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2011 Fiscal Year Final Research Report

Metallocenium Ionic Liquids: Preparation, Electronic Properties, and Chemical Reactivities

Research Project

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Project/Area Number 21350077
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionKobe University

Principal Investigator

MOCHIDA Tomoyuki  神戸大学, 大学院・理学研究科, 教授 (30280580)

Co-Investigator(Kenkyū-buntansha) NISHIO Yutaka  東邦大学, 理学部, 教授 (20172629)
KUWAHARA Daisuke  電気通信大学, 研究設備センター, 准教授 (50270468)
Co-Investigator(Renkei-kenkyūsha) HAYASHI Masahiko  神戸大学, 大学院・理学研究科, 教授 (60192704)
SAITO Toshiaki  東邦大学, 理学部, 教授 (80170512)
KANADANI Chikahide  東邦大学, 理学部, 博士研究員 (70468718)
TAKAHASHI Masashi  東邦大学, 理学部, 教授 (30171523)
Project Period (FY) 2009 – 2011
Keywordsイオン液体 / フェロセン・メタロセン / 相転移 / 磁性
Research Abstract

A series of metal-containing ionic liquids that are based on metallocenium cations were developed. The thermal properties, magnetic properties, and chemical reactivities of these ionic liquids were investigated.

  • Research Products

    (14 results)

All 2012 2011 2010 2009

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (4 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Reactive Half-metallocenium Ionic Liquids that Undergo Solventless Ligand Exchange2012

    • Author(s)
      T. Inagaki, T. Mochida
    • Journal Title

      Chem.Eur. J.

      Volume: 18 Pages: 8070-8075

    • Peer Reviewed
  • [Journal Article] Ionic Liquids of Cationic Sandwich Complexes2012

    • Author(s)
      T. Inagaki, T. Mochida, M. Takahashi, C.Kanadani, T. Saito, D. Kuwahara
    • Journal Title

      Chem. Eur. J

      Volume: 18 Pages: 6795-6804

    • Peer Reviewed
  • [Journal Article] Thermal properties of alkyloctamethyl ferrocenium salts with TFSA and TCNE (TFSA = bis(trifluoromethylsulfonyl) amide; TCNE = tetracyanoethylene)2012

    • Author(s)
      Y. Funasako, K. Abe, T. Mochida
    • Journal Title

      Thermochim. Acta

      Volume: 532 Pages: 78-82

    • Peer Reviewed
  • [Journal Article] Low-Frequency Spectra of Metallocenium Ionic Liquids Studied by Terahertz Time-Domain Spectroscopy2011

    • Author(s)
      A. Chakraborty, T. Inagaki, M. Banno, T.Mochida, K. Tominaga
    • Journal Title

      J. Phys. Chem. A

      Volume: 115 Pages: 1313-1319

    • Peer Reviewed
  • [Journal Article] Assembled Structures and Cation-Anion Interactions in Crystals of Alkyl imidazolium and Alkyltriazolium Iodides with Ferrocenyl Substituents2011

    • Author(s)
      T. Mochida, Y. Miura, F. Shimizu
    • Journal Title

      Cryst. Growth Des

      Volume: 11 Pages: 262-268

    • Peer Reviewed
  • [Journal Article] Magnetic Memory Based on Magnetic Alignment of a Paramagnetic Ionic Liquid near Room Temperature2011

    • Author(s)
      Y. Funasako, T. Mochida, T. Inagaki, T. Sakurai, H. Ohta, K. Furukawa, T. Nakamura
    • Journal Title

      Chem. Commun.

      Volume: 47 Pages: 4475-4477

    • Peer Reviewed
  • [Journal Article] Preparation, Properties, and Crystal Structures of Organometallic Ionic Liquids Comprising 1-Ferrocenyl-3-alkylimida zolium-Based Salts of Bis(trifluoromethane sulfonyl)amide and Hexafluorophosphate2010

    • Author(s)
      Y. Miura, F. Shimizu, T. Mochida
    • Journal Title

      Inorg. Chem.

      Volume: 49 Pages: 10032-10040

    • Peer Reviewed
  • [Journal Article] Metallocenium Ionic Liquids2010

    • Author(s)
      T. Inagaki, T. Mochida
    • Journal Title

      Chem. Lett

      Volume: 39 Pages: 572-573

    • Peer Reviewed
  • [Presentation] Metallocenium Ionic Liquids: From Magnetism to Chemical Reactions2011

    • Author(s)
      T. Mochida
    • Organizer
      The 14th Asian Chemical Congress
    • Place of Presentation
      Bangkok (Thailand)(招待講演)
    • Year and Date
      20110905-08
  • [Presentation] Metallocenium Ionic Liquids: Preparations and Properties2010

    • Author(s)
      T. Inagaki, T. Mochida
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu, Hawaii (USA)
    • Year and Date
      20101215-20
  • [Presentation] Ferrocenium Ionic Liquids: Phase Transitions and Physical Properties2010

    • Author(s)
      Y. Funasako, T. Inagaki, T. Mochida
    • Organizer
      21st IUPAC International Conference on Chemical Thermodynamics
    • Place of Presentation
      Tsukuba, Japan
    • Year and Date
      20100801-06
  • [Presentation] Magnetic Change Coupling with a Solid-Liquid Phase Transformation of Ferrocenium Salts2010

    • Author(s)
      Y. Funasako, T. Inagaki, T. Mochida, T. Sakurai, H. Ohta, K. Furukawa, T. Nakamura
    • Organizer
      International Conference on Science and Technology of Synthetic Metals 2010
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      20100704-09
  • [Patent(Industrial Property Rights)] 新規金属錯体系イオン液体2011

    • Inventor(s)
      持田智行、舟浴佑典
    • Industrial Property Rights Holder
      国立大学法人神戸大学
    • Industrial Property Number
      特許出願 2011-203806
    • Filing Date
      2011-07-16
  • [Patent(Industrial Property Rights)] メタロセン系イオン液体、およびその製造方法2009

    • Inventor(s)
      持田智行、稲垣尭
    • Industrial Property Rights Holder
      国立大学法人神戸大学
    • Industrial Property Number
      特許出願 2009-161175
    • Filing Date
      2009-07-07

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Published: 2014-08-29  

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