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2011 Fiscal Year Final Research Report

Nanopore analysis of natural rocks and minerals by positron

Research Project

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Project/Area Number 21540317
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics I
Research InstitutionTokyo Gakugei University

Principal Investigator

NAKATA Masataka  東京学芸大学, 教育学部, 教授 (80180305)

Co-Investigator(Renkei-kenkyūsha) SATO Kiminori  東京学芸大学, 教育学部, 准教授 (00401448)
Project Period (FY) 2009 – 2011
Keywords鉱物 / ナノ空孔 / 陽電子 / ポジトロニウム
Research Abstract

Nano-scale pores in natural minerals and rocks were investigated by positron annihilation spectroscopy combined with other porosimetric techniques as N_2 gas absorption porosimetry and small angle x-ray scattering. It was found that positron annihilation spectroscopy sensitively probes micropore less than 2 nm in diameter. The Cs diffusion coefficient through angstrom-scale inter layer spaces of saponite was evaluated to be 2. 5×10^<-8>[ cm^2s^<-1>].

  • Research Products

    (51 results)

All 2011 2010 2009 Other

All Journal Article (31 results) (of which Peer Reviewed: 30 results) Presentation (19 results) Book (1 results)

  • [Journal Article] Steady-State Quartz Formation in terms of Water Migration through Nanopores2011

    • Author(s)
      K. Sato
    • Journal Title

      Proceedings of International Conference on Water, Energy and Environment 2011

      Pages: 541-545

    • Peer Reviewed
  • [Journal Article] Study of Gadolinium-Doped Ceria for High Efficiency Fuel Cell2011

    • Author(s)
      Tomomi Kosaka and Kiminori Sato
    • Journal Title

      Proceedings of International Conference on Water, Energy and Environment 2011

      Pages: 622-624

    • Peer Reviewed
  • [Journal Article] Origin of Organism-Dependent Biogenic Silica Quartz Formation2011

    • Author(s)
      K. Sato
    • Journal Title

      J. of Phys. Chem.

      Volume: B 115 Pages: 14874-14877

  • [Journal Article] Diffusion-Reaction of Water Molecules in Angstrom Pores as Basic Mechanism of Biogenic Quartz Formation2011

    • Author(s)
      K. Sato, K. Fujimoto, M. Nakata, and T. Hatta
    • Journal Title

      J. of Phys. Chem.

      Volume: C 115 Pages: 18131-18135

    • Peer Reviewed
  • [Journal Article] Vacancies and atomic processes in intermetallics-from crystals to quasicrystals and bulk metallic glasses2011

    • Author(s)
      Hans-Eckhardt Schaefer, Falko Baier, Markus A. Muller, Klaus J. Reichle, Klaus Reimann, Andrey Rempel, Kiminori Sato, Feng Ye, Xiangyi Zhang, and Wolfgang Sprengel
    • Journal Title

      physica status solidi

      Volume: B Pages: 1-10

    • Peer Reviewed
  • [Journal Article] Kinetic Study of Hydration-Dehydration in Nano-Scale Interlayer Spaces for Smectite Clay Minerals2011

    • Author(s)
      K. Sato, K. Fujimoto
    • Journal Title

      Proceedings of 10th International congress for Applied Mineralogy

      Pages: 637-643

    • Peer Reviewed
  • [Journal Article] Macroscopic and Microscopic Investigation of Densification Behavior for Gadolinium-doped Ceria upon Sintering2011

    • Author(s)
      Tomomi Kosaka and Kiminori Sato
    • Journal Title

      Mater. Sci. Eng

      Volume: 18 Pages: 0920141-0920143

    • Peer Reviewed
  • [Journal Article] Characterizatin of open nanospaces in nanomaterials2010

    • Author(s)
      Kiminori Sato
    • Journal Title

      Proceedings of 2nd International Conference NANOCON 2010

      Pages: B11-B15

    • Peer Reviewed
  • [Journal Article] Geological Environment with Nanotechnology : Elemental Migration through Open Nanospaces2010

    • Author(s)
      Kiminori Sato, KoichiroFujimoto, Masataka Nakata, Tamao Hatta, and Naotatsu Shikazono
    • Journal Title

      Proceedings of 2nd International Conference NANOCON 2010

      Pages: S31-S35

    • Peer Reviewed
  • [Journal Article] Nanoscale Densification Mechanism of Gadolinium-Doped Ceria upon Sintering2010

    • Author(s)
      Tomomi Kosaka and Kiminori Sato
    • Journal Title

      Proceedings of 2nd International Conference NANOCON 2010

      Pages: B51-B54

    • Peer Reviewed
  • [Journal Article] Free Volumes Associated with Sintering in Gadolinium Doped Ceria Solid Solutions2010

