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2011 Fiscal Year Final Research Report

Synthesis of coordination polymers which show functions based on the tube type channels.

Research Project

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Project/Area Number 21550059
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionShizuoka University

Principal Investigator

KONDO Mitsuru  静岡大学, 機器分析センター, 准教授 (80254142)

Project Period (FY) 2009 – 2011
Keywords超分子錯体 / チャンネル構造
Research Abstract

Tube-like channels were constructed by two methods ; one was by connections of metal complexes with intermolecular hydrogen bonds, and the other was by assemblies of 1D polymer complexes. The former compound showed collapse and reconstructions of the channel structures responding to the removal and re-contact of methanol, which was a part of building block of the tube frameworks. Particularly, this function was useful for adsorption of larger guest molecules induced by addition of methanol. The latter compound showed reversible structural changes of the tube-like channels responding to temperature-variation. The phase-transition properties were dependent on kinds of metal ions and guest molecules in the channels.

  • Research Products

    (7 results)

All 2012 2011 2010 2009

All Journal Article (3 results) (of which Peer Reviewed: 1 results) Presentation (3 results) Book (1 results)

  • [Journal Article]2011

    • Author(s)
      K. Yamanishi, M. Miyazawa, T. Yairi, S. Sakai, N. Nishina, Y. Kobori, M. Kondo, F. Uchida
    • Journal Title

      Angew. Chem. Int.

      Volume: 50 Pages: 6583-6586

  • [Journal Article]2010

    • Author(s)
      M. Kondo, H. Takahashi, H. Watanabe, Y. Shimizu, K. Yamanishi, M. Miyazawa, N. Nishina, Y. Ishida, H. Kawaguchi, F. Uchida
    • Journal Title

      Int. J. Mol. Sci.

      Volume: 11 Pages: 2821-2838

  • [Journal Article] Syntheses, characterizations, and redox behaviors of new self-assembled metal complexes with bridging ligand sincorpo rating chalcogen sites2009

    • Author(s)
      M. Miyazawa, Y. Irie, K. Kashimoto, N. Nishina, M. Kondo, S. Yasue, K. Maeda, and F. Uchida
    • Journal Title

      Inorg. Chem. Commun.

      Volume: 12 Pages: 336-339

    • Peer Reviewed
  • [Presentation] 温度変化に応答して配列構造を可逆的に変化させる配位高分子の合成と構造2011

    • Author(s)
      山田祐介・高橋英明・近藤満
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山市
    • Year and Date
      2011-09-17
  • [Presentation] 外部刺激に応答して細孔構造を変化させる多孔性配位高分子の小分子吸着2010

    • Author(s)
      山田裕介・近藤満
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪市
    • Year and Date
      2010-09-28
  • [Presentation] 11族金属イオンを用いた歪んだ金属中心を有するシッフ塩基錯体の合成と構造2009

    • Author(s)
      松本洋明・望月奨太・坂本健太・仁科直子・近藤満
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎市
    • Year and Date
      2009-09-26
  • [Book] Functions Based on Dynamic Structural Changes of Coordination Polymers2012

    • Author(s)
      M. Kondo
    • Total Pages
      3205-3220
    • Publisher
      John Wiley & Sons

URL: 

Published: 2013-07-31  

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