2011 Fiscal Year Final Research Report
Understanding Mechanism of Adsorption-Induced Structure Transition of Metal Organic Frameworks and its Application for Design of New Soft Nanospaces
| Project/Area Number |
21360379
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Properties in chemical engineering process/Transfer operation/Unit operation
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
TANAKA Hideki 京都大学, 工学研究科, 講師 (80376368)
渡邉 哲 京都大学, 工学研究科, 助教 (80402957)
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| Project Period (FY) |
2009 – 2011
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| Keywords | 吸着 / 第三世代柔軟多孔性配位錯体 |
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| Research Abstract |
The Metal-Organic Frameworks(MOF) of the third generation are known to exhibit a steep rise in adsorption isotherm driven by adsorption-induced structure transition, which provides potential applications for gas storage and separation. We succeeded in understanding the mechanism of the adsorption-induced structure transition for the jungle-gym-like and stacked layer MOFs by the free-energy analysis coupled with the molecular simulations.
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