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2011 Fiscal Year Final Research Report

Novel properties of liquid crystal gels with helical alignment

Research Project

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Project/Area Number 21350123
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionKyoto University

Principal Investigator

URAYAMA Kenji  京都大学, 工学研究科, 准教授 (20263147)

Project Period (FY) 2009 – 2011
Keywords液晶 / エラストマー / ゲル / キラリティ
Research Abstract

Twist nematic elastomers having a 90 degree twist alignment with definite handedness are prepared by chiral imprint method. The twist nematic elastomers exhibit a macroscopic helical form, and the reversal of the handedness is driven by temperature change. In addition, the shape transition between helicoids and spiral ribbons is induced by changing the width/thickness ratio. Cholesteric elastomers are prepared using reactive chiral LC monomers. The cholestric elastomers reflect the left-circularly polarized light with a characteristic wavelength, and the corresponding wavelength is variable by imposed strain.

  • Research Products

    (24 results)

All 2013 2012 2011 2010 2009 Other

All Journal Article (11 results) (of which Peer Reviewed: 9 results) Presentation (10 results) Book (2 results) Remarks (1 results)

  • [Journal Article] Switching Shapes of Nematic Elastomers with Various Director Configurations2013

    • Author(s)
      K. Urayama
    • Journal Title

      React. Funct. Polym

      Volume: 73 Pages: 885

    • DOI

      DOI:10.1016/j.reactfunctpolym. 2012.10.008

    • Peer Reviewed
  • [Journal Article] Memory and Development of Textures of Polydomain Nematic Elastomers2012

    • Author(s)
      H. Higaki, K. Urayama, T. Takigawa
    • Journal Title

      Macromol. Chem. Phys

      Volume: 213 Pages: 1907

    • DOI

      DOI:10.1002/macp.201200239

    • Peer Reviewed
  • [Journal Article] Electro-Opto-Mechanical Effects of Swollen Nematic Elastomers2012

    • Author(s)
      K.Urayama
    • Journal Title

      Adv. Polym. Sci.

      Volume: 250 Pages: 119

    • DOI

      DOI::10.1007/12_2010_107

    • Peer Reviewed
  • [Journal Article] ハイブリッド配向液晶エラストマーの熱屈曲挙動2012

    • Author(s)
      澤芳樹、浦山健治、瀧川敏算、DeSimone,A.,Teresi, L.
    • Journal Title

      日本液晶学会誌

      Volume: 16 Pages: 56

    • URL

      http://jglobal.jst.go.jp/public/20090422/201202248765118556

  • [Journal Article] Large Electromechanical Effect of Isotropic Genesis PolydomainNematic Elastomers2011

    • Author(s)
      T.Okamoto,T.,K.Urayama,T.Takigawa
    • Journal Title

      Soft Matter

      Volume: 7 Pages: 10585

    • DOI

      DOI:10.1039/C1SM06372C

    • Peer Reviewed
  • [Journal Article] Shape Selection of Twist Nematic Elastomer Ribbons2011

    • Author(s)
      Y. Sawa,Y.Fangfu,K.Urayama,T.Takigawa,V.Gimenez-Pinto,R.Selinger,J.Selinger
    • Journal Title

      Proc. Natl. Acad. Sci.

      Volume: 108 Pages: 6364

    • DOI

      DOI:10.1073/pnas.1017658108

    • Peer Reviewed
  • [Journal Article] Temperature responsive bending of nematic elastomers with hybrid molecular alignment2011

    • Author(s)
      Y. Sawa, K. Urayama, T. Takigawa
    • Journal Title

      Mol.Cryst.Liq.Cryst

      Volume: 106 Pages: 549

    • DOI

      DOI:10.1080/15421406.2011.581157

    • Peer Reviewed
  • [Journal Article] Thermally Driven Giant Bending of Liquid Crystal Elastomer Films with Hybrid Alignment2010

    • Author(s)
      Y.Sawa,K.Urayama,T.Takigawa,T.,A.DeSimone,L.Teresi
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 4362

    • DOI

      DOI:10.1021/ma1003979

    • Peer Reviewed
  • [Journal Article] 液晶エラストマー・液晶ゲルの多様な刺激応答特性2010

    • Author(s)
      浦山健治
    • Journal Title

      物性研究

      Volume: 93 Pages: 579

    • URL

      http://hdl.handle.net/2433/169245

  • [Journal Article] Polydomain-Monodomain Transition of Randomly Disordered Nematic Elastomers with Different Cross-Linking Histories2009

