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2011 Fiscal Year Final Research Report

Mitigation of Environmental Loading by Establishment of Biorefinery

Research Project

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Project/Area Number 21380198
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Boundary agriculture
Research InstitutionKyoto University

Principal Investigator

SAKA Shiro  京都大学, 大学院・エネルギー科学研究科, 教授 (50205697)

Co-Investigator(Kenkyū-buntansha) KAWAMOTO Haruo  京都大学, エネルギー科学研究科, 准教授 (80224864)
MIYAFUJI Hisashi  京都大学, エネルギー科学研究科, 助教 (00293928)
Research Collaborator YAMAUCHI Kazuchika  京都大学, エネルギー科学研究科, GCOE特定助教 (20467335)
Project Period (FY) 2009 – 2011
Keywordsバイオリファイナリー / 超(亜)臨界流体技術 / フェノール類 / 酢酸メチル / 炭酸ジメチル / バイオマス / バイオケミカルス / バイオ燃料
Research Abstract

With sub/supercritical fluid characteristics, solid biomass was treated with phenols in sub/supercritical conditions to achieve biochemicals and biofuels. In addition, plant oils as liquid biomass were treated with methyl acetate and dimethyl carbonate in their supercritical state to obtain useful biochemicals such as triacetine, glycerol carbonate and citramalic acid as by-products of biodiesel(fatty acid methyl esters). Consequently, it was clarified that supercritical fluid technology can be a useful tool for biorefinery.

  • Research Products

    (37 results)

All 2012 2011 2010 2009 Other

All Journal Article (19 results) (of which Peer Reviewed: 8 results) Presentation (9 results) Book (5 results) Remarks (1 results) Patent(Industrial Property Rights) (3 results) (of which Overseas: 3 results)

  • [Journal Article] Zero-Carbon Energy Kyoto 2011 : Special Edition of Jointed Symposium of Kyoto University Global COE"Energy Science in the Age of Global Warming"and Ajou University BK21 Green Energy and Technology2012

    • Author(s)
      Zul Ilham, Shiro Saka
    • Journal Title

      Green Energy and Technology

      Pages: 127-133

    • DOI

      DOI:10.1007/978-4-431-54067-0_13

    • Peer Reviewed
  • [Journal Article] Conversion of glycerol as by-product from biodiesel production to value-added glycerol carbonate, Zero-Carbon Energy Kyoto 2011 : Special Edition of Jointed Symposium of Kyoto University Global COE"Energy Science in the Age of Global Warming"and Ajou Univ2012

    • Author(s)
      Gaurav Mishra, Shiro Saka
    • Journal Title

      Green Energy and Technology

      Pages: 153-158

    • DOI

      DOI:10.1007/978-4-431-54067-0_17

    • Peer Reviewed
  • [Journal Article] 超臨界流体技術によるバイオディーゼル2012

    • Author(s)
      坂志朗
    • Journal Title

      Jasco Report超臨界最新技術特集第11号実用化技術特集

      Pages: 5-10

  • [Journal Article] Kinetic behavior of liquefaction of Japanese beech in subcritical phenol, Bioresource Technology2011

    • Author(s)
      Gaurav Mishra, Shiro Saka
    • Journal Title

      Bioresource Technology

      Volume: 102(23) Pages: 10946-10950

    • DOI

      DOI:10.1016/j.biortech.2011.08.126

    • Peer Reviewed
  • [Journal Article] 第三世代液体バイオエネルギーの現状と展望2011

    • Author(s)
      坂志朗
    • Journal Title

      ケミカルエンジニヤリング

      Volume: 56(6) Pages: 15-23, 423-431

  • [Journal Article] 廃油脂及び未利用油脂を用いたバイオディーゼル燃料化技術-混相状態での製造課題克服に向けた超臨界流体の魅力2011

    • Author(s)
      坂志朗
    • Journal Title

      混相流

      Volume: 25(2) Pages: 125-134

  • [Journal Article] Glycerol to value-added glycerol carbonate in the two-step non-catalytic supercritical dimethyl carbonate method, Zero-Carbon Energy Kyoto 2010 : Proceedings of the Second International Symposium of Global COE Program"Energy Science in the Age of Global W2011

    • Author(s)
      Zul Ilham, Shiro Saka
    • Journal Title

      Green Energy and Technology

      Pages: 153-158

    • DOI

      DOI:10.1007/978-4-431-53910-0_20

    • Peer Reviewed
  • [Journal Article] Liquefaction behaviors of Japanese beech as treated in subcritical phenol, Zero-Carbon Energy Kyoto 2010 : Proceedings of the Second International Symposium of Global COE Program"Energy Science in the Age of Global Warming-Toward CO2 Zero-emission Energy2011

