• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2011 Fiscal Year Final Research Report

Structure analysis of porous coordination polymers with flexible framework by X-ray powder diffraction.

Research Project

  • PDF
Project/Area Number 21510107
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanostructural science
Research InstitutionOsaka Prefecture University

Principal Investigator

KUBOTA Yoshiki  大阪府立大学, 理学系・研究科, 准教授 (50254371)

Project Period (FY) 2009 – 2011
Keywordsナノ材料 / 多孔性材料 / ガス吸着 / 放射光粉末回折 / 精密電子密度解析
Research Abstract

This study revealed the structural change in the gas adsorption process of porous coordination polymers(PCP) with flexible framework by the synchrotron powder diffraction method. It was found that a certain PCP with reporter molecules in the nanopore transformed its framework from lozenge shape to square shape with increasing the amount of adsorbate CO_2.The structure of reporter molecule in the nanopore also deformed in sync with it emitting a blue light. As a result this material was found to play role as a CO_2 sensor.

  • Research Products

    (24 results)

All 2011 2010 2009

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (14 results)

  • [Journal Article] Gas detection by structural variations of fluorescent guest molecules in a flexible porous coordination polymer2011

    • Author(s)
      Nobuhiro Yanai, Koji Kitayama, Yuh Hijikata, Hiroshi Sato, Ryotaro Matsuda, Yoshiki Kubota, Masaki Takata, Motohiro Mizuno, Takashi Uemura, Susumu Kitagawa
    • Journal Title

      Nature Mater

      Volume: 10 Pages: 787-793

    • Peer Reviewed
  • [Journal Article] Crystallization of the chalcogenide compound Sb_8Te_32011

    • Author(s)
      Kouichi Kifune, Tomoko Fujita, Yoshiki Kubota, Noboru Yamada, Toshiyuki Matsunaga
    • Journal Title

      Acta Cryst. B

      Volume: 67 Pages: 381-385

    • Peer Reviewed
  • [Journal Article] Control of Interpenetration for Tuning Structural Flexibility Impacts on Sorption Properties2010

    • Author(s)
      Sareeya Bureekaew, Hiroshi Sato, Ryotaro Matsuda, Yoshiki Kubota, Raita Hirose, Jungeun Kim, Kenichi Kato, Masaki Takata, Susumu Kitagawa
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: 49 Pages: 7660-7664

    • Peer Reviewed
  • [Journal Article] Structural investigation of GeSb_6Te_<10> and GeBi_6Te_<10> intermetallic compounds in the chalcogenide homologous series2010

    • Author(s)
      Toshiyuki Matsunaga, Rie Kojima, Noboru Yamada, Tomoko Fujita, Kouichi Kifune, Yoshiki Kubota, Masaki Takata
    • Journal Title

      Acta Cryst. B

      Volume: 66 Pages: 407-411

    • Peer Reviewed
  • [Journal Article] Temperature responsive channel uniformity impacts on highly guest-selective adsorption in a porous coordination polymer2010

    • Author(s)
      Ryotaro Matsuda, Takashi Tsujino, Hiroshi Sato, Yoshiki Kubota, Kunimitsu Morishige, Masaki Takata
    • Journal Title

      Susumu Kitagawa, Chem. Sci

      Volume: 1 Pages: 315-321

    • Peer Reviewed
  • [Journal Article] Selective sorption of oxygen and nitric oxide by an electron-donating flexible porous coordination polymer2010

    • Author(s)
      Satoru Shimomura, Masakazu Higuchi, Ryotaro Matsuda, Ko Yoneda, Yuh Hijikata, Yoshiki Kubota, Yoshimi Mita, Jungeun Kim, Masaki Takata, Susumu Kitagawa
    • Journal Title

      Nature Chem

      Volume: 2 Pages: 633-637

    • Peer Reviewed
  • [Journal Article] Solid Solutions of Soft Porous Coordination Polymers : Fine-Tuning of Gas Adsorption Properties2010