    • Author(s)
      Tomomi Kosaka and Kiminori Sato
    • Journal Title

      J. of Nanomaterials

      Pages: 9351461-9351465

    • Peer Reviewed
  • [Journal Article] Interlayer Spaces Associated with Hydration and Dehydration in Synthetic Saponite2010

    • Author(s)
      K. Sato, K. Fujimoto, M. Nakata, and N. Shikazono
    • Journal Title

      IOP Conference Series : Materials Science and Engineering

      Volume: 15 Pages: 0120061-012005

    • Peer Reviewed
  • [Journal Article] Geological environment with respect to sub-nanoscale pores2010

    • Author(s)
      K. Sato, K. Fujimoto, M. Nakata, and N. Shikazono
    • Journal Title

      Proceedings of the International Conference on Nanotechnology : Fundamentals and Applications

      Pages: 3351-3356

    • Peer Reviewed
  • [Journal Article] Local atomic structures at grain boundaries in Gadolinium doped Cerium Oxides2010

    • Author(s)
      Tomomi Kosaka and Kiminori Sato
    • Journal Title

      High Temperature Materials and Processes

      Volume: 29 Pages: 373-379

    • Peer Reviewed
  • [Journal Article] Improving the interfacial structure of nanocomposite magnets on an atomic scale2010

    • Author(s)
      Defeng Guo, Wei Li, Xiaohong Li, Yan Chen, Kiminori Sato, Xiangyi Zhang
    • Journal Title

      J. of Phys. D : Appl. Phys

      Volume: 43 Pages: 3250031-3250035

    • Peer Reviewed
  • [Journal Article] Study of Cs-loaded SiO2 glass by thermal analysis and positron annihilation spectroscopy2010

    • Author(s)
      K. Sato, H. Murakami, K. Ito, K. Hirata, and Y. Kobayashi
    • Journal Title

      Journal of Physics : Conference Series

      Volume: 225 Pages: 0120461-0120466

    • Peer Reviewed
  • [Journal Article] Study of Gadolinium-doped Cerium Oxide by XRD, TG-DTA, impedance analysis, and positron lifetime spectroscopy2010

    • Author(s)
      S. Ohta, T. Kosaka, and K. Sato
    • Journal Title

      Journal of Physics : Conference Series

      Volume: 225 Pages: 0120431-012045

    • Peer Reviewed
  • [Journal Article] Review of Positron-Age-Momentum Correlation(AMOC) Studies of Open Nanospaces in Materials2010

    • Author(s)
      K. Sato, H. Murakami, and Y. Kobayashi, Topics in Chemistry and Material Science, eds. K. Hadjiivanov, V. Valtchev, S. Mintova, G. Vayssilov
    • Journal Title

      Heron Press Ltd.

      Volume: Vol.4 Pages: 167-174

    • Peer Reviewed
  • [Journal Article] Study of nanocrystallization transitions in amorphous Nd9Fe85B6 on an atomic scale2009

    • Author(s)
      Defeng Guo, Xiaohong Li, Wei Li, Lei Xu, Kiminori Sato, and Xiangyi Zhang
    • Journal Title

      J. of Phys. D : Appl. Phys

      Volume: 42 Pages: 2154071-2154074

    • Peer Reviewed
  • [Journal Article] Nano-and micro-scale free volume in ultrafine grained Cu-1wt.% Pb alloy deformed by equal channel angular pressing2009

    • Author(s)
      Sergiy V. Divinski, Jens Ribbe, Dietmar Baither, Guido Schmitz, Gerrit Reglitz, Harald Rosner, Kiminori Sato, Yuri Estrin, and Gerhard Wilde
    • Journal Title

      Acta Materialia

      Volume: 57 Pages: 5706-5717

    • Peer Reviewed
  • [Journal Article] Atomic-scale structural evolution upon crystallite nucleation and growth in amorphous Fe78B13Si92009

    • Author(s)
      K. Sato, H. Murakami, K. Fujimoto, M. Nakata, W. Sprengel, H.-E. Schaefer, Y. Ueji, Y. Amemiya, and Y. Kobayashi
    • Journal Title

      Jpn. J. of Appl. Phys

      Volume: 48 Pages: 0855051-0855054

    • Peer Reviewed
  • [Journal Article] Atomic-scale structural evolution in amorphous Nd9Fe85B6 subjected to severe plastic deformation at room temperature2009

    • Author(s)
      Wei Li, Xiaohong Li, Defeng Guo, Kiminori Sato, D. V. Gunderov, V. V. Stolyarov, and Xiangyi Zhang
    • Journal Title

      Appl. Phys. Lett

      Volume: 94 Pages: 231941-231943

    • Peer Reviewed
  • [Journal Article] Probing the Elemental Environment around the Free Volume in Polymers with Positron Annihilation Age-Momentum Correlation Spectroscopy2009

