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2011 Fiscal Year Final Research Report

Systematic Studies on the Synthesis of New Tripodal Ligands and Their Metal Complexes for the Activation of Small Molecules

Research Project

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Project/Area Number 21550034
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionGunma University

Principal Investigator

TAKEDA Nobuhiro  群馬大学, 大学院・工学研究科, 准教授 (80304731)

Project Period (FY) 2009 – 2011
Keywords三脚型四座配位子 / 金属錯体 / カルコゲノエーテル配位子 / シリル配位子
Research Abstract

Group 10 metal(II) complexes bearing a new tripodal tetradentate ligand, E[C_6H_4(2-YR)]_3 (1,_EYR> : E = P, Si^-; Y = O, S, Se, CH_2S (mS) ; R = i-Pr (Pr), t-Bu (Bu)), were synthesized, and their properties were systematically elucidated. In addition, we succeeded in the synthesis of dimethylpalladium complex, [PdMe_2(1_<PSPr>)], and cationic iridium complex having vacant coordination site, [IrH(1_<SimSBu>)]ClO_4. These complexes are expected to be highly reactive to small molecules such as N_2 and CO_2.

  • Research Products

    (37 results)

All 2012 2011 2010 2009 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (27 results) Remarks (1 results)

  • [Journal Article] Catalytic Activities for Olefin Polymerization : Titanium(III), Titanium(IV), Zirconium(IV), and Hafnium(IV) β-Diketiminato, 1-Aza-1,3-butadienyl? Imido, and 1-Aza-2-butenyl? Imido Complexes Bearing an Extremely Bulky Substituent, the Tbt Group (Tbt = 2,42012

    • Author(s)
      H. Hamaki, N. Takeda, M. Nabika, and N. Tokitoh
    • Journal Title

      Tokitoh, Macromolecules

      Volume: 45 Pages: 1758-1769

    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Octakis-(3-propylethanethioate)octasilsesquioxane2011

    • Author(s)
      V. Ervithayasuporn, T. Tomeechai, N. Takeda, M. Unno, A. Chaiyanurakkul, R. Hamkool, and T. Osotchan
    • Journal Title

      Organometallics

      Volume: 30 Pages: 4475-4478

    • Peer Reviewed
  • [Journal Article] Synthesis and Reactivities of Dihydrosilanes Tethered with Two Thioether Moieties2011

    • Author(s)
      N. Takeda, T. Nakamura, A. Imamura, M. Unno
    • Journal Title

      Heteroatom Chem

      Volume: 22 Pages: 438-445

    • Peer Reviewed
  • [Journal Article] Synthesis and Complexation of a New Tripodal Tetradentate Ligand, a Silyl Ligand Tethered with Three Thioether Moieties2010

    • Author(s)
      N. Takeda, D. Watanabe, T. Nakamura, M. Unno
    • Journal Title

      Organometallics

      Volume: 29 Pages: 2839-2841

    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of Group 9 Metal Complexes Bearing a β-Ketophosphenato Ligand2010

    • Author(s)
      T. Matsumoto, T. Sasamori, N. Takeda, N. Tokitoh
    • Journal Title

      J. Organomet. Chem

      Volume: 695 Pages: 1019-1025

    • Peer Reviewed
  • [Journal Article] Synthesis and Structure of Group 10 Metal Complexes with New Tripodal Tetradentate Ligand Bearing One Phosphine and Three Thioether Moieties2010

    • Author(s)
      N. Takeda, Y. Tanaka, F. Sakakibara, M. Unno
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 83 Pages: 157-164

    • Peer Reviewed
  • [Journal Article] An Efficient Approach to Monophenyl-Functionalized Octasilsesquioxanes2009

    • Author(s)
      H. Liu, S. Kondo, N. Takeda, M. Unno
    • Journal Title

      Eur. J. Inorg. Chem

      Pages: 1317-1319

    • Peer Reviewed
  • [Journal Article] Intramolecular Si-C and C-H Bond Activation in a Platinum Complex Leading to the Formation of the Platinacycles2009

    • Author(s)
      N. Tokitoh, M. Kawai, N. Takeda, T. Sasamori
    • Journal Title

      Heterocycles

      Volume: 79 Pages: 311-318

    • Peer Reviewed
  • [Journal Article] Syntheses and structures of overcrowded silanedichalcogenols and their applications to the syntheses of silanedichalcogenolato complexes2009

    • Author(s)
      T. Tanabe, Y. Mizuhata, N. Takeda, N. Tokitoh
    • Journal Title

      J. Organomet. Chem

      Volume: 694 Pages: 353-365

    • Peer Reviewed
  • [Presentation] PS_3型三脚型四座配位子を有するジメチルPd錯体の合成と反応2012

    • Author(s)
      小暮祐輝, 武田亘弘, 海野雅史
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2012-03-28
  • [Presentation] 3つのカルコゲノエーテル部位を有する三脚型四座ホスフィン配位子を用いた10族金属の合成とその性質2011

