2011 Fiscal Year Final Research Report
Emergence of multifunctional property correlations induced bythe order structure formation of polypeptide helix.
| Project/Area Number |
21550141
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Functional materials chemistry
|
|---|
| Research Institution | Tokyo Polytechnic University |
|---|
Principal Investigator |
|
|---|
| Co-Investigator(Renkei-kenkyūsha) |
UCHIDA Takayuki 東京工芸大学, 工学部, 教授 (80203537)
|
|---|
| Project Period (FY) |
2009 – 2011
|
| Keywords | ポリペプチド / 有機EL素子 / 超分子化学 |
|---|
| Research Abstract |
Helical poly(L-glutamate) with carbazole(Cz) side chains(PCELG) was synthesized as a hole-transport material for a dye-doped polymer electroluminescence(EL) device. For green and blue light, EL devices using PCELG(PCELG device) was found to exhibit luminance efficiencies comparable to those using poly(N-vinyl carbazole)(PVK). The maximal efficiencies of PCELG devices strongly depend on the casting solvents used during the film-forming process, which amount to the 20 times at the maximum. We pointed out that the solvent dependence of PCELG device attributed to the aggregation structure of PCELG chain at around the interface of the emitter layer/ITO electrode from the ellipsometric analysis.
|
