Studies on Solid Catalysts for Green Synthesis of Fine-Chemicals

2011 Fiscal Year Final Research Report

• Project/Area Number: 21510098
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Environmental technology/Environmental materials
• Research Institution: Nagoya Industrial Science Research Institute
• Principal Investigator: SUGI Yoshihiro 財団法人名古屋産業科学研究所, 研究部, 上席研究員 (90281047)
• Co-Investigator(Renkei-kenkyūsha): KOMURA Kenichi 岐阜大学, 工学部, 准教授 (40377685)
• Project Period (FY): 2009 – 2011
• Keywords: グリーンケミストリー / 環境調和性固体触媒

Research Abstract

Mesoporous aluminosilicate with zeolite beta structures(Al-MCM-48-BEA) was synthesized by the dual templates, trimethylcetylammonium bromide for the introduction of mesoporous arrays and tetraethylammonium hydroxide for the introduction of Beta zeolite structure. The material has high hydorothermal and mechanical stabilities due to two-types of pore system : micro-and meso-pores. Vitamin K was synthesized from trimethylquinone and isophytol over Al-MCM-48-BEA in supercritical carbon dioixde.

Research Products

• [Journal Article] The Isopropylation of Diphenyl Ether over H-Mordenite Catalysts (2012)
  • Author(s): Y. Sugi, M. Kamiya,. Tamada, I. Toyama,. S. Tawada, K. Komura, Y. Kubota, C. Anand, A. Vinu
  • Journal Title: J. Mol. Catal. A : Chem. Volume: 355 Pages: 113-122
  • DOI: doi:10.1016/j.molcata.2011.12.004
  • Peer Reviewed
• [Journal Article] Isomerization and Cracking of Hexane over Beta zeolites Synthesized by Dry Gel Conversion Method (2012)
  • Author(s): Pusparatu, Y. Haga, K. Aoyama, K. Komura, Y. Kubota, Y. Nishimura, Y. Sugi
  • Journal Title: J. Jpn. Pterol. Inst Volume: 55 Pages: 120-131
  • DOI: doi:10.1627/jpi.55.120.
  • Peer Reviewed
• [Journal Article] Isopropylation of Naphthalene over H-Mordenite, H-Y, and H-Beta Zeolites : Roles of Isopropylnaphthalene Isomers (2011)
  • Author(s): Y. Sugi, Y. Hasegawa, H. Tamada, K. Komura, Y. Kubota, J.-H. Kim
  • Journal Title: Korean J. Chem. Eng. Volume: 28
  • DOI: doi:10.1007/s11814-010-0382-5
  • Peer Reviewed
• [Journal Article] Lanthanoid Exchanged Mordenites as Catalysts for the Isopropylation of Biphenyl (2011)
  • Author(s): Y. Sugi, S. Watanabe, H. Naiki, K. Komura
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 84 Pages: 660-666
  • DOI: doi:10.1246/bcsj.20110115
  • Peer Reviewed
• [Journal Article] Cesium Carbonate Supported on Alumina for the Michael Addition of Diethyl Malonate to Methyl Acrylates (2011)
  • Author(s): T. Hida, K. Komura, Y. Sugi
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 84 Pages: 960-967
  • DOI: doi:10.1246/bcsj.20110022
  • Peer Reviewed
• [Journal Article] Shape-Selective Isopropylation of Aromatic Hydrocarbons over H-Mordenite in Supercritical Carbon Dioxide Medium (2011)
  • Author(s): S. C. Laha, H. Naiki, K. Komura, Y. Sugi
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 84 Pages: 1283-1290
  • DOI: doi:10.1246/bcsj.20110214
  • Peer Reviewed
• [Journal Article] SSZ-60 : Synthetic Investigation and Catalytic Application to the Alkylation of Biphenyl and Naphthalene (2011)
  • Author(s): H. Naiki, K. Komura, J.-H. Kim, G. Seo, Y. Sugi
