nanoparticle-Dispersed Polyaniline Films for Thermoelectric Applications2011

    • Author(s)
      M. Hokazono, H. Anno, K. Yamaguchi, H. Kurokawa, F. Akagi, M. Hojo, N. Toshima
    • Journal Title

      Proceedings of ECO-MATES

      Volume: 2011 Pages: 9-10

    • URL

      http://www.casi.osaka-u.ac.jp/ecomate s2011/

  • [Journal Article] Thermoelectric Properties of ConductingPolyaniline/BaTiO3 Nanoparticle Composite Films2011

    • Author(s)
      H. Anno, K. Yamaguchi, T. Nakabayashi, H. Kurokawa, F. Akagi, M. Hojo, N. Toshima
    • Journal Title

      IOP Conference Series: Materials Science and Engineering

      Volume: 18 Pages: 142003

    • DOI

      DOI:10.1088/1757-899X/18/14/142003

    • Peer Reviewed
  • [Journal Article] ハイブリッド・ナノ粒子の液晶ディスプレイおよび熱電変換材料への展開2011

    • Author(s)
      戸嶋直樹
    • Journal Title

      月刊ディスプレイ

      Volume: 17(3) Pages: 63-70

    • URL

      http://www.techno-times.co.jp/display-latest.htm

  • [Journal Article] 有機熱電変換材料としての導電性高分子の可能性2010

    • Author(s)
      戸嶋直樹
    • Journal Title

      Material Stage

      Volume: 10(1) Pages: 42-45

    • URL

      http://www.gijutu.co.jp/doc/magazine_material%20stage.htm

  • [Journal Article] 有機-無機ハイブリッド熱電変換材料2010

    • Author(s)
      戸嶋直樹
    • Journal Title

      未来材料

      Volume: 10(4) Pages: 38-46

    • URL

      http://www.nts-book.co.jp/

  • [Journal Article] ナノテクノロジーを推進する金属粒子-事始めから最近の展開まで-2010

    • Author(s)
      戸嶋直樹
    • Journal Title

      現代化学

      Volume: 472 Pages: 56-62

    • URL

      http://www.tkd-pbl.com/news/nc243.html

  • [Journal Article] 有機熱電変換材料としての導電性高分子2009

    • Author(s)
      戸嶋直樹
    • Journal Title

      日本熱電学会誌

      Volume: 6(1) Pages: 8-12

    • URL

      http://www.thermoelectrics.jp/

    • Peer Reviewed
  • [Journal Article] Preparation of Conducting Polyaniline-Bismuth Nanoparticle Composites by Planetary Ball Milling2009

    • Author(s)
      H. Anno, M. Fukamoto, Y. Heta, K. Koga, H. Itahara, R. Asahi, R. Satomura, M. Sannomiya, N. Toshima
    • Journal Title

      J. Electronic Materials

      Volume: 38(7) Pages: 1443-1449

    • DOI

      DOI: 10.1007/s11664-009-0786-3

    • Peer Reviewed
  • [Presentation] Metal Nanoparticles for Conversion of Material and Energy2013

    • Author(s)
      N. Toshima
    • Organizer
      MANA Seminar
    • Place of Presentation
      Tsukuba
    • Year and Date
      2013-03-14
  • [Presentation] Metal Nanoparticles for Energy Conversion2012

    • Author(s)
      N. Toshima
    • Organizer
      The 12th Eurasia Conference on Chemical Sciences (EuAsC2S12)
    • Place of Presentation
      Corfu (Greece)
    • Year and Date
      20120416-21
  • [Presentation] Organic ThermoelectricMaterials of Conducting Polymers and TheImprovement of Their Properties by Metal Nanoparticles, Seminar at Department of Energy Conversion and Storage2012

    • Author(s)
      N. Toshima
    • Organizer
      Technical University of Denmark
    • Place of Presentation
      Rokilde (Denmark)
    • Year and Date
      2012-07-06
  • [Presentation] 金属ナノ粒子の構造制御とその有機熱電変換材料への応用2012

    • Author(s)
      戸嶋直樹
    • Organizer
      北海道大学大学院工学研究院材料化学部門主催第9回マテリアルセミナー
    • Place of Presentation
      北海道大学
    • Year and Date
      2012-06-11
  • [Presentation] Conducting Polymers and Their Hybrids with Metal Nanoparticles as Thermoelectric Materials2012

    • Author(s)
      N. Toshima
    • Organizer
      International Workshop on Green Innovation (12th and9th Joint Symposium of Institutes at TokyoUniversity of Science Yamaguchi)
    • Place of Presentation
      Tokyo University of ScienceYamaguchi
    • Year and Date
      2012-03-12
  • [Presentation] Semiconductor Silicon Clathrates for Thermoelectric Application2012

