2011 Fiscal Year Final Research Report
Study on the syntheses and properties of distillable mesoionic liquids as highly polar reaction media
| Project/Area Number |
21550042
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Nagoya Institute of Technology |
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Principal Investigator |
ARAKL Shukl 名古屋工業大学, 大学院・工学研究科, 教授 (30115670)
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| Project Period (FY) |
2009 – 2011
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| Keywords | 反応有機化学 / メソイオン / イオン液体 / 反応媒体 / 高極性液体 |
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| Research Abstract |
Efficient synthetic methods for distillable mesoionic liquids, 1,3-dialkyltetrazolium-5-olates, have been developed. The preparations and reactions of organoindium reagents in ionic and mesoionic liquids have been studied, and it have been found that the indium reagents allylate aldehydes more effectively than in conventional organic solvents. The characteristics of mesoionic liquids as reaction media, such as high polarity and enhanced donor ability, have been revealed.
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Research Products
(7 results)
