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2011 Fiscal Year Final Research Report

Development of vibrational spectroscopy of single molecular junction based on the conductance measurement

Research Project

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Project/Area Number 21340074
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics I
Research InstitutionTokyo Institute of Technology

Principal Investigator

MANABU Kiguchi  東京工業大学, 大学院・理工学研究科, 教授 (70313020)

Project Period (FY) 2009 – 2011
Keywords単一分子伝導 / 振動分光 / 量子化コンダクタンス / 金属ナノワイヤー
Research Abstract

We have developed the measurement system for the vibrational spectroscopy of the single molecular junction. The electron transport properties and atomic configurations of the single benzene, ethylene, acetylene, fullerene molecules bridging between Au, Ag, Cu, Pt electrodes, have been investigated. The conductance of these single molecular junction was about 1Go, which was close to that of the metal atomic contact. We also investigated the electron transport through π-stacked systems using cage molecule.

  • Research Products

    (21 results)

All 2012 2011 2010 2009

All Journal Article (9 results) Presentation (12 results)

  • [Journal Article] Electron transport through single π-conjugated molecules bridging between metal electrode2012

    • Author(s)
      Manabu Kiguchi and Satoshi Kaneko
    • Journal Title

      Chem Phys Chem

      Volume: 13 Pages: 1116-1126

  • [Journal Article] Single Molecule Conductance of π-Conjugated Rotaxane2012

    • Author(s)
      Manabu Kiguchi, Shigeto Nakashima, Tomofumi Tada, Satoshi Watanabe, Susumu Tsuda, Yasushi Tsuji, Jun Terao
    • Journal Title

      New Method for Measuring Stipulated Electric Conductance of π-Conjugated Molecular Wire Using STM Break Junction, Small

      Volume: 8 Pages: 726-730

  • [Journal Article] Electron Transport through Single Molecules Comprising Aromatic Stacks Enclosed in Self-assembled Cages2011

    • Author(s)
      Manabu Kiguchi, Takuya Takahashi, Yuta Takahashi, Yoshihiro Yamauchi, Takashi Murase, Makoto Fujita, Tomofumi Tada, and Satoshi Watanabe.
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: 50 Pages: 5708-5711

  • [Journal Article] Effect of metal-molecule contact on electron-vibration interaction in single hydrogen molecule junction2011

    • Author(s)
      Ryuji Matsushita, Satoshi Kaneko, Tomoka Nakazumi, Manabu Kiguchi
    • Journal Title

      Physical Review B

      Volume: 84 Pages: 245412

  • [Journal Article] Fabrication of the well defined single benzene molecule junction using Ag electrodes2010

    • Author(s)
      Satoshi Kaneko, Tomoka Nakazumi, Manabu Kiguchi
    • Journal Title

      The Journal of Physical Chemistry Letters 1

      Pages: 3520-3523

  • [Journal Article] Formation of a Pd atomic chain in hydrogen atmosphere2010

    • Author(s)
      Manabu Kiguchi, Kunio Hashimoto, Yuriko Ono, Tetsuya Taketsugu, Kei Murakoshi
    • Journal Title

      Physical Review B 81

      Pages: 195401

  • [Journal Article] Formation of Co atomic wire in hydrogen atmosphere2010

    • Author(s)
      Tomoka Nakazumi and Manabu Kiguchi
    • Journal Title

      The Journal of Physical Chemistry Letters 1

      Pages: 923-926

  • [Journal Article] Atomic motion in H_2 and D_2 single-molecule junctions induced by phonon excitation2010

    • Author(s)
      Manabu Kiguchi, Tomoka Nakazumi, Kunio Hashimoto, Kei Murakoshi
    • Journal Title

      Physical Review B 81

      Pages: 045420

  • [Journal Article] Electrical conductance of single C_60 and benzene molecules bridging between Pt electrode2009

    • Author(s)
      Manabu Kiguchi
    • Journal Title

      Applied Physics Letters 95

      Pages: 073301

  • [Presentation] 溶液中における単一分子の電子伝導特性の解明2012

    • Author(s)
      木口学
    • Organizer
      電気化学会
    • Place of Presentation
      浜松
    • Year and Date
      2012-03-30
  • [Presentation] 1次元単分子ワイヤの創成およびその電子伝導特性の解明2012

    • Author(s)
      木口学
    • Organizer
      日本化学会
    • Place of Presentation
      横浜
    • Year and Date
      2012-03-28
  • [Presentation] Recent development of single molecule chemistry2011

    • Author(s)
      Manabu Kiguchi
    • Organizer
      Seminar of regional development and cutting edge technology
    • Place of Presentation
      Wuhan, China
    • Year and Date
      2011-12-10
  • [Presentation] 単一分子の電気伝導度計測の現状と課題2011

    • Author(s)
      木口学
    • Organizer
      高分子学会若手の会交流会
    • Place of Presentation
      つくば
    • Year and Date
      2011-11-21
  • [Presentation] Electron Transport through Single Molecules of Aromatic Stacks Enclosed in Self-assembled Cages2011

    • Author(s)
      Manabu Kiguchi
    • Organizer
      China-Japan Joint Symposium on Current and Future Molecular Electronics
    • Place of Presentation
      Nanjung(China)
    • Year and Date
      2011-10-25
  • [Presentation] Electron transport through single π stacked molecules bridging between metal electrodes2011

    • Author(s)
      M. Kiguchi
    • Organizer
      Colloquia in Department of Chemistry
    • Place of Presentation
      Durham University, Durham (UK)
    • Year and Date
      2011-10-13
  • [Presentation] 単一πスタック分子接合の電子伝導特性2011

    • Author(s)
      木口学,高橋雄太,山内祥弘,村瀬隆史,藤田誠,多田朋史,渡辺聡
    • Organizer
      分子科学会
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-22
  • [Presentation] Electron Transport through Single Molecules of Aromatic Stacks Enclosed in Self-assembled Cages2011

    • Author(s)
      Manabu Kiguchi, Takuya Takahashi, Yuta Takahashi, Yoshihiro Yamauchi, Takashi Murase, Makoto Fujita,Tomofumi Tada
    • Organizer
      Satoshi Watanabe、ECOSS28
    • Place of Presentation
      Wroclaw (Poland)
    • Year and Date
      2011-09-02
  • [Presentation] 分子エレクトロニクスの研究開発・素子設計と応用に向けたポイント2011

    • Author(s)
      木口学
    • Organizer
      情報通信機構5月セミナー
    • Place of Presentation
      東京
    • Year and Date
      2011-05-20
  • [Presentation] 制御された単一分子の新規物性制御2011

    • Author(s)
      木口学
    • Organizer
      新化学技術推進協会電子情報技術部会講演会
    • Place of Presentation
      東京
    • Year and Date
      2011-05-19
  • [Presentation] 単一π共役分子の電子伝導2011

    • Author(s)
      木口学
    • Organizer
      日本化学会
    • Place of Presentation
      横浜
    • Year and Date
      2011-03-11
  • [Presentation] 単一分子の表面科学2011

    • Author(s)
      木口学
    • Organizer
      表面科学会研究会
    • Place of Presentation
      東京
    • Year and Date
      2011-03-09

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Published: 2014-08-29  

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