2011 Fiscal Year Final Research Report
Synthesis and characterization of compounds fluctuating via radical cleavage and recombination of the carbon-carbon bond.
| Project/Area Number |
21550048
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Josai University |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
KATO Tatsuhisa (80175702)
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| Project Period (FY) |
2009 – 2011
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| Research Abstract |
With the intention of exploring new diradical species which show dynamic interconversion between recombination and bond cleavage, possible precursor compounds were designed, prepared and characterized. Among those, a spiro-cyclohexadienone compound was found to undergo unusual photoinduced rearrangements via a diradical intermediate. Dynamic proton migration was found in some imino-enamine compounds and in precursor compound for galvinoxyl radicals.
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