  • Journal Title: Micropor. Mesopor. Mater. Volume: 84 Pages: 383-391
  • DOI: doi:10.1016/j.micromeso.2011.03.023
  • Peer Reviewed
• [Journal Article] Preparation of[Fe]-SSZ-24 through the Isomorphous Substitution of[B]-SSZ-24 with Iron, and Its Catalytic Properties in the Isopropylation of Biphenyl (2011)
  • Author(s): H. Kawagoe, K. Komura, J.-H. Kim, G. Seo, Y. Sugi
  • Journal Title: J. Mol. Catal. A : Chem. Volume: 143 Pages: 1-8
  • DOI: doi:10.1016/j.molcata.2011.08.027
  • Peer Reviewed
• [Journal Article] Isopropylation of Naphthalene over H-Mordenite, H-Y, and H-Beta Zeolites : Roles of Isopropyl-Naphthalene Isomers (2011)
  • Author(s): Y. Sugi, Y. Hasegawa, H. Tamada, K. Komura, Y. Kubota, J.-H. Kim
  • Journal Title: Korean J. Chem. Eng. Volume: 28 Pages: 409-417
  • DOI: doi:10.1007/s11814-010-0382-5
  • Peer Reviewed
• [Journal Article] Highly Stable Aluminosilicates with a Dual Pore System : Simultaneous Formation of Meso-and Microporosities with Zeolitic BEA Building Units (2010)
  • Author(s): S. C. Laha, C. Venkatesan, A. Sakthivel, K. Komura, T.-H. Kim, S.-J. Cho, S.-J. Huang, P.-H. Wu, S.-B. Liu, Y. Sasaki, M. Kobayashi, Y. Sugi
  • Journal Title: Micropor. Mespor. Mater. Volume: 133 Pages: 82-90
  • DOI: doi:10.1016/j.micromeso.2010.04.018
  • Peer Reviewed
• [Journal Article] Alkylation of Biphenyl and Naphthalene over Zeolites. Nature of Shape-selective Catalysis in Zeolite Channels (2010)
  • Author(s): Y. Sugi
  • Journal Title: J. Jpn. Petrol. Inst. Volume: 53 Pages: 263-275
  • DOI: doi:10.1627/jpi.55.120
  • Peer Reviewed
• [Journal Article] Convenient Synthesis of Mesoporous Aluminosilicates by Using Pre-Heated Sodium Aluminosilicate Gel (2010)
  • Author(s): K. Komura, Y. Tsuchiya, C. Venkatesan, S. C. Laha, Y. Sasaki, M. Kobayashi, Y. Sugi
  • Journal Title: Top. Catal. Volume: 53 Pages: 529-534
  • DOI: doi:10.1007/s11244-010-9482-z
  • Peer Reviewed
• [Journal Article] Shape-Selective Alkylation of Naphthalene over Zeolites : Steric Interaction of Reagents with Zeolites (2010)
  • Author(s): Y. Sugi
  • Journal Title: J. Chin. Chem. Soc. Volume: 57 Pages: 1-13
  • Peer Reviewed
• [Journal Article] Calcium-Incorporated Mesoporous Aluminosilicates : Synthesis, Characterization, and Applications to the Condensation of Long-Chain Fatty Acid with Long-Chain Amine and Alcohol (2010)
  • Author(s): A. Sakthivel, K. Komura, S.-J. Huang, P.-H. Wu, S.-B. Liu, Y. Sasaki, Y. Sugi
  • Journal Title: Ind. Eng. Chem. Res. Volume: 49 Pages: 65-71
  • DOI: DOI:10.1021/ie900641u
  • Peer Reviewed
• [Journal Article] Structure Determination of H-LDS : An Acidified Form of the Layered Silicate K-LDS (2010)
  • Author(s): T. Ikeda, M. Uenaka, K. Komura, Y. Sugi
  • Journal Title: Chem. Lett. Volume: 39 Pages: 747-748
  • DOI: doi:10.1246/cl.2010.747
  • Peer Reviewed
• [Journal Article] Synthesis of Boron-containing CDS-1 Zeolite by Topotactic Dehydration Condensation of[B]-PLS-1 Prepared from Layered Silicate H-LDS (2010)
  • Author(s): K. Komura, T. Murase, Y. Sugi, M. Koketsu
  • Journal Title: Chem. Lett. Volume: 39 Pages: 948-949
  • DOI: doi:10.1007/s11244-010-9477-9
  • Peer Reviewed
