2011 Fiscal Year Final Research Report
Synthesis of coordination polymers which show functions based on the tube type channels.
| Project/Area Number |
21550059
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Inorganic chemistry
|
|---|
| Research Institution | Shizuoka University |
|---|
Principal Investigator |
KONDO Mitsuru 静岡大学, 機器分析センター, 准教授 (80254142)
|
|---|
| Project Period (FY) |
2009 – 2011
|
| Keywords | 超分子錯体 / チャンネル構造 |
|---|
| Research Abstract |
Tube-like channels were constructed by two methods ; one was by connections of metal complexes with intermolecular hydrogen bonds, and the other was by assemblies of 1D polymer complexes. The former compound showed collapse and reconstructions of the channel structures responding to the removal and re-contact of methanol, which was a part of building block of the tube frameworks. Particularly, this function was useful for adsorption of larger guest molecules induced by addition of methanol. The latter compound showed reversible structural changes of the tube-like channels responding to temperature-variation. The phase-transition properties were dependent on kinds of metal ions and guest molecules in the channels.
|
-
[Journal Article]2011
Author(s)
K. Yamanishi, M. Miyazawa, T. Yairi, S. Sakai, N. Nishina, Y. Kobori, M. Kondo, F. Uchida
-
Journal Title
Angew. Chem. Int.
Volume: 50
Pages: 6583-6586
-
[Journal Article]2010
Author(s)
M. Kondo, H. Takahashi, H. Watanabe, Y. Shimizu, K. Yamanishi, M. Miyazawa, N. Nishina, Y. Ishida, H. Kawaguchi, F. Uchida
-
Journal Title
Int. J. Mol. Sci.
Volume: 11
Pages: 2821-2838
-
-
-
-
-