    • Author(s)
      Tomohiro Fukushima, Satoshi Horike, Yasutaka Inubushi, Keiji Nakagawa, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: 49 Pages: 4820-4824

    • Peer Reviewed
  • [Journal Article] Systematic Construction of Porous Coordination Pillared-Layer Structures and Their Sorption Properties2010

    • Author(s)
      Hirotoshi Sakamoto, Ryo Kitaura, Ryotaro Matsuda, Susumu Kitagawa, Yoshiki Kubota, Masaki Takata
    • Journal Title

      Chem. Lett

      Volume: 39 Pages: 218-219

    • Peer Reviewed
  • [Journal Article] Incommensurate guest adsorption in bellows-shaped one-dimensional channels of porous coordination polymers2010

    • Author(s)
      Ryotaro Matsuda, Ryo Kitaura, Yoshiki Kubota, Tatsuo C. Kobayashi, Masaki Takata, Susumu Kitagawa
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 129 Pages: 296-303

    • Peer Reviewed
  • [Journal Article] Porous Coordination Polymer with Pyridinium Cationic Surface,[Zn_2(tpa)_2(cpb)]2009

    • Author(s)
      Masakazu Higuchi, Daisuke Tanaka, Satoshi Horike, Hirotoshi Sakamoto, Kohei Nakamura, Yohei Takashima, Yuh Hijikata, Nobuhiro Yanai, Jungeun Kim, Kenichi Kato, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa
    • Journal Title

      J. Am. Chem. Soc

      Volume: 131 Pages: 10336-10337

    • Peer Reviewed
  • [Presentation] Molecular arrangement and magnetic properties of O_2 in the nanoporous materials2011

    • Author(s)
      Yoshiki Kubota, Akihiro Hori, Tatsuo C. Kobayashi, Ryotaro Matsuda, Kouichi Kindo, Kenichi Kato, Masaki Takata, Susumu Kitagawa
    • Organizer
      XXII Congress of the International Union of Crystallography
    • Place of Presentation
      Palacio Municipal de Congresos(Madrid, Spain)
    • Year and Date
      20110827-28
  • [Presentation] Incommensurate structure analyses of Bi-Te and Sb-Te binary system2011

    • Author(s)
      Kazuyuki Shakudo, Kouichi Kifune, Yoshiki Kubota, Toshiyuki Matsunaga, Noboru Yamada, Masaki Takata
    • Organizer
      XXII Congress of the International Union of Crystallography
    • Place of Presentation
      Palacio Municipal de Congresos(Madrid, Spain)
    • Year and Date
      20110827-28
  • [Presentation] Ab-initio structure determination of[Cu(dhbc)_2(dpa)] n as high CO_2 adsorption materials2011

    • Author(s)
      Yohei Sato, Yoshiki Kubota, Yasutaka Inubushi, Masaki Takata
    • Organizer
      The 11th Tamura Memorial Symposium
    • Place of Presentation
      Osaka Prefecture University(Sakai)
    • Year and Date
      2011-12-03
  • [Presentation] 非整合な電荷密度波を示すCuV_2S_4の結晶構造解析2011

    • Author(s)
      河口彰吾, 久保田佳基, 石橋広記
    • Organizer
      日本結晶学会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2011-11-24
  • [Presentation] Structural Analysis of Spinel Compound CuV_2S_4 with Incommensurate Charge-Density Wave2011

    • Author(s)
      Shogo Kawaguchi, Yoshiki Kubota, Naruki Tsuji, Jungeun Kim, Kenichi Kato, Masaki Takata, Hiroki Ishibashi
    • Organizer
      International Conference on Strongly Correlated Electron Systems
    • Place of Presentation
      University of Cambridge(Cambridge, UK)
    • Year and Date
      2011-08-31
  • [Presentation] 酸素分子が吸着したゼオライトの構造相転移2011

