2012 Fiscal Year Final Research Report
Ion Cluster Spectroscopy for Chemical Intermediates of Nucleophilic Addition and Substitution Reactions
| Project/Area Number |
21350016
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Physical chemistry
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| Research Institution | Hiroshima University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
EBATA Takayuki 広島大学, 大学院・理学研究科, 教授 (70142924)
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| Project Period (FY) |
2009 – 2012
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| Keywords | クラスター |
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| Research Abstract |
We produced chemical intermediates and/or reaction products of nucleophilic addition and substitution reactions of ions in vacuum. Absorption spectra of these molecular cluster ions in the UV~IR region were measured by mass-selected photodissociation spectroscopy in the gas phase. The structure of these species was determined by analyzing the spectra with the aid of quantum chemical calculations.
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