2011 Fiscal Year Final Research Report
Development of a novel organic chemical hydride for COx-free hydrogen storage-transport-production system
| Project/Area Number |
21360377
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Properties in chemical engineering process/Transfer operation/Unit operation
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| Research Institution | Kogakuin University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
AKAMATSU Kazuki 工学院大学, 工学部, 助教 (50451795)
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| Project Period (FY) |
2009 – 2011
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| Keywords | 有機ハイドライド / 水素エネルギー / 膜反応器 / シリカ膜 / 水素キャリア / 自然エネルギー / ディストリビューター / エクストラクター |
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| Research Abstract |
We have successfully developed H_2-distributor-type membrane reactors for hydrogenation of 1-methylnaphtalene. When the membrane reactors were operated with 10mol% of 1-methylnaphtalene solution under 0.8 MPa in H_2 flow side, 0.6 MPa in feed side, and at 250℃, the conversion reached 10% in 2 min of contact time. When using conventional reactors for such hydrogenation reactions, H_2 should be dissolved in the feed solution, which requires high pressure condition such as 2 MPa or more. In this study, we showed that H_2-distributor-type membrane reactors made it possible to carry out the hydrogenation reaction of 1-methylnaphtalene under lower pressure condition.
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