• [Journal Article] Further Investigations on the Promoting Effect of Mesoporous Silica on Base-Catalyzed Aldol Reaction (2010)
  • Author(s): Y. Kubota, H. Yamaguchi, T. Yamada, S. Inagaki, Y. Sugi, T. Tatsumi
  • Journal Title: Top. Catal. Volume: 53 Pages: 492-499
  • DOI: doi:10.1007/s11244-010-9482-z
  • Peer Reviewed
• [Journal Article] Convenient Synthesis of Mesoporous Aluminosilicates by Using Pre-heated Sodium Aluminosilicate Gel (2010)
  • Author(s): K. Komura, Y. Tsuchiya, C. Venkatesan, S. C. Laha, Y. Sasaki, M. Kobayashi, Y. Sugi
  • Journal Title: Top. Catal. Volume: 53 Pages: 529-534
  • DOI: doi:10.1007/s11244-010-9477-9
  • Peer Reviewed
• [Journal Article] H-Y zeolite Is a Versatile Heterogeneous Catalyst for the Synthesis ofβ-Nitroamines (2010)
  • Author(s): K. Komura, Y. Taninaka, Y. Ohtaki, Y. Sugi
  • Journal Title: Appl. Catal. A : Gen. Volume: 388 Pages: 211-215
  • DOI: doi:10.1016/j.apcata.2010.08.054
  • Peer Reviewed
• [Journal Article] Highly Stable Mesoporous Aluminosilicates with a Dual Pore System : Simultaneous Formation of Mesophase with Zeolitic Building Units (2009)
  • Author(s): S. C. Laha, A. Sakthivel, K. Komura, S.-J. Huang, P.-H. Wu, S.-B. Liu, Y. Sasaki, M. Kobayashi, Y. Sugi
  • Journal Title: Chem. Lett Volume: 38 Pages: 548-549
  • DOI: doi:10.1246/cl.2009.548
  • Peer Reviewed
• [Journal Article] The Isomerization of 4, 4'-Diisopropylbiphenyl at External Acid Sites in the Isopropylation of Biphenyl over H-Mordenites (2009)
  • Author(s): Y. Sugi, I. Toyama, H. Tamada, S. Tawada, K. Komura, Y. Kubota
  • Journal Title: J. Mol. Catal. A : Chem Volume: 304 Pages: 22-27
  • DOI: doi:10.1016/j.molcata.2009.01.018
  • Peer Reviewed
• [Journal Article] The Alkylation of Naphthalene over MCM-68 with MSE Topology (2009)
  • Author(s): T. Shibata, S. Suzuki, H. Maekawa, K. Komura, Y. Kubota, Y. Sugi
  • Journal Title: J. Mol. Catal. A : Chem Volume: 297 Pages: 80-85
  • DOI: doi:10.1016/j.molcata.2008.09.016
  • Peer Reviewed
• [Journal Article] Theβ-Zeolite Synthesized by Dry-gel Conversion Method without the Use of Sodium Hydroxide : Characterization and Catalytic Behaviors (2009)
  • Author(s): A. Sakthivel, A. Iida, K. Komura, Y. Sugi
  • Journal Title: J. Nanosci. Nanotechnol. Volume: 9 Pages: 475-483
  • DOI: doi:10.1166/jnn.2009.J073
  • Peer Reviewed
• [Journal Article] Nano-sizedβ-Zeolites with Tunable Particle Sizes : Synthesis by DGC Method in the Presence of Surfactants, Characterization, and Catalytic Properties (2009)
  • Author(s): A. Sakthivel, A. Iida, K. Komura, Y. Sugi, K. V. R. Chary
  • Journal Title: Micorpor. Mesopor. Mater Volume: 119 Pages: 322-330
  • DOI: doi:10.1016/j.micromeso.2008.10.034
  • Peer Reviewed
• [Journal Article] Na-Y Zeolite as a Highly Active Catalyst for the Hydroamination ofα,β-Unsaturated Compounds with Aromatic Amines (2009)
  • Author(s): K. Komura, R. Hongo, J. Tsutsui, Y. Sugi
  • Journal Title: Catal. Lett. Volume: 128 Pages: 203-209
  • DOI: doi:10.1007/s10562-008-9738-4
  • Peer Reviewed
• [Journal Article] Strong Acids as Catalysts for the Chloromethylation of m-Xylene. Environmentally Conscious Synthesis of 1, 3-bis(Chloromethyl)-4, 6-dimethylbenzene (2009)