    • Author(s)
      K. Sato, H. Murakami, K. Ito, K. Hirata, and Y. Kobayashi
    • Journal Title

      Macromolecules

      Volume: 42 Pages: 4853-4857

    • Peer Reviewed
  • [Journal Article] Nanocrystallization Mechanism of Amorphous Fe78B13Si92009

    • Author(s)
      K. Sato, H. Murakami, W. Sprengel, H.-E. Schaefer, Y. Kobayashi
    • Journal Title

      Appl. Phys. Lett

      Volume: 94 Pages: 1719041-1719043

    • Peer Reviewed
  • [Journal Article] Positron age-momentum-correlation studies of free volumes in polymers2009

    • Author(s)
      K. Sato, H. Murakami, K. Ito, K. Hirata, Y. Kobayashi
    • Journal Title

      Rad. Phys. and Chem

      Volume: 78 Pages: 1085-1087

    • Peer Reviewed
  • [Journal Article] Mechanism of Bi precipitation in Sn65. 4Bi34. 6 Eutectic System2009

    • Author(s)
      K. Sato, H. Murakami, K. Fujimoto, M. Nakata, and Y. Kobayashi
    • Journal Title

      Jpn. J. of Appl. Phys

      Volume: 48 Pages: 0202211-0202213

    • Peer Reviewed
  • [Journal Article] Momentum distributions of ortho-positronium dependent on electronic state at free volume walls in insulators2009

    • Author(s)
      K. Sato, H. Murakami, K. Ito, K. Hirata, and Y. Kobayashi
    • Journal Title

      Materials Science Forum

      Volume: 607 Pages: 53-57

    • Peer Reviewed
  • [Journal Article] Open-nano pores in natural minerals studied by positron lifetime spectroscopy2009

    • Author(s)
      K. Yoshizawa, K. Sato, H. Murakami, N. Shikazono, K. Fujimoto, and M. Nakata
    • Journal Title

      Materials Science Forum

      Volume: 607 Pages: 189-191

    • Peer Reviewed
  • [Journal Article] Interlaboratory Comparison of Positron Annihilation Lifetime Measurements2009

    • Author(s)
      K. Ito, T. Oka, Y. Kobayashi, Y. Shirai, K. Wada, M. Matsumoto, M. Fujinami, T. Hirade, Y. Honda, H. Hosomi, Y. Nagai, K. Inoue, H. Saito, K. Sakaki, K. Sato, A. Shimazu, and A. Uedono
    • Journal Title

      Materials Science Forum

      Volume: 607 Pages: 248-250

    • Peer Reviewed
  • [Journal Article] Quartz formation in natural environment with respect to diffusion-reaction of water molecules in angstrom-scale open spaces

    • Author(s)
      K. Sato
    • Journal Title

      International Journal of Thermal and Environmental Engineering

      Volume: (in press)

    • Peer Reviewed
  • [Journal Article] Study of Gadolinium-Doped Ceria for High Efficiency Fuel Cell

    • Author(s)
      T. Kosaka and K. Sato
    • Journal Title

      International Journal of Thermal and Environmental Engineering

      Volume: (in press)

    • Peer Reviewed
  • [Presentation] Migration of Water molecules in Geological Environment2011

    • Author(s)
      K. Sato
    • Organizer
      International Conference on Water, Energy, and Environment 2011
    • Place of Presentation
      Sharjah, UAE
    • Year and Date
      2011-11-15
  • [Presentation] Kinetic Studies of Hydration-dehydration in Nano-Scale Spaces for Smectite Clay Minerals2011

    • Author(s)
      K. Sato and Fujimoto
    • Organizer
      10th International Congress for Applied Mineralogy
    • Place of Presentation
      Trondheim, Norway
    • Year and Date
      2011-08-02
  • [Presentation] ガドリニウム固溶セリアの焼結過程における緻密化の研究2010

    • Author(s)
      佐藤公法,小坂知己
    • Organizer
      京大原子炉専門研究会
    • Place of Presentation
      京都大学
    • Year and Date
      2010-11-26
  • [Presentation] Characterizatin of open nanospaces in nanomaterials2010

    • Author(s)
      K. Sato
    • Organizer
      2nd International Conference NANOCON 2010
    • Place of Presentation
      Olomouc, Czech
    • Year and Date
      2010-10-12
  • [Presentation] Geological environment with nanotechnology2010

    • Author(s)
      K. Sato, K. Fujimoto, M. Nakata, and N. Shikazono
    • Organizer
      2nd International Conference NANOCON 2010
    • Place of Presentation
      Olomouc, Czech
    • Year and Date
      2010-10-12
  • [Presentation] Elemental Migration through Nano andSubnano-Scale Pores in Geological Environment2010

