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2011 Fiscal Year Final Research Report

Next-generation high-performance biofuel cell

Research Project

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Project/Area Number 21360388
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionTokyo Institute of Technology

Principal Investigator

YAMAGUCHI Takeo  東京工業大学, 資源化学研究所, 教授 (30272363)

Co-Investigator(Kenkyū-buntansha) ITO Taichi  東京大学, 医学研究科, 准教授 (50447421)
TAMAKI Takanori  東京工業大学, 資源化学研究所, 助教 (80567438)
OHASHI Hidenori  東京工業大学, 資源化学研究所, 助教 (00541179)
Project Period (FY) 2009 – 2011
Keywordsバイオ燃料電池 / レドックスポリマー / 酵素反応 / 失活 / カーボン / グラフト重合 / 表面処理 / 超耐熱性酵素
Research Abstract

Enzymatic biofuel cells have a potential to achieve a high current density of 102 mA/cm2, a value required for portable energy devices, with fuels such as glucose and ethanol. Model calculations have suggested that a high-surface area three-dimensional carbon electrode made of redox-polymer-grafted carbon black can realize the required current density. The main reason of the low current density obtained thus far was the deactivation of enzymes upon adsorption on hydrophobic surface of carbon black. Surface modification of carbon black and the use of hyperthermophilic enzymes are effective in reducing the deactivation of enzymes.

  • Research Products

    (43 results)

All 2012 2011 2010 2009 Other

All Journal Article (14 results) (of which Peer Reviewed: 11 results) Presentation (27 results) Book (2 results)

  • [Journal Article] Physical Reexamination of Parameters on a Molecular Collisions-based Diffusion Model for Diffusivity Prediction in Polymers2011

    • Author(s)
      Hidenori Ohashi, Takanori Tamaki, Takeo Yamaguchi
    • Journal Title

      J. Phys. Chem. B

      Volume: 115(51) Pages: 15181-15187

    • Peer Reviewed
  • [Journal Article] Bio-molecule-Recognition Gating Membrane Using Biomolecular Cross-Linking and Polymer Phase Transition2011

    • Author(s)
      Hidenori Kuroki, Taichi Ito, Hidenori Ohashi, Takanori Tamaki, Takeo Yamaguchi
    • Journal Title

      Anal. Chem.

      Volume: 83(24) Pages: 9226-9229

    • Peer Reviewed
  • [Journal Article] Grafting of Polyelectrolyte on Porous Substrate by Plasma-induced Polymerization2011

    • Author(s)
      Xueqin Chi, Hidenori Ohashi, Takanori Tamaki, Takeo Yamaguchi
    • Journal Title

      J. Photopolym. Sci. Technol.

      Volume: 24(4) Pages: 471-473

    • Peer Reviewed
  • [Journal Article] グルコースを用いた酵素型バイオ燃料電池2011

    • Author(s)
      田巻孝敬, 山口猛央
    • Journal Title

      水素エネルギーシステム

      Volume: 36 Pages: 32-36

  • [Journal Article] 自動車用電池技術における高分子化学の役割2011

    • Author(s)
      山口猛央
    • Journal Title

      高分子

      Volume: 60(8) Pages: 64-65

  • [Journal Article] Evaluation of Immobilized Enzyme in a High-Surface-Area Biofuel Cell Electrode Made of Redox-Polymer-Grafted Carbon Black2010

    • Author(s)
      Takanori Tamaki, Atsushi Hiraide, Faizly B. Asmat, Hidenori Ohashi, Taichi Ito, Takeo Yamaguchi
    • Journal Title

      Ind. Eng. Chem. Res.

