2011 Fiscal Year Final Research Report
Cooperative phenomenon of molecular assembly confined in coordination polymer and application to the innovative functional materials
| Project/Area Number |
21350012
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Physical chemistry
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| Research Institution | Toyo University (2010-2011)
Osaka University (2009) |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
KAWAJI Hitoshi 東京工業大学, 応用セラミックス研究所, 教授 (10214644)
ISHIMARU Shin' ichi 東京電機大学, 工学部, 教授 (10251034)
MIYAKUBO Keisuke 大阪大学, 総合学術博物館, 准教授 (70263340)
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| Co-Investigator(Renkei-kenkyūsha) |
MIYAKUBO Keisuke 大阪大学, 総合学術博物館, 准教授 (70263340)
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| Project Period (FY) |
2009 – 2011
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| Keywords | 表面・界面 / 固体物性 |
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| Research Abstract |
Zinc-based crystalline coordination polymer [Zn_4O(O_2CC_6H_4CO_2)_3]_n(IRMOF-1) has extremely homogeneous jangle-gym type micropore, and can then accommodate a lot of kinds of guest molecules. In this system, we first found that the molecular assembly confined in the micropore of IRMOF-1 exhibits thermal anomaly. In the present research project, we conducted the heat capacity, NMR, XRD, and electric conductivity measurements in order to reveal the mechanism of thermal anomalies. Furthermore, we also examined the possibility of the development of IRMOF-1 to the innovative functional materials such as solid-state ionics, temperature-responsible battery and so on.
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