2011 Fiscal Year Final Research Report
Precise synthesis and functionalization of alternating copolymers consisting of a combination of specific functional groups
| Project/Area Number |
21550111
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Yamagata University |
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Principal Investigator |
MORI Hideharu 山形大学, 大学院・理工学研究科, 教授 (00262600)
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| Project Period (FY) |
2009 – 2011
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| Keywords | 高分子合成 / 交互配列 / リビング重合 / 開環重合 |
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| Research Abstract |
In this study, various main-chain/side-chain type alternating copolymers containing aromatic rings in the main chains were developed by controlled radical ring-opening polymerization for the purpose of precise synthesis of alternating copolymers consisting of a combination of specific functional groups and emergence of novel functions derived from the alternating arrangement. Alternating copolymers composed of conjugated/non-conjugated monomers were also synthesized by reversible addition-fragmentation chain transfer (RAFT) copolymerization of non-conjugated N-vinyl monomers. These results indicated the feasibility to develop functional alternating copolymers with alternating arrangement of specific functional groups, such as donor and acceptor.
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