      Volume: 49(14) Pages: 6394-6398

    • Peer Reviewed
  • [Journal Article] Isolation and Analysis of a Grafted Polymer onto a Straight Cylindrical Pore in a Thermal-Responsive Gating Membrane and Elucidation of its Permeation Behavior2010

    • Author(s)
      Hidenori Kuroki, Hidenori Ohashi, Takanori Tamaki, Taichi Ito, TakeoYamaguchi
    • Journal Title

      J. Membrane Sci.

      Volume: 352(1-2) Pages: 22-31

    • Peer Reviewed
  • [Journal Article] Reentrant Phase Transition Behavior and Sensitivity Enhancement of a Molecular Recognition Ion Gating Membrane in an Aqueous Ethanol Solution2010

    • Author(s)
      Taichi Ito, Yuhei Oshiba, Hidenori Ohashi, Takanori Tamaki, Takeo Yamaguchi
    • Journal Title

      J. Membrane Sci.

      Volume: 348(1-2) Pages: 369-375

    • Peer Reviewed
  • [Journal Article] Fabrication of Protein Renaturation Facilitating Membrane Using Plasma Graft Pore Filling Technique2010

    • Author(s)
      Hidenori Ohashi, Maiko Watanabe, Taichi Ito, Takanori Tamaki, Takeo Yamaguchi
    • Journal Title

      J. Photopolym. Sci. Technol.

      Volume: 23(4) Pages: 571-573

    • Peer Reviewed
  • [Journal Article] Prediction of Self-Diffusivity in Multicomponent Polymeric Systems Using Shell-Like Free Volume Theory2010

    • Author(s)
      Hidenori Ohashi, Taichi Ito, Takeo Yamaguchi
    • Journal Title

      Ind. Eng. Chem. Res.

      Volume: 49(22) Pages: 11676-11681

    • Peer Reviewed
  • [Journal Article] ガスバリア膜・蒸気透過膜の設計-高分子中での分子拡散理論より-2010

    • Author(s)
      大橋秀伯, 山口猛央
    • Journal Title

      膜

      Volume: 36(2) Pages: 71-78

  • [Journal Article] Modeling of Reaction and Diffusion Processes in High-Surface-Area Biofuel Cell Electrode2009

    • Author(s)
      Takanori Tamaki, Taichi Ito, Takeo Yamaguchi
    • Journal Title

      Fuel Cells

      Volume: 9(1) Pages: 37-43

    • Peer Reviewed
  • [Journal Article] A New Free Volume Theory Based on Microscopic Concept of Molecular Collisions for Penetrant Self-Diffusivity in Polymers2009

    • Author(s)
      Hidenori Ohashi, Taichi Ito, Takeo Yamaguchi
    • Journal Title

      J. Chem. Eng. Jpn.

      Volume: 42(2) Pages: 86-94

    • Peer Reviewed
  • [Journal Article] Development of molecular recognition membrane showing autonomous adsorption-desorption phenomenon2009

    • Author(s)
      Hidenori Ohashi, Toshio Shimada, Takeo Yamaguchi
    • Journal Title

      J. Photo-polym. Sci. Technol.

      Volume: 22(4) Pages: 473-476

    • Peer Reviewed
  • [Presentation] Functionalized membranes inspired from bio-system2012

    • Author(s)
      Takeo Yamaguchi
    • Organizer
      化学工学会第77年会
    • Place of Presentation
      工学院大学,東京【Invited Lecture】
    • Year and Date
      20120315-17
  • [Presentation] membranes and membrane electrode assemblies, CRC International Symposium on Green & sustainable catalysis : fromtheoretical and fundamental aspects to catalyst design2012

    • Author(s)
      Takeo Yamaguchi
    • Organizer
      Systematic material development for PEMFCs catalysts
    • Place of Presentation
      北海道大学,北海道【Invited Lecture】
    • Year and Date
      2012-01-27
  • [Presentation] 機能膜の新展開~分離材料からバイオ材料・エネルギー材料へ~2012

    • Author(s)
      山口猛央
    • Organizer
      高分子学会超分子研究会
    • Place of Presentation
      東京大学,東京【招待講演】
    • Year and Date
      2012-01-23
  • [Presentation] 燃料電池性能向上のための高分子電解質膜とイオン伝導メカニズム2011

    • Author(s)
      山口猛央
    • Organizer
      高分子学会第60回年次大会
    • Place of Presentation
      大阪国際会議場,大阪【招待講演】
    • Year and Date
      20110525-27
  • [Presentation] 細孔フィリング現象と界面伝導現象を利用した次世代燃料電池電解質膜の開発2011

