2011 Fiscal Year Final Research Report
Development of crystallized mesoporous materials including singlesite organometallic complexes and their catalytic activity with high selectivity
| Project/Area Number |
21550192
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Osaka Prefecture University |
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Principal Investigator |
MATSUOKA Masaya 大阪府立大学, 大学院・工学研究科, 教授 (80305648)
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| Project Period (FY) |
2009 – 2011
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| Keywords | 無機工業化学 / 触媒・化学プロセス / ナノ材料 / 表面・界面物性 |
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| Research Abstract |
Various organometallic complexes were immobilized by CVD or ligand exchange methods on inorganic-organic porous materials such as HMM-ph which involves phenylene moieties in the mesoporous silica structure or MOF which is composed of metal clusters and organic linkers. Organometallic complexes can also be immobilized on carbon nanotubes(CNT) by similar method. These unique heterogeneous catalysts can be applied for the epoxidation of alkenes or hydrosilylation of alkynes.
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