    • Author(s)
      K.Urayama,E.Kohmon,M.Kojima,T.Takigawa
    • Journal Title

      Macromolecules

      Volume: 42 Pages: 4084

    • DOI

      DOI:10.1021/ma9004692

    • Peer Reviewed
  • [Journal Article] Electrically driven director-rotation in swollen nematic elastomers as revealed by polarized Fourier transform infrared spectroscopy2009

    • Author(s)
      A. Fukunaga,K.Urayama,P.Koelsch,T.Takigawa
    • Journal Title

      Phys.Rev.E

      Volume: 79 Pages: 051702

    • DOI

      DOI:10.1103/PhysRevE.79.051702

    • Peer Reviewed
  • [Presentation] Shape Selection and Variation of Twist Nematic Elastomer Ribbons2011

    • Author(s)
      K.Urayama
    • Organizer
      KIPS-ESPCI Workshop on Polymer Science
    • Place of Presentation
      京都
    • Year and Date
      2011-11-28
  • [Presentation] ツイスト配向液晶エラストマーリボンの形態の選択性と温度応答性2011

    • Author(s)
      浦山健治
    • Organizer
      2011年高分子討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2011-09-28
  • [Presentation] ツイスト配向液晶エラストマーリボンの形態の選択性と温度依存性2011

    • Author(s)
      浦山健治
    • Organizer
      2011年液晶討論会
    • Place of Presentation
      東京
    • Year and Date
      2011-09-12
  • [Presentation] Shape Selection of Twist Nematic Elastomer Films:Experimental Study2011

    • Author(s)
      K. Urayama
    • Organizer
      The 6th International Liquid Crystal Elastomer Conference
    • Place of Presentation
      Lisbon,Portugal
    • Year and Date
      2011-09-05
  • [Presentation] Deformation and Mesogen Reorientation of Polydomain Nematic Elastomers under Electric Fields2011

    • Author(s)
      K.Urayama
    • Organizer
      The 2011 International Workshop on Physics of Poly-Domain Liquid Crystalline Elastomers
    • Place of Presentation
      Shanghai,China
    • Year and Date
      2011-06-08
  • [Presentation] 液晶/エラストマーハイブリッド材料の刺激応答特性2011

    • Author(s)
      浦山健治
    • Organizer
      ゴム技術フォーラム「ソフトマテリアルの高機能化
    • Place of Presentation
      東京
    • Year and Date
      2011-01-20
  • [Presentation] キラルインプリント法により作製した90度ツイスト配向液晶エラストマーリボンの形態変化と形態選択2010

    • Author(s)
      浦山健治
    • Organizer
      2010年エラストマー討論会
    • Place of Presentation
      京都
    • Year and Date
      2010-12-09
  • [Presentation] Shape Variations of Nematic Elastomer Ribbons with Nonuniform Director Configurations2010

    • Author(s)
      K.Urayama
    • Organizer
      The 23rd International Liquid Crystal Conference
    • Place of Presentation
      Krakow,Poland
    • Year and Date
      2010-07-11
  • [Presentation] Thermal Deformations of Nematic Elastomer Ribbons with Nonuniform Director Configurations2010

    • Author(s)
      K.Urayama
    • Organizer
      The 5th Italian-Japanese Workshop on Liquid Crystals (JILC2010)
    • Place of Presentation
      Cetrano,Italy
    • Year and Date
      2010-07-06
  • [Presentation] 液晶エラストマー・液晶ゲルの多様な外部刺激応答特性2009

    • Author(s)
      浦山健治
    • Organizer
      第19回日本MRS学術シンポジウム
    • Place of Presentation
      横浜
    • Year and Date
      2009-12-09
  • [Book] in Cross-Linked Liquid Crystalline Systems:From Rigid Polymer Networks to Elastomers,Broer,D.,Crawford,G.P.,Zumer,S.,Eds.,Taylor&Francis2011

    • Author(s)
      K. Urayama,T.Takigawa
    • Total Pages
      473-485
    • Publisher
      CRC
  • [Book] CSJ カレントレビュー01:驚異のソフトマテリアル 最新の機能性ゲル研究、第11 章 液晶ゲル2010

    • Author(s)
      浦山健治
    • Total Pages
      117-123
    • Publisher
      化学同人
  • [Remarks]

    • URL

      http://www.cis.kit.ac.jp/urayama/Kenji_Urayama.html

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Published: 2014-08-29  

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