    • Author(s)
      山口猛央
    • Organizer
      高分子学会高分子コロキウム
    • Place of Presentation
      東北大学,宮城【招待講演】
    • Year and Date
      2011-10-28
  • [Presentation] Takanori Tamaki, Tomoharu Sugiyama, Haruki Fujimoto, Hidenori Ohashi, Takeo Yamaguchi2011

    • Author(s)
      Takanori Tamaki, Tomoharu Sugiyama, Haruki Fujimoto, Hidenori Ohashi, Takeo Yamaguchi
    • Organizer
      Minneapolis Convention Center
    • Place of Presentation
      Minneapolis, Minnesota, USA【Invited Speaker Session】
    • Year and Date
      2011-10-20
  • [Presentation] プロトン伝導メカニズムと新規電解質膜2011

    • Author(s)
      山口猛央
    • Organizer
      燃料電池実用化推進協議会燃料電池基盤技術研究懇話会
    • Place of Presentation
      山梨【招待講演】
    • Year and Date
      2011-09-21
  • [Presentation] カーボン微粒子へのグラフト重合によるバイオ燃料電池の開発2011

    • Author(s)
      田巻孝敬
    • Organizer
      2011年度粉体操作に伴う諸現象に関する勉強会
    • Place of Presentation
      倉敷シーサイドホテル,岡山【招待講演】
    • Year and Date
      2011-08-04
  • [Presentation] 革新的材料技術が支える燃料電池自動車の未来2011

    • Author(s)
      山口猛央
    • Organizer
      高分子学会ナノテクノロジー研究会
    • Place of Presentation
      産業技術総合研究所臨海副都心センター,東京【招待講演】
    • Year and Date
      2011-06-23
  • [Presentation] Electrolyte Membranes Using Nano Capping and Pore-Filling Technologies for Next Generation PEFCs2011

    • Author(s)
      Takeo Yamaguchi
    • Organizer
      Korean Chemical Society
    • Place of Presentation
      Jeju, Korea【Invited Lecture】
    • Year and Date
      2011-04-29
  • [Presentation] Pore-Filling Electrolyte Membranes and Interface Proton Transfer Technologies for Next Generation PEFCs2011

    • Author(s)
      Takeo Yamaguchi
    • Organizer
      GIST Seminar
    • Place of Presentation
      Guanju, Korea【Invited Lecture】
    • Year and Date
      2011-04-27
  • [Presentation] High-Surface-Area Enzyme Electrode Made of Redox Polymer Grafted Carbon Black for Biofuel Cell Application2010

    • Author(s)
      Takanori Tamaki, Takeo Yamaguchi
    • Organizer
      2010 AICh EAnnual Meeting
    • Place of Presentation
      Salt Palace Convention Center, Salt Lake City, USA【Invited Speaker Session】
    • Year and Date
      20101107-12
  • [Presentation] Molecular recognition gating membranes inspired bybio-systems, 6th International Symposium On High-Tech Polymer Materials(HTPM-VI) Synthesis2010

    • Author(s)
      Takeo Yamaguchi
    • Organizer
      Characteri-zation And Applications
    • Place of Presentation
      Xiamen, CHINA【Invited Lecture】
    • Year and Date
      20101107-11
  • [Presentation] ミクロ細孔を利用した高分子機能の発現~燃料電池用電解質膜から生体システム発想材料まで~2010

    • Author(s)
      山口猛央
    • Organizer
      第55回高分子学会夏期大学
    • Place of Presentation
      仙台【招待講演】
    • Year and Date
      20100714-16
  • [Presentation] 電池材料およびシステムの革新と未来への期待2010

    • Author(s)
      山口猛央,八尾滋
    • Organizer
      化学工学会第75年会
    • Place of Presentation
      鹿児島大学,鹿児島【依頼講演】
    • Year and Date
      20100318-20
  • [Presentation] Systematic Device Design,分子からデバイスまで2010

