2011 Fiscal Year Final Research Report
Studies on Paramagnetic Species of Heavier Main Group Elements
| Project/Area Number |
21350023
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | University of Tsukuba |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
SEKIGUCHI Akira 筑波大学, 数理物質系, 教授 (90143164)
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| Project Period (FY) |
2009 – 2011
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| Keywords | 有機典型元素化学 / 構造有機化学 / 常磁性化学種 / 多重項化学種 |
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| Research Abstract |
We succeeded synthesizing and isolating of stable multiplet oligo (silyl radical) s which have two and three silyl radical moieties on 1, 3-positions and 1, 3, 5-positions of benzene ring, respectively. The molecular structures of oligo (silyl radical) s were determined by X-ray crystallography. Furthermore, we also synthesized the silylene cation radicals stabilized by cyclic diaminocarbene coordination, and their molecular structures were determined by X-ray crystallography.
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