    • Author(s)
      鰐川泰, 久保田佳基, 堀彰宏, 桑名加菜子, 小林達生, 白曼雅子, 仲井和之, 金廷恩, 加藤健一, 高田昌樹, 松田亮太郎, 北川進
    • Organizer
      日本放射光学会
    • Place of Presentation
      つくば国際会議場(つくば市)
    • Year and Date
      2011-01-10
  • [Presentation] 吸着酸素分子の磁性が誘起するゼオライトの構造相転移2010

    • Author(s)
      久保田佳基, 鰐川泰, 堀彰宏, 桑名加菜子, 小林達生, 白曼雅子, 仲井和之, 金廷恩, 加藤健一, 高田昌樹, 松田亮太郎, 北川進
    • Organizer
      日本結晶学会
    • Place of Presentation
      大阪大学(吹田市)
    • Year and Date
      2010-12-03
  • [Presentation] MFIゼオライトに吸着した酸素分子の配列構造2010

    • Author(s)
      鰐川泰, 久保田佳基, 堀彰宏, 桑名加菜子, 小林達生, 白曼雅子, 仲井和之, 金廷恩, 加藤健一, 高田昌樹, 松田亮太郎, 北川進
    • Organizer
      日本物理学会
    • Place of Presentation
      大阪府立大学(堺市)
    • Year and Date
      2010-09-26
  • [Presentation] 多孔性配位高分子Cu-CHDに吸着したO2の磁性と構造の相関2010

    • Author(s)
      堀彰宏, 小林達生, 久保田佳基, 松尾晶, 金道浩一, 金延恩, 加藤健一, 高田昌樹, 坂本裕俊, 松田亮太郎, 北川進
    • Organizer
      日本物理学会
    • Place of Presentation
      岡山大学(岡山市)
    • Year and Date
      2010-03-22
  • [Presentation] MFIゼオライトに吸着した酸素分子の配列構造2010

    • Author(s)
      鰐川泰, 久保田佳基, 堀彰宏, 桑名加菜子, 小林達生, 白曼雅子, 仲井和之, 金廷恩, 加藤健一, 高田昌樹, 松田亮太郎, 北川進
    • Organizer
      日本物理学会
    • Place of Presentation
      岡山大学(岡山市)
    • Year and Date
      2010-03-22
  • [Presentation] 多孔性金属錯体CuBDTのO_2ガス吸着構造2010

    • Author(s)
      鰐川泰, 久保田佳基, 堀彰宏, 小林達生, 高田昌樹, 北川進
    • Organizer
      日本放射光学会
    • Place of Presentation
      イーグレ姫路(姫路市)
    • Year and Date
      2010-01-08
  • [Presentation] 多孔性金属錯体CID-4に吸着した酸素分子の整列構造2010

    • Author(s)
      宮村真理子, 久保田佳基, 堀彰宏, 小林達生, 高田昌樹, 田中大輔, 北川進
    • Organizer
      日本放射光学会
    • Place of Presentation
      イーグレ姫路(姫路市)
    • Year and Date
      2010-01-08
  • [Presentation] 多孔性金属錯体のナノ細孔に吸着した酸素分子の整列構造と磁性2009

    • Author(s)
      久保田佳基
    • Organizer
      日本結晶学会
    • Place of Presentation
      関西学院大学西宮上ヶ原キャンパス(西宮市)
    • Year and Date
      2009-12-06
  • [Presentation] 多孔性金属錯体Cd(bpndc)(bpy)に吸着した酸素分子の整列構造と磁性II2009

    • Author(s)
      宮村真理子, 南方千晴, 鰐川泰, 久保田佳基, 堀彰宏, 戸田洋平, 鈴木雄太, 小林達生, 松尾晶, 金道浩一, 高田昌樹, 田中大輔, 北川進
    • Organizer
      日本物理学会
    • Place of Presentation
      熊本大学黒髪キャンパス(熊本市)
    • Year and Date
      2009-09-27

URL: 

Published: 2013-07-31  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi