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2011 Fiscal Year Final Research Report

Establishment of Extended Hypervalent Chemistry Containing Acetylene Unit Incorporated in Group 16 Elements Through Synthesis and Property Development

Research Project

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Project/Area Number 21550046
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionWakayama University

Principal Investigator

HAYASHI Satoko  和歌山大学, システム工学部, 准教授 (00294306)

Co-Investigator(Kenkyū-buntansha) NAKANISHI Waro  和歌山大学, システム工学部, 教授 (80110807)
Project Period (FY) 2009 – 2011
Keywords有機典型元素 / 構造有機化学 / 理論有機化学 / NMR解析 / アセチレン結合 / ジアセチレン結合 / アントラキノン / アントラセン
Research Abstract

We have developed the extended hypervalent chemistry, which consists of linearσ-type bonds in linearly aligned four or more atoms. Here, we aimed for the establishment of the novel extended hypervalent chemistry containing acetylene unit incorporated in the group 16 elements. Such novel extended hypervalent compounds were prepared that consist of linear molecular(or bond) axes surrounded by atoms helically distributed around the axes. Their structures and properties were determined. Such compounds were also prepared that consist of zig-zag type bonding schemes, which are important to clarify the nature of the novel extended hypervalent bonds. Cyclic system is also under preparation. Inclusion of smaller molecules in the compounds is planning.

  • Research Products

    (22 results)

All 2012 2011 2010 2009

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (11 results)

  • [Journal Article] Role of p(Z)-π(Ar/Nap) conjugation in structures of 1-(arylchalcogena)-naphthalenes for Z=Te versus SeS and O : experimental and theoretical investigations2012

    • Author(s)
      T. Nakai, M. Nishino, S. Hayashi, M. Hashimoto and W. Nakanishi
    • Journal Title

      Dalton Transactions

      Volume: 41 Pages: 7485-7497

    • Peer Reviewed
  • [Journal Article] Dynamic and Static Behaviors of N-Z-Nσ(3c-4e)(Z=S, Se, and Te) Interactions : Atoms-in-Molecules Dual Functional Analysis with High-Resolution X-ray Diffraction Determination of Electron Densities for 2-(2-Pyridylimino)-2H-1, 2, 4-thiadiazo lo[2, 3-a] pyridine2011

    • Author(s)
      W. Nakanishi, S. Hayashi, M. B. Pitak, M. B. Hursthouse, and S. J. Coles
    • Journal Title

      J. Phys. Chem. A

      Volume: 115 Pages: 11775-11787

    • Peer Reviewed
  • [Journal Article] How do Weak Z-X-X and Stronger X-Z-X Interactions Affect NMR Chemical Shifts of Halogen Adducts with Chalcogenides(R_2Z・X_2)? Theoretical Background on the Structural Prediction of R_2Z・X_2 Through Chemical Shifts in Solutions2011

    • Author(s)
      A. Tanioku, T. Nakai, S. Hayashi, and W. Nakanishi
    • Journal Title

      Heteroatom Chemistry

      Volume: 22 Pages: 446-456

    • Peer Reviewed
  • [Journal Article] Synthesis, Structural, Spectroscopic and Electrochemical Studies of Carborane Substituted Naphthyl Selenides2011

    • Author(s)
      O. Guzyr, C. Vinas, H. Wada, S. Hayashi, W. Nakanishi, F. Teixidor, A. V. Puga, and V. David
    • Journal Title

      Dalton Transactions

      Volume: 40 Pages: 3402-3411

    • Peer Reviewed
  • [Journal Article] P(O, S, Se, and Te)-π(Ar) Conjugations as Factors to Control Fine Structures of 1-(Chalcogena) naphthalenes2010

    • Author(s)
      T. Nakai, S. Hayashi, and W. Nakanishi
    • Journal Title

      Phosphorus, Sulfur, and Silicon and the Related Elements

      Volume: 185 Pages: 1031-1045

    • Peer Reviewed
  • [Journal Article] Evidence for Effective p(Z)-π(Ar) Conjugations(Z=S, Se, and Te, as Well as Z=O) in 9-(Arylchalcogenyl) triptycenes : Experimental and Theoretical Investigations2009

    • Author(s)
      S. Hayashi, T. Nakamoto, M. Minoura, and W. Nakanishi
    • Journal Title

      J. Org. Chem

      Volume: 74 Pages: 4763-4771

    • Peer Reviewed
  • [Journal Article] How Are Non-bonded G-Z(Z=O, S, and Se) Distances at Benzene 1, 2-, Naphthalene 1, 8-, and Anthracene 1, 8, 9-Positions Controlled? An Approach to Causality in Weak Interactions2009

    • Author(s)
      S. Hayashi and W. Nakanishi
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: 82 Pages: 712-722

    • Peer Reviewed
  • [Journal Article] Fine Structures of 8-G-1-(p-YC_6H_4C≡CSe) C_<10> H_6(G=H, Cl, and Br) in Crystals and Solutions : Ethynyl Influence and Y-and G-Dependences2009

    • Author(s)
      S. Hayashi, K. Yamane, and W. Nakanishi
    • Journal Title

      Bioinorganic Chemistry and Applications

    • DOI

      DOI:10.1155/2009/347359

    • Peer Reviewed
  • [Journal Article] Analysis of^1J(Se, Se) Based on MO Theory : Predominant Contribution of Paramagnetic Spin-Orbit Terms and Torsional Angular Dependence in^1J(Se, Se)2009

    • Author(s)
      A. Tanioku, S. Hayashi, and W. Nakanishi
    • Journal Title

      Bioinorganic Chemistry and Applications

    • DOI

      DOI:10.1155/2009/381925

    • Peer Reviewed
  • [Journal Article] Structures and Dynamic Stereochemistry of 9-Arylselanyltriptycenes : X-ray Crystallographic, Spectroscopic and Theoretical Investigations2009

    • Author(s)
      T. Nakamoto, S. Hayashi, and W. Nakanishi
    • Journal Title

      New J. Chem

      Volume: 33 Pages: 1588-1595

    • Peer Reviewed
  • [Journal Article] H/D Isotope Effect onδ(Se) in 8-Methyl-1-(arylselanyl) naphthalenes and Related Selenides : Nonbonded C-H-Se Through-space versus Through-bond Mechanisms2009

    • Author(s)
      S. Hayashi, K. Yamane, and W. Nakanishi
    • Journal Title

      Phosphorus, Sulfur, and Silicon and the Related Elements

      Volume: 184 Pages: 1481-1495

    • Peer Reviewed
  • [Presentation] ナフタレン系におけるカルコゲン-カルコゲン非共有相互作用: Z_2 2c-4e, Z_2C 3c-4eおよびZ_4 4c-6eに対するAIM2元関数解析2012

    • Author(s)
      林聡子・島袋里佐・松岩浩平・中西和郎
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      神奈川大学(神奈川)
    • Year and Date
      20120325-28
  • [Presentation] Experimental and Theoretical Investigations on p(Z)-π(Ar) Conjugation where Z=S, Se, and Te, Together with Z=O2011

    • Author(s)
      S. Hayashi, T. Nakai, T. Nakamoto, and W. Nakanishi
    • Organizer
      14th Asian Chemical Congress 2011(14 ACC)
    • Place of Presentation
      Bangkok(Thailand)
    • Year and Date
      20110905-08
  • [Presentation] Orientational Effect on^<77> Se NMR Chemical Shifts of Aryl Selenides2011

    • Author(s)
      S. Hayashi, T. Nakai, and W. Nakanishi
    • Organizer
      XVIIth International Seminar on Physics and Chemistry of Solids(17th ISPCS)
    • Place of Presentation
      Bystre(Poland)
    • Year and Date
      20110712-15
  • [Presentation] アントラキノン系におけるO-Se-X 3c-4eおよびX-Se-O-Se-X 5c-6e(X=Cl, Br, I)相互作用の動的・静的挙動: AIM2元関数解析法の適用2011

    • Author(s)
      松岩浩平・見座弘祥・林聡子・中西和郎
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(神奈川)
    • Year and Date
      20110326-29
  • [Presentation] 平面および直交型アリールセレノおよびアリールテルロ化合物の構造とNMR化学シフト基準への寄与2011

    • Author(s)
      西野充浩・林聡子・橋本正人・中西和郎
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(神奈川)
    • Year and Date
      20110326-29
  • [Presentation] 1-(カルコゲナ)ナフタレンの構造: 1-(p-YC_6H_4Z) C_<10> H_7の微細構造におけるYおよびZ依存性2010

    • Author(s)
      中井孝仁・林聡子・中西和郎
    • Organizer
      第37回有機典型元素化学討論会
    • Place of Presentation
      室蘭市民会館ホール(北海道)
    • Year and Date
      20101125-27
  • [Presentation] 拡張超原子価結合間にジアセチレン架橋を組み込んだ新規直線状相互作用の構築2010

    • Author(s)
      林亮平・林聡子・中西和郎
    • Organizer
      第37回有機典型元素化学討論会
    • Place of Presentation
      室蘭市民会館ホール(北海道)
    • Year and Date
      20101125-27
  • [Presentation] Evidence for the p(Z)-π(Ar) Conjugation for Z=S, Se, and Te, as Well as Z=O : Experimental and Theoretical Investigations2010

    • Author(s)
      S. Hayashi, T. Nakamoto, T. Nakai, M. Minoura, and W. Nakanishi
    • Organizer
      Halchem V
    • Place of Presentation
      Cagliari(Italy)
    • Year and Date
      20100919-23
  • [Presentation] Determination of planar and perpendicular structures of aryl selenides in solutions based on^<77> Se NMR chemical shifts2010

    • Author(s)
      S. Hayashi, T. Nakamoto, T. Nakai, M. Minoura, and W. Nakanishi
    • Organizer
      The11th International Conference on the Chemistry of Selenium and Tellurium(ICCST-11)
    • Place of Presentation
      Oulu(Finland)
    • Year and Date
      20100801-06
  • [Presentation] 高精度電荷密度測定とAIM2元関数解析に基づいた拡張超原子価結合C_2S_2O 5c-6eの解明2010

    • Author(s)
      林聡子、桂静郁、中西和郎、フススザンヌ、ハーストハウスマイク
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪)
    • Year and Date
      20100326-29
  • [Presentation] 9-(アリールテラニル)アントラセンの^<125> Te NMR化学シフトはアリールテラニル基の平面構造を実証するか2010

    • Author(s)
      西野充浩・紺谷拓哉・土居由里枝・中井孝仁・林聡子・中西和郎
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪)
    • Year and Date
      20100326-29

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Published: 2013-07-31  

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