  • Author(s): T. Kishida, N. Ieda, T. Yamauchi, K. Komura, Y. Sugi
  • Journal Title: Ind. Eng. Chem. Res. Volume: 48 Pages: 1831-1839
  • DOI: doi:10.1021/ie8014022
  • Peer Reviewed
• [Journal Article] グリーン化学を実現する触 (2009)
  • Author(s): 杉義弘
  • Journal Title: SE(セイフティエンジニアリング) Volume: 37 Pages: 4-9
  • Peer Reviewed
• [Journal Article] ゼオライトの形状選択性-ビフェニル及びナフタレンのアルキル化を例として (2009)
  • Author(s): 杉義弘
  • Journal Title: ゼオライト Volume: 26 Pages: 98-107
  • Peer Reviewed
• [Journal Article] ナフタレンのアルキル化におけるゼオライトの形状選択性 (2009)
  • Author(s): 杉義弘
  • Journal Title: ペトロテック Volume: 38 Pages: 608-612
  • Peer Reviewed
• [Presentation] Synthesis of[Al]-SSZ-60 and Its Catalytic Properties in Alkylation of Biphenyl (2011)
  • Author(s): H. Naiki, K. Komura, Y. Sugi
  • Organizer: Valencia Convention Center
  • Place of Presentation: Valencia, Spain
  • Year and Date: 2011-07-04
• [Presentation] SSZ-60 : Synthesis and Catalytic Properties in the Alkylation of Biphenyl and Naphthalene (2010)
  • Author(s): H. Naiki, K. Komura, Y. Sugi
  • Organizer: The International Chemical Congress of Pacific Basin Societies
  • Place of Presentation: Hawaii Convention Center
  • Year and Date: 2010-12-17
• [Presentation] Synthesis of SSZ-60 and Catalytic Properties in the Alkylation of Biphenyl and Naphthalene (2010)
  • Author(s): H. Naiki, K. Komura, Y. Sugi
  • Organizer: Sixth Tokyo Conference on Advanced Catalytic Science and Technology & Fifth Asia Pacific Congress on Catalysis
  • Place of Presentation: 札幌コンベンションセンター
  • Year and Date: 2010-07-20
• [Presentation] Highly Stable Mesoporous Aluminosilicates with Dual Pore System : Simultaneous Formation of Mesophase with Zeolitic Building Units (2010)
  • Author(s): S. C. Laha, C. Venkatesen, A. Sakthivel, K. Komura, S.-J. Huang, P.-H. Wu, S.-B. Liu, Y. Sasaki, M. Kobayashi, Y. Sugi
  • Organizer: 16th International Zeolite Conference & 7th International Mesostructured Materials Symposium
  • Place of Presentation: Hilton Sorrento Palace
  • Year and Date: 2010-07-05
• [Presentation] Deactivation of Acid Sites on External Surface of Mordenites with Rare-earth Metal Oxides in the Isopropylation of Biphenyl (2009)
  • Author(s): Y. Sugi, S. Tawada, S. Noda, I. Toyama, S. Watanabe, K. Komura, Y. Kubota, K. Nakajima, T. Matsuzaki, T. Hanaoka, J.-H. Kim, G. Seo
  • Organizer: The 12th Japan-Korea Symposium on Catalysis
  • Place of Presentation: 秋田キャスルホテル
  • Year and Date: 2009-10-16
• [Presentation] Convenient Synthesis of Mesoporous Aluminosilicate by using Pre-heated Sodium Aluminosilicate gel (2009)
  • Author(s): K. Komura, Y. Tsuchiya, C. Venkatesan, S. C. Laha, Y. Sasaki, M. Kobayashi, Y. Sugi
  • Organizer: The 12th Japan-Korea Symposium on Catalysis
  • Place of Presentation: 秋田キャスルホテル
  • Year and Date: 2009-10-15
• [Presentation] ゼオライトの形状選択性-多環芳香族炭化水素のアルキル化を例として- (2009)
  • Author(s): 杉義弘
  • Organizer: 石油学会第52回年会学会賞受賞講演
  • Year and Date: 2009-05-20
• [Patent(Industrial Property Rights)] 高性能シリカメソ多孔体薄膜の製造方法 (2011)
  • Inventor(s): 杉本憲昭,後藤康友,中村忠司,福島喜章,杉義弘,窪田好裕
  • Industrial Property Rights Holder: 豊田中央研究所
  • Industrial Property Number: 特許、4524822
  • Acquisition Date: 2011-06-11