2012 Fiscal Year Final Research Report
Study on Cooperative Effect Between Metals of Heterodinuclear Organotransition Metal Complex
| Project/Area Number |
21350034
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Tokyo University of Agriculture and Technology |
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Principal Investigator |
KOMIYA Sanshiro 東京農工大学, 大学院・工学研究院, 教授 (00111667)
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| Project Period (FY) |
2009 – 2012
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| Keywords | ヘテロ二核錯体 / 協同効果 / 遷移金属錯体 / 白金 |
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| Research Abstract |
Series of heterodinuclear complexes having a platinum(palladium)-transition metal bond have been prepared and their chemical and catalytic activities are examined. Reversible organic group transfer, enhance CO-insertion, and regio- and stereo-selective ring-opening desulfurization of S-containing small rings are discovered. On the basis of these results, new catalytic reactions such as carbonylation of thietanes and Markovnikov type hydrometallation of transition metal hydrides are developed and their mechanisms are clarified.
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