2011 Fiscal Year Final Research Report
Design of efficient titanium complex catalyst for e new finctional polyolefins by precise olefin polymerization
| Project/Area Number |
21350054
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Tokyo Metropolitan University (2010-2011)
Nara Institute of Science and Technology (2009) |
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Principal Investigator |
NOMURA Kotohiro 首都大学東京, 大学院・理工学研究科, 教授 (20304165)
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| Project Period (FY) |
2009 – 2011
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| Keywords | 遷移金属錯体触媒 / 精密重合 / チタン錯体触媒 / 配位子設計 / 新規ポリマー |
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| Research Abstract |
A series of nonbridged half-titanocenes containing anionic donor ligands for highly efficient ethylene copolymerizations with various olefins have been designed and presented through this project. New titanium catalysts(Ti-Al hetero-bimetallic complex etc.) that polymerize ethylene without any additional cocatalysts have also been designed and presented.
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