    • Author(s)
      山口猛央
    • Organizer
      平成21年度つくば学生研究交流会
    • Place of Presentation
      産業技術総合研究所,茨城【基調講演】
    • Year and Date
      2010-03-12
  • [Presentation] 新エネルギー技術10年の展望と企業戦略の要点2010

    • Author(s)
      山口猛央
    • Organizer
      現代経営技術研究所産業事情検討会
    • Place of Presentation
      東京【招待講演】
    • Year and Date
      2010-01-26
  • [Presentation] Micro pore filling membranes with molecular assembly made by Plasma-Graft Polymerization2009

    • Author(s)
      Takeo Yamaguchi
    • Organizer
      Pre-conference of APSPT-6 : The Sixth Asia-Pacific International Symposium on the Basic and Application of Plasma Technology
    • Place of Presentation
      Taipei, Taiwan【Invited Lecture】
    • Year and Date
      2009-12-12
  • [Presentation] バイオマテリアル創製のための新規プラズマグラフト重合法の開発2009

    • Author(s)
      山口猛央
    • Organizer
      学振153委員会研究発表会
    • Place of Presentation
      郡山【招待講演】
    • Year and Date
      2009-11-27
  • [Presentation] 固体高分子形燃料電池材料のシステム設計と細孔フィリング型電解質膜2009

    • Author(s)
      山口猛央
    • Organizer
      学振151委員会研究発表会
    • Place of Presentation
      東京【招待講演】
    • Year and Date
      2009-11-24
  • [Presentation] Pore Filling Electrolyte Membranes : Water state, Morphology in the Micro Pores and Utilization of Interfaces2009

    • Author(s)
      Takeo Yamaguchi
    • Organizer
      LANL-NEDO-AISTFuel Cell Workshop
    • Place of Presentation
      Palm Springs, USA【Invited Lecture】
    • Year and Date
      2009-11-20
  • [Presentation] 地球温暖化問題のために、我々ができることは?~燃料電池とエコハウス~2009

    • Author(s)
      山口猛央
    • Organizer
      サイエンスアゴラ
    • Place of Presentation
      国際研究交流大学村,東京【招待講演】
    • Year and Date
      2009-10-31
  • [Presentation] 電解質膜における燃料透過阻止・高プロトン伝導性発現のための特異な構造と機構2009

    • Author(s)
      山口猛央
    • Organizer
      高分子学会超分子研究会シンポジウム
    • Place of Presentation
      慶応大学,東京【招待講演】
    • Year and Date
      2009-09-29
  • [Presentation] 地球環境問題と次世代燃料電池材料のシステム設計2009

    • Author(s)
      山口猛央
    • Organizer
      理化学研究所講演会
    • Place of Presentation
      和光,埼玉【招待講演】
    • Year and Date
      2009-07-06
  • [Presentation] 固体高分子形燃料電池の今・未来2009

    • Author(s)
      山口猛央
    • Organizer
      高分子膜セミナー
    • Place of Presentation
      関西大学【招待講演】
    • Year and Date
      2009-06-04
  • [Presentation] バイオ燃料電池2009

    • Author(s)
      山口猛央
    • Organizer
      財団法人協和会
    • Place of Presentation
      衆議院会館,東京【招待講演】
    • Year and Date
      2009-05-15
  • [Presentation] Pore filling electrolyte membranes : Water state, morphology in the micro pores and utilization of interfaces, PBFC2009

    • Author(s)
      Takeo Yamaguchi
    • Organizer
      4th International Conference on Polymer Batteries and Fuel Cells
    • Place of Presentation
      Yokohama Symposia, Kanagawa【InvitedLecture】
  • [Book] バイオ電池の最新動向(執筆分担-第3章6酵素固定多孔質電極)2011

    • Author(s)
      田巻孝敬
    • Total Pages
      90-94
    • Publisher
      シーエムシー出版
  • [Book] バイオ電池の最新動向(執筆分担-第4章4PEFC型バイオ電池)2011

    • Author(s)
      田巻孝敬,山口猛央
    • Total Pages
      123-129
    • Publisher
      シーエムシー出版

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Published: 2013-07-31  

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