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2011 Fiscal Year Final Research Report

Characterization of self-assembled metal ion array in solution

Research Project

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Project/Area Number 21550126
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionTohoku University

Principal Investigator

AKIYAMA Kimio  東北大学, 多元物質科学研究所, 准教授 (10167851)

Project Period (FY) 2009 – 2011
Keywordsナノ材料 / 自己組織化 / 電子スピン
Research Abstract

The purpose of the present research is to obtain the precise information on the metal ions array in the self-assembled systems, through the observations of transient EPR and magnetic field effects. It was found that G4 tetramer formation and stabilization were influenced by many factors such as the type of M^+ ion and the nucleotide sequence. Although a fully satisfying interpretation of the results obtained under various conditions still remains, the project will allow us to provide the aspects for future spectroscopic studies on the metal-ion array in solution.

  • Research Products

    (5 results)

All 2011 2010 2009

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (3 results)

  • [Journal Article] Giant magnetoresistance due to electron-hole pair mechanism in poly(N-vinylcarbazole)2010

    • Author(s)
      T. Ikoma, T. Ogiwara, Y. Takahashi, K. Akiyama, S. Tero-Kubota, Y. Takahashi, T. Suzuki, Y. Wakikawa
    • Journal Title

      Synthetic Metals

      Volume: 160 Pages: 285-290

    • Peer Reviewed
  • [Journal Article] Highly Efficient Photoproduction of Charge-Separated States in Donor-Acceptor-Linked Bis(acetylide)Platinum Complexes2009

    • Author(s)
      S. Suzuki, R. Sugimura, M. Kozaki, K. Keyaki, K. Nozaki, N. Ikeda, K. Akiyama, K. Okada
    • Journal Title

      J. Am. Chem. Soc

      Volume: 131 Pages: 10374-10375

    • Peer Reviewed
  • [Presentation] 白金架橋型BODIPY-トリフェニルアミン連結体の光電子移動反応2011

    • Author(s)
      岡田惠次・鈴木修一・家木宣宏・杉村亮治・内藤隆博・小嵜正敏・木本健嗣・野崎浩一・松下浩典・池田憲昭・秋山公男
    • Organizer
      光化学討論会
    • Place of Presentation
      宮崎
    • Year and Date
      2011-09-06
  • [Presentation] Li+ 内包フラーレン1電子還元体の電子構造2010

    • Author(s)
      秋山公男・岡田洋史・酒井健・小野吉弘・笠間泰彦・飛田博実
    • Organizer
      電子スピンサイエンス学会年会
    • Place of Presentation
      名古屋
    • Year and Date
      2010-11-12
  • [Presentation] Spectroscopic Characterization of Singly Reduced Li^+ C_〈60〉2010

    • Author(s)
      秋山公男、岡田洋史、酒井健、小野吉弘、笠間泰彦、飛田博美
    • Organizer
      フラーレン・ナノチューブ総合シンポジウム
    • Place of Presentation
      名古屋
    • Year and Date
      2010-03-02

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Published: 2013-07-31  

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