    • Author(s)
      武田亘弘, 町井美香, 田中雄介, 榊原史顕, 海野雅史
    • Organizer
      第38回有機典型元素化学討論会
    • Place of Presentation
      金沢
    • Year and Date
      2011-12-07
  • [Presentation] 新規な三脚型四座シリル配位子を有するパラジウム錯体の反応性と触媒活性2011

    • Author(s)
      上田岳志, 渡邉大亮, 武田亘弘, 海野雅史
    • Organizer
      第15回ケイ素化学協会シンポジウム
    • Place of Presentation
      神戸
    • Year and Date
      2011-10-21
  • [Presentation] SiS_3型三脚型四座配位子を有する10族金属錯体の合成と反応2011

    • Author(s)
      武田亘弘, 上田岳志, 富宇加剛広, 渡邉大亮, 海野雅史
    • Organizer
      錯体化学会第61回討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-18
  • [Presentation] Pd触媒を用いたテトラアリールシランの選択的脱アリールヒドロキシ化反応2011

    • Author(s)
      武田亘弘, 上田岳志, 海野雅史
    • Organizer
      第58回有機金属化学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2011-09-09
  • [Presentation] Synthesis of Group 9 and 10 Metal Complexes with New Silyl Ligands Tethered with Three Thioether Moieties2011

    • Author(s)
      N. Takeda, D. Watanabe, T. Tomiuka, M. Unno
    • Organizer
      The 16th International Symposium on Silicon Chemistry (ISOS XVI)
    • Place of Presentation
      Hamilton, Ontario, Canada
    • Year and Date
      2011-08-17
  • [Presentation] Selective Dearylhydroxylation of 2-(Alkylthiomethyl)pnenylsilane Derivatives Catalyzed by a Palladium Complex2011

    • Author(s)
      T. Ueda, N. Takeda, M. Unno
    • Organizer
      The 16th International Symposium on Silicon Chemistry (ISOSXVI)
    • Place of Presentation
      Hamilton, Ontario, Canada
    • Year and Date
      2011-08-16
  • [Presentation] 新規三脚型四座配位子であるトリス(2-アルキルチオメチルフェニル)ホスフィン配位子を用いた10族金属錯体の合成とその性質2011

    • Author(s)
      佐原真治, 武田亘弘, 海野雅史
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2011-03-26
  • [Presentation] Synthesis and Property of Group 6 Metal Complexes with Tris(2-alkylthiophenyl)phosphine Ligands2010

    • Author(s)
      Y. Yamamoto, N. Takeda, M. Unno
    • Organizer
      The International Chemical Congress of Pacific Basin Societies (PACIFICHEM-2010)
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2010-12-16
  • [Presentation] Synthesis of Group 10 Metal Complexes Bearing a New Phosphine Ligand Tethered with Three Thioether Moieties, Tris (2-isopropylthiomethylphenyl) phosphine2010

    • Author(s)
      S. Sahara, N. Takeda, M. Unno
    • Organizer
      The International Chemical Congress of Pacific Basin Societies (PACIFICHEM2010)
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2010-12-16
  • [Presentation] Synthetic Studies on Sulfur-coordinated Silylenes2010

    • Author(s)
      H. Mitsui, N. Takeda, M. Unno
    • Organizer
      The 6th International Symposium on Silicon Science (ISSS2010)
    • Place of Presentation
      Kiryu, Japan
    • Year and Date
      2010-12-09
  • [Presentation] Cleavage of Silicon-Carbon Bond in 2-(Alkylthiomethyl)phenylsilane Derivatives by Palladium Complex2010

    • Author(s)
      Takeshi Ueda, D. Watanabe, N. Takeda, M. Unno
    • Organizer
      The 6th International Symposium on Silicon Science (ISSS2010)
    • Place of Presentation
      Kiryu, Japan
    • Year and Date
      2010-12-09
  • [Presentation] Synthesis of Group 10 Metal Complexes with New Tripodal Tetradenate Silyl Ligand Tethered with Three Thioether Moieties2010

    • Author(s)
      T. Tomiuka, N. Takeda, M. Unno
    • Organizer
      The 6th International Symposium on Silicon Science (ISSS2010)
    • Place of Presentation
      Kiryu, Japan
    • Year and Date
      2010-12-09
  • [Presentation] 3つのカルコゲノエーテル部位と1つのホスフィン部位を有する三脚型四座配位子を用いた10族金属錯体の合成とその構造2010

    • Author(s)
      武田亘弘, 佐原真治, 田川朋徳, 海野雅史
    • Organizer
      第37回有機典型元素化学討論会
    • Place of Presentation
      室蘭
    • Year and Date
      2010-11-26
  • [Presentation] Pd錯体を用いた2-(アルキルチオメチル)フェニル基を有するケイ素化合物のケイ素-炭素結合切断反応2010

