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2011 Fiscal Year Final Research Report

Characterization of crystal defects in organic semiconductors for progress in device performance

Research Project

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Project/Area Number 21560005
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionIwate University

Principal Investigator

YOSHIMOTO Noriyuki  岩手大学, 工学部, 教授 (80250637)

Co-Investigator(Kenkyū-buntansha) HOSOKAI Takuya  岩手大学, 工学部, 助教 (90613513)
Project Period (FY) 2009 – 2011
Keywords有機半導体 / 結晶成長 / X線回折 / GIXD
Research Abstract

The characterization of structures and device properties was studied on organic semiconducting thin films for the purpose of controlling the crystal growth and of elucidating the relationship between crystal defects and transport properties in organic thin-film transistors. Two-dimensional grazing incidence X-ray diffraction (2D-GIXD) was successfully obtained for the vapor deposited pentacene thin-films and the solution-grown TIPS-pentane films. As to the thin film growth of pentacene, thickness-dependent structural change was clearly observed in a real-time observation, and the structural change is significantly affected by exposing to air. On the other hand, large single crystals of TIPS-pentane were grown from solution phase under high magnetic filed. The 2D-GIXD patterns of solution-grown TIPS-pentane were prudently analyzed, and hole mobility in a thin film transistor based was measured and discussed.

  • Research Products

    (26 results)

All 2012 2011 2010 2009 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (13 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Towards n-channel organic thin film transistors based on a distyryl-bithiophene derivative2012

    • Author(s)
      Y. Didane, R.P. Ortiz, J. Zhang, K. Aosawa, T. Tanisawa, H. Aboubakr, F. Fages, J. Ackermann, N. Yoshimoto, H Brisset, C. Videlot-Ackermann
    • Journal Title

      Tetrahedron

      Volume: 68 Pages: 4664-4671

    • Peer Reviewed
  • [Journal Article] Towards solution-processed ambipolar organic thin film transistors based on, hexyl-distyryl-bithiophene (DH-DS2T) and a fluorocarbon-substituted dicyanoperylene (PDIF-CN2)2012

    • Author(s)
      S. Nenon, T. Watanabe, H. Brisset, Z. Chen, J. Ackermann, F. Fages, S. Bernardini, M. Bendahan, K. Aguir, N. Yoshimoto, C. Videlot-Ackerman. J. Optoelectron
    • Journal Title

      Adv. Mater.

      Volume: 14 Pages: 131-135

    • Peer Reviewed
  • [Journal Article] Functionalization of 'kite' shaped styryl end-capped benzodithiophene with ketone groups : synthesis, characterization and properties2011

    • Author(s)
      Y. Didane, A. Kumagai, N. Yoshimoto, C. Videlot-Ackermann , H. Brisset
    • Journal Title

      Tetrahedron

      Volume: 67 Pages: 1628-1632

    • Peer Reviewed
  • [Journal Article] Investigation of solution-processed organic thin film transistors based on-hexyl-distyryl-bithiophene (DH-DS2T) : growth and transport properties2010

    • Author(s)
      Y. Didane, A. K. Diallo, T. Fiorido, A. Suzuki, N. Yoshimoto, S. Bernardini, J. Ackermann, F. Fages, H. Brisset, M. Bendahan, K. Aguir, _C. Videlot-Ackermann J. Optoelectron
    • Journal Title

      Adv. Mater

      Volume: vol.12, iss.7 Pages: 1546-1551

    • Peer Reviewed
  • [Journal Article] Growth and morphology properties of bis (2-phenylethynyl) end-substituted oligothiophenes based thin films2010

    • Author(s)
      C. Videlot-Ackermann, A.K. Diallo, H. Brisset, F. Fages, F. Serein-Spirau, J.-P. