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2011 Fiscal Year Final Research Report

Spin transition of ferric iron in the lower mantle

Research Project

  • PDF
Project/Area Number 21540491
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionEhime University (2010-2011)
Hokkaido University (2009)

Principal Investigator

FUJINO Kiyoshi  愛媛大学, 地球深部ダイナミクス研究センター, グローバルCOE教授 (40116968)

Co-Investigator(Kenkyū-buntansha) NAGAI Takaya  北海道大学, 大学院・理学研究院, 准教授 (20243131)
Project Period (FY) 2009 – 2011
Keywordsスピン転移 / 3価鉄 / ペロブスカイト / ポストペロブスカイト / 下部マントル / X線発光分光法 / X線回折
Research Abstract

Spin transitions of ferric iron in Mg-perovskite(Pv) and post-Mg-perovskite(PPv) were examined up to 200 GPa and 165 GPa, respectively, by X-ray emission spectroscopy and X-ray diffraction. The results showed that high spin ferric iron in Pv moves from the A-site to the B-site above 50-60 GPa and becomes low spin, while ferric iron in PPv occupies the B-site and is low spin in its whole stability region.

  • Research Products

    (10 results)

All 2012 2011 2010 2009

All Journal Article (3 results) Presentation (6 results) Book (1 results)

  • [Journal Article] Spin transition of ferric iron in Al-bearing Mg-perovskite up to 200 GPa and its implication for the lower mantle2012

    • Author(s)
      Fujino, K., Nishio-Hamane, D., Seto, Y., Sata, N., Nagai, T., Shinmei, T., Irifune, T., Ishii, H., Hiraoka, N., Cai, Y. Q., and Tsuei K.-D.
    • Journal Title

      Earth Planet. Sci. Lett.

      Pages: 317-318, 407-412

    • DOI

      doi:10.1016/j.epsl.2011.12.006.

  • [Journal Article] MgSiO_3-FeAlO_3系ペロブスカイトの固溶メカニズムと結晶化学2011

    • Author(s)
      永井隆哉, 濱根大輔, 藤野清志
    • Journal Title

      日本結晶学会誌

      Volume: 53 Pages: 8-12

  • [Journal Article] Pressure-induced spin transition in FeCO_3-siderite studied by X-ray diffraction measurements2010

    • Author(s)
      Nagai, T., Ishido T., Seto, Y., Hamane, D., Sata, N., and Fujino, K.
    • Journal Title

      Journal of Physics : Conference Series

      Volume: 215 Pages: 012002

    • DOI

      doi:10.1088/1742-6596/215/1/012002.

  • [Presentation] Spin transitions of iron in the lower mantle minerals-new approaches to settle the spin transition problems of iron-2012

    • Author(s)
      Fujino, K., Hamane, D., Nagai, T., Seto, Y., Kuwayama, Y., Ohfuji, H., Shinmei, T., Irifune, T.
    • Organizer
      日本地球惑星科学連合2012大会
    • Place of Presentation
      幕張,千葉
    • Year and Date
      2012-05-21
  • [Presentation] Spin states of ferric iron in Al-bearing Mg-perovskite and post-Mg-perovskite in the lower mantle2011

    • Author(s)
      Fujino, K., Hamane, D., Seto, Y., Nagai, T., Shinmei, T., Whitaker, M. L., Kuwayama, Y., Ohfuji, H., Irifune, T., Hiraoka, N., Ishii, H.
    • Organizer
      AGU Fall Meeting 2011
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2011-12-07
  • [Presentation] 下部マントル構成相における鉄のスピン転移2011

    • Author(s)
      藤野清志, 浜根大輔, 瀬戸雄介, 永井隆哉, 新名亨, 桑山靖弘, 大藤弘明, 入舩徹男
    • Organizer
      第52回高圧討論会
    • Place of Presentation
      沖縄キリスト教学院,那覇
    • Year and Date
      2011-11-11
  • [Presentation] 下部マントルにおける鉄のスピン転移と構成相間の鉄の分配および相転移圧への影響2011

    • Author(s)
      藤野清志, 浜根大輔, 永井隆哉, 瀬戸雄介, 桑山靖弘, 大藤弘明, 新名亨, 入舩徹男
    • Organizer
      日本地質学会第118年学術大会・日本鉱物科学会2011年年会合同学術大会
    • Place of Presentation
      水戸
    • Year and Date
      2011-09-11
  • [Presentation] Spin transition of ferric iron in Mg-perovskite up to 200 GPa and its implication to the lower mantle IMA20102010

    • Author(s)
      Fujino, K., Hamane, D., Seto, Y., Sata, N., Nagai, T., Shinmei, T., Irifune, T., Ishii, H., Hiraoka, N., Cai, Y. Q., and Tsuei, K. D.
    • Place of Presentation
      Budapest, Hungary
    • Year and Date
      2010-08-26
  • [Presentation] Spin state of ferric iron in Mg-perovskite up to 200 GPa by X-ray emission spectroscopy and its implication to the lower mantle2009

    • Author(s)
      Fujino, K., Nishio-Hamane, D., Seto, Y., Sata, N., Nagai, T., Ishido, T., Li, L., Shinmei, T., Irifune, T., Ishii, H., Hiraoka, N., Cai, Y., Tsuei, K.
    • Organizer
      American Geophysical Union Fall Meeting 2009
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2009-12-15
  • [Book] 地球惑星科学入門2010

    • Author(s)
      藤野清志, 蓬田清
    • Total Pages
      15-24
    • Publisher
      北海道大学出版会

URL: 

Published: 2013-07-31  

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