    • Author(s)
      K. Sato, K. Fujimoto, M. Nakata, and N. Shikazono
    • Organizer
      36th International Symposium on Environmental Analytical Chemistry
    • Place of Presentation
      Rome, Italy
    • Year and Date
      2010-10-08
  • [Presentation] 陽電子消滅法によるガドリニウム固溶セリアの焼結過程の研究2010

    • Author(s)
      佐藤公法,小坂知己
    • Organizer
      日本物理学会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2010-09-25
  • [Presentation] Geological environment with respect to sub-nanoscale pores2010

    • Author(s)
      K. Sato, K. Fujimoto, M. Nakata, and N. Shikazono
    • Organizer
      International Conference on Nanotechnology : Fundamentals and Applications
    • Place of Presentation
      Ottawa, Canada
    • Year and Date
      2010-08-06
  • [Presentation] Characterization of Nanodefect and Elemental Migration in Insulating Materials2010

    • Author(s)
      K. Sato, K. Fujimoto, M. Nakata, and N. Shikazono
    • Organizer
      Europhysical Conference on Defects in Insulating Materials
    • Place of Presentation
      Pecs, Hungary
    • Year and Date
      2010-07-15
  • [Presentation] 地質環境における石英生成メカニズムの研究2010

    • Author(s)
      佐藤公法,藤本光一郎,中田正隆,八田珠郎
    • Organizer
      第47回アイソトープ・放射線研究発表会
    • Place of Presentation
      日本未来科学館
    • Year and Date
      2010-07-08
  • [Presentation] ポジトロニウムを用いた石英生成プロセスのナノ構造評価2010

    • Author(s)
      佐藤公法,藤本光一郎,中田正隆,八田珠郎,鹿園直建
    • Organizer
      資源地質学会
    • Place of Presentation
      東京大学
    • Year and Date
      2010-06-25
  • [Presentation] ポジトロニウム元素依存性の発見とそれを用いたナノ構造評価2010

    • Author(s)
      佐藤公法
    • Organizer
      日本物理学会
    • Place of Presentation
      岡山大学
    • Year and Date
      2010-03-20
  • [Presentation] Probing Open Nanospaces in Functional Materials with Positronium2009

    • Author(s)
      K. Sato, H. Murakami, and Y. Kobayashi
    • Organizer
      The International Conference Material Science in the Age of Nano
    • Place of Presentation
      Havana, Cuba
    • Year and Date
      2009-11-26
  • [Presentation] Studies of positronium states in alkali-metal occluded glasses2009

    • Author(s)
      K. Sato, H. Murakami, K. Ito, K. Hirata, Y. Kobayashi, and T. Hatta
    • Organizer
      Advanced Science Research Symposium 2009
    • Place of Presentation
      東海,テクノ交流館リコッティ
    • Year and Date
      2009-11-12
  • [Presentation] 陽電子寿命-運動量相関計測によるアルカリ金属吸蔵石英ガラスの研2009

    • Author(s)
      佐藤公法,村上英興,伊藤賢志,平田浩一,小林慶規
    • Organizer
      日本物理学会2009年秋季大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-28
  • [Presentation] Characterization of Open Nanospaces in Porous Materials by Positronium2009

    • Author(s)
      K. Sato, H. Murakami, and Y. Kobayashi
    • Organizer
      3rd International Symposium Advanced Micro-and mesoporousmaterials' 2009
    • Place of Presentation
      ブルガリア,アルベナ
    • Year and Date
      2009-09-09
  • [Presentation] 地質環境における石英生成プロセスのナノ空孔サイトからの研究2009

    • Author(s)
      佐藤公法,村上英興,藤本光一郎,中田正隆
    • Organizer
      第46回アイソトープ・放射線研究発表会
    • Place of Presentation
      日本科学未来館
    • Year and Date
      2009-07-02
  • [Presentation] 北海道幌延堆積岩試料中のナノ空隙占有物質の分析2009

    • Author(s)
      佐藤公法,中田正隆,鹿園直建,小室光世
    • Organizer
      資源地質学会第59回年会学術講演会
    • Place of Presentation
      東京大学
    • Year and Date
      2009-06-26
  • [Presentation] 陽電子消滅法によるナノ結晶材料中の核生成および成長過程の研究2009

    • Author(s)
      佐藤公法,村上英興,小林慶規
    • Organizer
      日本物理学会第64回年次大会
    • Place of Presentation
      立教大学
    • Year and Date
      2009-03-27
  • [Book] Quasicrystals : Types, Systems, and Techniques, Chapter 3. Vacancies in Quasicrystals2011

    • Author(s)
      B. E. Puckermann
    • Total Pages
      77-105
    • Publisher
      Nova Science Publishers, Inc.

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Published: 2013-07-31  

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