    • Author(s)
      H. Anno
    • Organizer
      International Workshop on GreenInnovation (12th and 9th Joint Symposium of Institutes at Tokyo University of Science Yamaguchi)
    • Place of Presentation
      Tokyo University of Science Yamaguchi
    • Year and Date
      2012-03-12
  • [Presentation] 導電性高分子及びその無機ナノ粒子とのハイブリッド熱電材料2012

    • Author(s)
      戸嶋直樹
    • Organizer
      日本熱電学会第14回研究会
    • Place of Presentation
      阪大吹田コンベンションセンター(大阪)
    • Year and Date
      2012-01-10
  • [Presentation] Structure Control of Metal Nanoparticles and Their Applications to Various Fields2011

    • Author(s)
      N. Toshima
    • Organizer
      Diamond Jubilee Symposium on Recent Trends inChemistry (DJSRTC-2011)
    • Place of Presentation
      Indian Institute of Technology, Kharagpur (India)
    • Year and Date
      20111121-23
  • [Presentation] 熱エネルギーを直接電気に変える熱電発電技術2011

    • Author(s)
      阿武宏明
    • Organizer
      シリーズ先端講演会(第6回)「熱電発電技術の最近の展開とその応用」
    • Place of Presentation
      山口東京理科大学
    • Year and Date
      2011-07-01
  • [Book] 有機電子デバイスのための導電性高分子の物性と評価2012

    • Author(s)
      戸嶋直樹
    • Total Pages
      210-218
    • Publisher
      シーエムシー出版
  • [Book] 熱電材料と製造プロセス技術~熱電学シリーズII~2012

    • Author(s)
      戸嶋直樹
    • Total Pages
      69-84
    • Publisher
      サイエンス&テクノロジー社
  • [Book] PEDOTの材料物性とデバイス応用2012

    • Author(s)
      戸嶋直樹
    • Total Pages
      386-398
    • Publisher
      サイエンス&テクノロジー社
  • [Book] 有機-無機ハイブリッド材料の新展開(新材料・新素材シリーズ)2009

    • Author(s)
      戸嶋直樹
    • Total Pages
      167-176
    • Publisher
      シーエムシー出版
  • [Book] 導電性高分子の応用展開(普及版)(新材料・新素材シリーズ)2009

    • Author(s)
      大野尚典,厳虎,戸嶋直樹
    • Total Pages
      121-128
    • Publisher
      シーエムシー出版
  • [Remarks]

    • URL

      http://www.ed.yama.tus.ac.jp/toshima/

  • [Patent(Industrial Property Rights)] 熱電変換材料及び熱電変換素子2012

    • Inventor(s)
      戸嶋直樹、ジラーワニチャーナン・ ナッター、吉田晃人、市川章子
    • Industrial Property Rights Holder
      学校法人東京理科大学
    • Industrial Property Number
      特許、特願 2012-149662
    • Filing Date
      2012-07-03
  • [Patent(Industrial Property Rights)] ポリピロール類膜、その製造方法およびそれよりなる熱電材料2012

    • Inventor(s)
      戸嶋直樹、厳虎、石田友子
    • Industrial Property Rights Holder
      学校法人東京理科大学
    • Industrial Property Number
      日本国特許登録、特許第4901018号
    • Acquisition Date
      2012-01-13
  • [Patent(Industrial Property Rights)] テルルナノ粒子製造方法及びテルル化 ビスマスナノ粒子の製造方法2011

    • Inventor(s)
      戸嶋直樹、渡邉法久
    • Industrial Property Rights Holder
      学校法人東京理科大学
    • Industrial Property Number
      日本国特許登録、特許第4865210号
    • Acquisition Date
      2011-11-18
  • [Patent(Industrial Property Rights)] ポリアニリン類製膜状物、それを用い た熱電材料2011

    • Inventor(s)
      戸嶋直樹、厳虎、福岡直彦
    • Industrial Property Rights Holder
      ケミプロ化成株式会社
    • Industrial Property Number
      日本国特許登録、特許第4766735号
    • Acquisition Date
      2011-06-24
  • [Patent(Industrial Property Rights)] 有機-無機ハイブリッド熱電材料、当 該熱電材料を用いた熱電変換素子及び有機- 無機ハイブリッド熱電材料の製造方法2010

    • Inventor(s)
      戸嶋直樹、今井将太
    • Industrial Property Rights Holder
      学校法人東京理科大学
    • Industrial Property Number
      特許、特願 2010-123510
    • Filing Date
      2010-05-28
  • [Patent(Industrial Property Rights)] 有機-無機ハイブリッド熱電材料、当 該熱電材料を用いた熱電変換素子及び有機- 無機ハイブリッド熱電材料の製造方法2009

    • Inventor(s)
      戸嶋直樹、今井将太
    • Industrial Property Rights Holder
      学校法人東京理科大学
    • Industrial Property Number
      特許、特願 2009-21281
    • Filing Date
      2009-09-14

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Published: 2014-08-29  

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