2011 Fiscal Year Final Research Report
Preparation and Characterization of New Dimensional Polymers by Fixation of Molecular Arrangement in Ionic Molecular Crystals
| Project/Area Number |
21550117
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Nagoya Institute of Technology |
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Principal Investigator |
SUZUKI Masahito 名古屋工業大学, 大学院・工学研究科, 教授 (20179253)
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| Co-Investigator(Renkei-kenkyūsha) |
MATSUOKA Shin-ichi 名古屋工業大学, 工学部, 助教 (10432288)
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| Project Period (FY) |
2009 – 2011
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| Keywords | 高分子合成 |
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| Research Abstract |
Ionic molecular crystals were prepared by the combinations of tri- or tetra-topic anionic molecules with cationic ones, both of which had planar or tetrahedral structures. Then, in the solid state, the ionic interactions of benzylpyridinium carboxylate were thermally transformed to covalent bonds of benzylester. The product polymers were expected to have the regular network structures. A variety of monomers were prepared and examined. Most of them gave amorphous polymers, but some cross-linked crystalline polymers were obtained, for example, from the combination of tetra-topic phorphyrine derivatives.
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