2011 Fiscal Year Final Research Report
Development of Soft Materials Based on New Concept for Molecular Wire
| Project/Area Number |
21550173
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Functional materials/Devices
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| Research Institution | Shimane University |
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Principal Investigator |
YAMAGUCHI Isao 島根大学, 総合理工学部, 准教授 (00272708)
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| Project Period (FY) |
2009 – 2011
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| Keywords | 有機電子材料 / 共役高分子 |
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| Research Abstract |
Reactions of N-(2, 4-dinitrophenyl)-4-arylpyridinium chlorides with R-(-)-or S-(+)-2-methylpiperazines caused ring-opening of the pyridinium ring and yielded ionic polymers that consisted of 5-(2-methylpiperazinium)-3-aryl-penta-2, 4-dienylideneammonium chloride units. UV-vis measurements revealed that the・-conjugation system expanded along the polymer chain due to the orbital interaction between the electrons on the two nitrogen atoms of the 2-methylpiperazinium ring.
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