    • Author(s)
      Gaurav Mishra, Shiro Saka
    • Journal Title

      Green Energy and Technology

      Pages: 147-152

    • DOI

      DOI:10.1007/978-4-431-53910-0_19

    • Peer Reviewed
  • [Journal Article] 木質バイオマス資源からのバイオエタノール生産の課題と展望2011

    • Author(s)
      坂志朗
    • Journal Title

      木科学情報

      Volume: 18(1) Pages: 2-7

  • [Journal Article] Production of biodiesel with glycerol carbonate by non-catalytic supercritical dimethyl carbonate2011

    • Author(s)
      Zul Ilham, Shiro Saka
    • Journal Title

      Lipid Technology

      Volume: 23(1) Pages: 10-13

    • DOI

      DOI:10.1002/lite.201100076

    • Peer Reviewed
  • [Journal Article] 超(亜)臨界水技術によるセルロース系バイオマス変換2011

    • Author(s)
      坂志朗
    • Journal Title

      日本エネルギー学会誌

      Volume: 90(1) Pages: 17-23

  • [Journal Article] バイオ燃料で持続可能な社会は実現できるか2010

    • Author(s)
      坂志朗
    • Journal Title

      環境技術

      Volume: 39(10) Pages: 9-15, 585-591

  • [Journal Article] 超臨界流体技術によるバイオディーゼル燃料の創製2010

    • Author(s)
      坂志朗、服部亮、村上洋司
    • Journal Title

      エネルギー・資源

      Volume: 31(5)通巻183号 Pages: 1-4, 236-239

  • [Journal Article] ポスト化石時代の幕明けバイオマスの利活用期待と課題2010

    • Author(s)
      坂志朗
    • Journal Title

      THE TRC News No

      Volume: 111 Pages: 1-14

  • [Journal Article] New process for catalyst-free biodiesel production using sub critical acetic acid and supercritical methanol2010

    • Author(s)
      Shiro Saka, Yohei Isayama, Zul Ilham, Jiayu Xin
    • Journal Title

      Fuel

      Volume: 89(7) Pages: 1442-1446

    • DOI

      DOI:10.1016/j.fuel.2009.10.018

    • Peer Reviewed
  • [Journal Article] Recent progress of biofuels in Japan2009

    • Author(s)
      Shiro Saka
    • Journal Title

      IEA Task 39 Newsletter

      Volume: 23 Pages: 2-10

  • [Journal Article] A new process for catalyst-free production of biodiesel using supercritical methyl acetate2009

    • Author(s)
      Shiro Saka, Yohei Isayama
    • Journal Title

      Fuel

      Volume: 88(7) Pages: 1307-1313

    • DOI

      DOI:10.1016/j.fuel.2008.12.028

    • Peer Reviewed
  • [Journal Article] バイオエネルギー創製のための環境に優しい新技術2009

    • Author(s)
      坂志朗
    • Journal Title

      Biophilia

      Volume: 5(2) Pages: 45-49

  • [Journal Article] 超臨界流体によるバイオ燃料の先駆的研究2009

    • Author(s)
      坂志朗
    • Journal Title

      日本エネルギー学会誌

      Volume: 88(5) Pages: 362-368

  • [Presentation] 超臨界流体技術によるバイオリファイナリーの構築2012

    • Author(s)
      坂志朗依頼
    • Organizer
      第62回日本木材学会大会研究発表要旨集
    • Place of Presentation
      札幌北海道大学農学部
    • Year and Date
      20120315-17
  • [Presentation] Biorefinery from lignocellulosics as progressed by supercritical fluid science and technology2011

    • Author(s)
      Shiro Saka
    • Organizer
      The 2011 International Symposium on Provide Energy Potential of Biomass
    • Place of Presentation
      Nantou, Taiwan
    • Year and Date
      20110708-10
  • [Presentation] 超臨界流体によるリグノセルロースの化学変換-バイオエタノール、バイオディーゼル、バイオケミカルスなどの生産-2011

    • Author(s)
      坂志朗
    • Organizer
      第10回静岡大学グローバル・サステイナブル・テクノロジー研究会超臨界流体技術グループミーティング
    • Place of Presentation
      京都
    • Year and Date
      2011-03-11
  • [Presentation] Recent progress in biorefinery from lignocellulosics by supercritical fluid science and technology2010

    • Author(s)
      Shiro Saka
    • Organizer
      The 9th Syposium on Development of Supercritical Fluid Technology and Application
    • Place of Presentation
      Taipei
    • Year and Date
      20101013-14
  • [Presentation] Recent progress in biorefinery from lignocellulosics by supercritical fluid science and technology2010

    • Author(s)
      Shiro Saka
    • Organizer
      The 3rd AUN/SEED-Net Regional Conference on New Renewable Energy
    • Place of Presentation
      Vistana Hotel, Penang, Malaysia
    • Year and Date
      20101013-14
  • [Presentation] Recent progress in biorefinery from lignocellulosics as introduced by supercritical fluid science and technology2010

