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2012 Fiscal Year Final Research Report

Preparation of nano particles of sulfides by solvothermal reactions and development of oxygen reduction catalysts

Research Project

  • PDF
Project/Area Number 21350116
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionKochi University

Principal Investigator

YANAGISAWA Kazumichi  高知大学, 教育研究部総合科学系, 教授 (90145110)

Co-Investigator(Kenkyū-buntansha) KOTSUKI Hiyoshizo  高知大学, 副学長 (80093954)
ONDA Ayumu  高知大学, 教育研究部総合科学系, 講師 (80335918)
Project Period (FY) 2009 – 2012
Keywordsナノ粒子 / 硫化物 / 酸素還元触媒
Research Abstract

It is clarified that mono-dispersed spherical particles consisting of sulfide and carbon are synthesized by solvothermal reactions of metal carbonyls and sulfur in alcohols. For the preparation of oxygen reduction catalysts by solvothermal reactions, the addition of carbon black to the starting materials before the reactions improved the property of the oxygen reduction catalysts. The ruthenium selenide system showed the better catalytic performance than the ruthenium sulfide system.

  • Research Products

    (14 results)

All 2012 2011 2010 2009

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (9 results)

  • [Journal Article] Oxygen Reduction Activity and Methanol Resistance of Ru-based Catalysts Prepared by Solvothermal Reaction2012

    • Author(s)
      C. Zhang, K. Yanagisawa, H. Tao, A. Onda, T. Shou, S. Kamiya
    • Journal Title

      Catal. Lett

      Volume: 142 Pages: 1128-1133

    • DOI

      DOI: 10.1007/s10562-012-0863-8

    • Peer Reviewed
  • [Journal Article] Synthesis and growth mechanism of monodispersed MoS_2 sheets/carbon microspheres2012

    • Author(s)
      H. Tao, K. Yanagisawa, C. Zhang, T. Ueda, A. Onda, N. Li, T. Shou, S. Kamiya, J. Tao
    • Journal Title

      CrystEngComm

      Volume: 14(9) Pages: 3027 - 3032

    • DOI

      DOI: 10.1039/C2CE06543F

    • Peer Reviewed
  • [Journal Article] Solvothermal One-Step Synthesis and Effect of Carbon on Properties of Ruthenium Sulfide Catalysts2011

    • Author(s)
      C. Zhang, K. Yanagisawa, H. Tao, A. Onda, T. Shou, S. Kamiya
    • Journal Title

      Catal. Lett

      Volume: 141 Pages: 1311-1315

    • DOI

      DOI: 10.1007/s10562-011-0628-9

    • Peer Reviewed
  • [Journal Article] Phase controllable synthesis of well crystallized rhodium sulfides by hydrothermal method2009

    • Author(s)
      W. Zhang, K. Yanagisawa, S. Kamiya, T. Shou
    • Journal Title

      Crystal Growth & Design

      Volume: 9(8) Pages: 3765-3770

    • DOI

      DOI:10.1021/cg900454g

    • Peer Reviewed
  • [Journal Article] Solvothermal Synthesis and Phase Control of Nano-sized Rhodium Sulfide Particles2009

    • Author(s)
      W. Zhang, K. Yanagisawa, S. Kamiya, T. Shou
    • Journal Title

      Chemistry Letters

      Volume: 38(3) Pages: 210-211

    • DOI

      DOI:10.1246/cl.2009.210

    • Peer Reviewed
  • [Presentation] Preparation and Oxygen Reduction Reaction of Se-Modified Ru/C Catalyst2012

    • Author(s)
      C. Zhang, K. Yanagisawa, A. Onda
    • Organizer
      セラミックス基礎科学討論会第50回記念大会
    • Place of Presentation
      東京
    • Year and Date
      20120112-13
  • [Presentation] Solvothermal Synthesis of Mono-Dispersed Spherical Particles of Molybdenum Sulfide2011

    • Author(s)
      K. Yanagisawa, H. Tao, T Ueda, A. Onda, N. Li, T. Shou, S. Kamiya
    • Organizer
      The 4th International Symposium on Functional Materials
    • Place of Presentation
      Sendai
    • Year and Date
      20110802-06
  • [Presentation] Effects of synthesis conditions on the oxygen reduction activity of RuxSey catalyst prepared by solvothermal one step synthesis method2011

    • Author(s)
      C. Zhang, K. Yanagisawa, A. Onda, H. Tao, T. Shou, S. Kamiya
    • Organizer
      The 4th International Symposium on Functional Materials
    • Place of Presentation
      Sendai
    • Year and Date
      20110802-06
  • [Presentation] Solvothermal One-step Synthesis and Oxygen Reduction Properties of Ruthenium Chalcogenide Catalysts2011

    • Author(s)
      C. Zhang, H. Tao, A. Onda, K. Yanagisawa,T. Shou, S. Kamiya
    • Organizer
      日本セラミックス協会2011年年会
    • Place of Presentation
      静岡大学
    • Year and Date
      20110316-18
  • [Presentation] Solvothermal Synthesis and Performance Study of Transition Metal Sulfides as Oxygen Reduction Catalysts2010

    • Author(s)
      C. Zhang, H. Tao, A. Onda, K. Yanagisawa, T. Shou, S. Kamiya
    • Organizer
      The 2nd International Solvothermal & Hydrothermal Association (ISHA2010)
    • Place of Presentation
      Beijing, China
    • Year and Date
      20100827-29
  • [Presentation] Synthesis and Growth Mechanism of Monodisperse MoS_2 Sheets/Carbon Nanospheres2010

    • Author(s)
      H.J. Tao, T. Ueda, A. Onda, K. Yanagaisawa, N. Li, T. Shou. T Kamiya
    • Organizer
      Second Joint Seminar between Shaanxi University Science & Technology and Kochi University
    • Place of Presentation
      Xian, China
    • Year and Date
      20100731-0801
  • [Presentation] Solvothermal One-step Synthesis and Oxygen Reduction Properties of Ruthenium Sulfide Catalysts2010

    • Author(s)
      C. Zhang, K. Yanagisawa, H.J. Tao, A. Onda, T. Shou, S. Kamiya
    • Organizer
      Second Joint Seminar between Shaanxi University Science & Technology and Kochi University
    • Place of Presentation
      Xian, China
    • Year and Date
      20100731-0801
  • [Presentation] 溶液法による硫化ロジウム結晶の合成2009

    • Author(s)
      張五星,柳澤和道,神谷純生,庄辰夫
    • Organizer
      日本セラミックス協会第22回秋季シンポジウム
    • Place of Presentation
      愛媛大学
    • Year and Date
      20090916-18
  • [Presentation] Solvothermal Synthesis of Sulfides in Different Organic Solvents2009

    • Author(s)
      K. Yanagisawa, N. Li, H. Tao, W. Zhang, S. Kamiya,T. Shou
    • Organizer
      ICMAT2009 & IUMRS-ICA 2009 (International Conference on Materials for Advanced Technologies & International Unions of Materials Research Society - International Conference in Asia 2009)
    • Place of Presentation
      Singapore
    • Year and Date
      20090628-0703

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Published: 2014-08-29  

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