    • Author(s)
      武田亘弘, 上田岳志, 渡邉大亮, 海野雅史
    • Organizer
      第14回ケイ素化学協会シンポジウム
    • Place of Presentation
      熱海市
    • Year and Date
      2010-11-19
  • [Presentation] Synthetic Studies on Dialkylsilylene Stabilized by Coordination of Thioether Moieties2010

    • Author(s)
      H. Mitsui, N. Takeda, M. Unno
    • Organizer
      The 3rd Asian Silicon Symposium (ASiS-III)
    • Place of Presentation
      Hangzhou, China
    • Year and Date
      2010-10-18
  • [Presentation] 3つのチオエーテル部位と1つのホスフィン部位を有する三脚型四座配位子を用いた10族金属錯体の合成とその性質2010

    • Author(s)
      武田亘弘, 田中雄介, 田川朋徳, 榊原史顕, 佐原真治, 町井美香, 海野雅史
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-28
  • [Presentation] 3つのチオエーテル部位を有する新規三脚型四座シリル配位子を用いた遷移金属錯体の合成とその性質2010

    • Author(s)
      武田亘弘, 渡邉大亮, 上田岳志, 富宇加剛広, 海野雅史
    • Organizer
      第57回有機金属化学討論会
    • Place of Presentation
      八王子
    • Year and Date
      2010-09-16
  • [Presentation] 3つのエーテル部位を有する三脚型四座ホスフィン配位子を用いた9族および10族金属錯体の合成とその性質2010

    • Author(s)
      田川朋徳, 武田亘弘, 海野雅史
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      東大阪
    • Year and Date
      2010-03-28
  • [Presentation] Synthesis of Transition Metal Complexes with Tripodal Tetradentate Phosphine Ligand Tethered with Three Ether Moieties2009

    • Author(s)
      T. Tagawa, N. Takeda, M. Unno
    • Organizer
      9th International Conference on Heteroatom Chemistry (ICHAC-9)
    • Place of Presentation
      Oviedo, Spain
    • Year and Date
      20090701-02
  • [Presentation] Synthesis of Transition Metal Complexes with New Silyl Ligand Tethered with Three Sulfide Moieties2009

    • Author(s)
      D. Watanabe, N. Takeda, M. Unno
    • Organizer
      9th International Conference on Heteroatom Chemistry (ICHAC-9)
    • Place of Presentation
      Oviedo, Spain
    • Year and Date
      20090701-02
  • [Presentation] 複数のチオエーテル部位を有する新規シリル配位子およびその遷移金属錯体の合成2009

    • Author(s)
      武田亘弘, 渡邉大亮, 今村文香, 海野雅史
    • Organizer
      第36回有機典型元素化学討論会
    • Place of Presentation
      鳥取
    • Year and Date
      2009-12-11
  • [Presentation] Synthesis and Reactivities of Dialkylsilylene Stabilized by Coordination of Sulfur Atom2009

    • Author(s)
      H. Mitsui, N. Takeda, M. Unno
    • Organizer
      The 5th International Symposium on Silicon Science (ISSS2009)
    • Place of Presentation
      Kiryu, Japan
    • Year and Date
      2009-12-10
  • [Presentation] 3つのチオエーテル部位を有する新規なシリル配位子を用いた遷移金属錯体の合成とその構造2009

    • Author(s)
      武田亘弘, 渡邉大亮, 海野雅史
    • Organizer
      第13回ケイ素化学協会シンポジウム
    • Place of Presentation
      唐津
    • Year and Date
      2009-10-30
  • [Presentation] 3つのチオエーテル部位を有する新規三脚型四座配位子を用いた遷移金属錯体の合成とその構造2009

    • Author(s)
      武田亘弘, 田中雄介, 中村哲, 今村文香, 田川朋徳, 渡邉大亮, 山本陽子, 海野雅史
    • Organizer
      第20回基礎有機化学討論会
    • Place of Presentation
      桐生
    • Year and Date
      2009-09-28
  • [Presentation] 新規三脚型四座配位子,トリス(アルキルチオメチルフェニル)シリル配位子を用いた遷移金属錯体の合成2009

    • Author(s)
      武田亘弘, 渡邉大亮, 海野雅史
    • Organizer
      第56回有機金属化学討論会
    • Place of Presentation
      京都
    • Year and Date
      2009-09-11
  • [Presentation] Synthesis and Coordination Chemistry of New Phosphine Ligands Tethered with Three Sulfide Moieties2009

    • Author(s)
      N. Takeda, Y. Tanaka, M. Unno
    • Organizer
      9th International Conference on Heteroatom Chemistry (ICHAC-9)
    • Place of Presentation
      Oviedo, Spain
    • Year and Date
      2009-07-02
  • [Remarks]

    • URL

      http://www.chem-bio.gunma-u.ac.jp/%7Entakeda/index.html

URL: 

Published: 2013-07-31  

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