2011 Fiscal Year Final Research Report
Synthesis of functional polyisocyanides using rigid helical structure of the main chain
| Project/Area Number |
21350065
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
OKAMURA Taka-aki 大阪大学, 大学院・理学研究科, 准教授 (90252569)
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| Project Period (FY) |
2009 – 2011
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| Keywords | らせん / ポリイソシアニド / ポリマー / 機能性ポリマー |
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| Research Abstract |
Integration of functional molecules on the rigid helical structure of polyisocyanides leads to new functional polymers. Addition of suitable alkali metal ions to fit into the crown ether of the side chain on the helical polycyanide resulted in the deformation of the helix by electrostatic repulsion. We also found a new method to detect the helical structure by emission spectra.
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Research Products
(12 results)