    • Author(s)
      Shiro Saka
    • Organizer
      BIT's 3rd World Congress of Industrial Biotechnology-2010
    • Place of Presentation
      Dalian, China
    • Year and Date
      20100725-27
  • [Presentation] 超臨界流体によるバイオマスの化学変換-バイオエタノール、バイオディーゼル、バイオプラスティック、バイオケミカルスなどの生産-」(財)バイオインダストリー協会(JBA)主催2010

    • Author(s)
      坂志朗
    • Organizer
      未来へのバイオ技術勉強会月例会新しい溶媒(イオン液体/超臨界流体)で生体分子を扱う
    • Place of Presentation
      東京
    • Year and Date
      2010-11-25
  • [Presentation] 木質バイオマスの水熱反応によるバイオリファイナリーの構築NPO法人近畿バイオインダストリー振興会議2010

    • Author(s)
      坂志朗
    • Organizer
      第13回バイオマス研究会
    • Place of Presentation
      大阪
    • Year and Date
      2010-05-10
  • [Presentation] Recent progress in biorefineries from lignocellulosics as introduced by supercritical fluid technologies2009

    • Author(s)
      Shiro Saka
    • Organizer
      SNU Global Research Frontier ship The 3rd Forum-Biofuel and Biorefinery from Lignocellulosics-
    • Place of Presentation
      Seoul National University, Korea
    • Year and Date
      2009-11-13
  • [Book] Effects of various solvent on precipitation of phenolated products from Japanese beech as treated by subcritical phenol,"Zero-Carbon Energy Kyoto 2011 : Special Edition of Jointed Symposium of Kyoto University Global COE "Energy Science in the Age of Glob2012

    • Author(s)
      Gaurav Mishra, Shiro Saka
    • Total Pages
      153-158
    • Publisher
      Springer Japan, Tokyo
  • [Book] 8リグニンの化学変換技術とケミカルス合成、"バイオマスリファイナリー触媒技術の新展開(New Development ofBiomass-refinery CatalyticTechnology)"、市川勝監修2011

    • Author(s)
      坂志朗
    • Total Pages
      243-248
    • Publisher
      シーエムシー出版、東京
  • [Book] 2超臨界流体を用いたバイオマスの処理技術と応用展開、"バイオマスリファイナリー触媒技術の新展開(New Development of Biomass-refinery Catalytic Technology)"、市川勝監修2011

    • Author(s)
      坂志朗
    • Total Pages
      54-61
    • Publisher
      シーエムシー出版、東京
  • [Book] 超臨界流体による細胞壁成分の分離技術、"木質系有機資源の有効利用技術(Effective Technology of Woody Organic Resources)"普及版、舩岡正光監修2010

    • Author(s)
      坂志朗
    • Total Pages
      55-67
    • Publisher
      シーエムシー出版、東京
  • [Book] バイオマスエネルギーの技術革新、"エネルギー・環境・社会現代技術社会論第2版〈京大人気講義シリーズ〉2010

    • Author(s)
      坂志朗
    • Total Pages
      2-15
    • Publisher
      丸善、東京
  • [Remarks]

    • URL

      http://www.ecs.energy.kyoto-u.ac.jp/

  • [Patent(Industrial Property Rights)] 脂肪酸アルキルエステルの製造方法および油脂類の処理方法2011

    • Inventor(s)
      坂志朗、ビンズルキフリールベスズルイルハム
    • Industrial Property Rights Holder
      坂志朗、豊田通商(株)
    • Industrial Property Number
      特許、特願2011-015869
    • Filing Date
      2011-01-28
    • Overseas
  • [Patent(Industrial Property Rights)] 嫌気性微生物を用いた酢酸の製造方法及びバイオエタノールの製造方法2010

    • Inventor(s)
      坂志朗、宮藤久士、小原嘉仁、河本晴雄
    • Industrial Property Rights Holder
      坂志朗
    • Industrial Property Number
      特許、特願2010-193142
    • Filing Date
      2010-08-31
    • Overseas
  • [Patent(Industrial Property Rights)] 有機酸発酵および直接水素化分解によるアルコール類の製造方法2009

    • Inventor(s)
      坂志朗、河本晴雄、宮藤久士、山内一慶、増田昇三、中村陽輔、ナッタノンパイブーンスィルパ、世良豊、冨山茂男、中森研一
    • Industrial Property Rights Holder
      坂志朗、日立造船(株)
    • Industrial Property Number
      特許、特願2009-093607
    • Filing Date
      2009-04-08
    • Overseas

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Published: 2013-07-31   Modified: 2013-10-31  

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