2011 Fiscal Year Final Research Report
Physical properties of stereoregular polymers able to produce films having guest molecules distributed with highly regular orientation
Project/Area Number |
21550206
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Polymer/Textile materials
|
Research Institution | Shizuoka University |
Principal Investigator |
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Project Period (FY) |
2009 – 2011
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Keywords | 結晶成長 / シンジオタクチックポリスチレン / 偏光蛍光 / 光物性 / 高分子構造/物性 / ナノ材料 / 構造/機能材料 / 測定法開発 |
Research Abstract |
First we have succeeded in showing what kind of molecule can be co-crystallized with syndiotactic polystyrene(SPS) by making most of gelation conditions of SPS with a solvent, i. e., its molecular size and/or solubility parameter. Our conclusion will be useful for developing SPS films co-crystals with functional guest molecules such as metal coordination complex. Second, we have established the method for determining three-dimensional arrangements of fluorescent guest molecules even if the fraction of the guest is low. This method will be a powerful tool for invention of functional SPS films.
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