2011 Fiscal Year Final Research Report
Dynamical molecular structure of the NO3 radical : a fundamental NOx molecule
| Project/Area Number |
21550009
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Physical chemistry
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| Research Institution | The Graduate University for Advanced Studies |
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Principal Investigator |
HIROTA Eizi 総合研究大学院大学, 学融合推進センター, 特任研究員 (30011464)
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| Co-Investigator(Kenkyū-buntansha) |
KAWAGUCHI Kentarou 岡山大学, 自然科学研究科, 教授 (40158861)
ISHIWATA Takashi 広島市立大学, 情報科学部, 教授 (40134811)
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| Project Period (FY) |
2009 – 2011
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| Keywords | NOx分子 / 硝酸ラジカル / 振電相互作用 / 赤外スペクトル / 動的分子構造 |
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| Research Abstract |
We have experimentally examined a theoretical proposal made by Stanton on the vibrational assignment and have established the traditional assignment to be correct. We have discovered the angular momenta along the symmetry axis, of the unpaired electron orbital and the degenerate vibrational motions to be coupled strongly, which is a most important vibronic coupling mechanism. We have succeeded in assigning some part of the B-X, 0-0 band, based upon ground-state combination differences of the transition frequencies and Zeeman effects.
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