• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2011 Fiscal Year Final Research Report

Study on the Reaction Mechanism of the Reaction of Isolable Hydrido-chalcogenolato Platinum Complexes with Alkynes

Research Project

  • PDF
Project/Area Number 21550035
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionSaitama University

Principal Investigator

ISHII Akihiko  埼玉大学, 大学院・理工学研究科, 教授 (90193242)

Co-Investigator(Renkei-kenkyūsha) NAKATA Norio  埼玉大学, 大学院・理工学研究科, 助教 (50375416)
Project Period (FY) 2009 – 2011
Keywords合成化学 / 白金 / カルコゲン元素 / アルキン / ヒドリド
Research Abstract

The hydroselenation of hydrido-selenolato Pt(II) complexes with alkynes was studied. On the basis of the results employing the complexes having a 9-triptycyl group on the selenium and triphenylphosphine or 1,2-(diphenylphosphino)ethane as the phosphorus ligand, it was revealed that the dissociation of a phosphorus ligand is essential in the initial stage. It is also discovered that the complex having triphenyl phosphite ligands reacts with phenylacetylene to yield the corresponding selenaplatinacycle and styrene.

  • Research Products

    (10 results)

All 2012 2011 2010 2009 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (5 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Hydroselenation and Carboselenation of Electron-deficient Alkynes with Isolable (Hydrido)(Selenolato)platinum(II) Complexes and a Selenaplatinacycle Bearing a Triptycene Skeleton2011

    • Author(s)
      A. Ishii, H. Kamon, N. Nakata
    • Journal Title

      Eur. J. Org. Chem.

      Pages: 1653-1659

    • Peer Reviewed
  • [Journal Article] Syntheses of Selenolato-Bridged Dinuclear Hydridoplatinum Complexes [Pt2H2(.-SetBu)2(PPh3)2] and [Pt2H(SetBu)(.-SetBu)2(PPh3)2]: Unusual Thermal Reaction of Hydrido(1,1-dimethylethaneselenolato) Platinum Complex cis-[PtH(SetBu)(PPh3)2]2010

    • Author(s)
      N. Nakata, T. Ikeda, A. Ishii
    • Journal Title

      Inorg. Chem.

      Volume: 49 Pages: 8122-8116

    • Peer Reviewed
  • [Journal Article] Synthesis and Thermal Reaction of Hydrido(selenolato) Platinum(II) Complex Having a 9,10,11,12,14,15-Hexahydro-9,10[3',4']furanoanthracenyl Group2010

    • Author(s)
      N. Nakata, Y. Yamaguchi, A. Ishii
    • Journal Title

      J. Organomet. Chem.

      Volume: 695 Pages: 970-973

    • Peer Reviewed
  • [Presentation] 嵩高い置換基を有するヒドリド-セレノラト白金(II)錯体とアルキン類の反応2012

    • Author(s)
      青木雄太郎, 加門ひとみ, 中田憲男, 石井昭彦
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      神奈川,慶應義塾大学矢上キャンパス
    • Year and Date
      2012-03-25
  • [Presentation] セレン上に2,4,6-トリ-t-ブチルフェニル基を有するヒドリド(セレノラト)白金(II)錯体の合成と反応性2011

    • Author(s)
      加門ひとみ, 中田憲男, 石井昭彦
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川,神奈川大学横浜キャンパス
    • Year and Date
      2011-03-26
  • [Presentation] アレーンセレノラト-ヒドリド白金(II)錯体の単離とアルキン類との反応2010

    • Author(s)
      加門ひとみ, 中田憲男, 石井昭彦
    • Organizer
      第37回有機典型元素化学討論会
    • Place of Presentation
      北海道,室蘭市民会館
    • Year and Date
      2010-11-26
  • [Presentation] トリフェニルホスファイト配位子を有するヒドリド(セレノラト)白金(II)錯体の合成と反応2010

    • Author(s)
      加門ひとみ, 中田憲男, 石井昭彦
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪,近畿大学
    • Year and Date
      2010-03-28
  • [Presentation] ヒドリド(1,1-ジメチルエタンセレノラト)白金(II)錯体の合成とアルキン類との反応2009

    • Author(s)
      池田貴重, 中田憲男, 石井昭彦
    • Organizer
      第36回有機典型元素化学討論会
    • Place of Presentation
      鳥取,とりぎん文化会館
    • Year and Date
      2009-12-11
  • [Book] Springer, 2012

    • Author(s)
      A. Ishii, N. Nakata
    • Publisher
      The Mechanism for Transition-Metal-Catalyzed Hydrochalcogenation of Unsaturated Organic Molecules,の第1章(30ページ)
  • [Remarks]

    • URL

      http://www.chem.saitama-u.ac.jp/ishii-lab/

URL: 

Published: 2013-07-31  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi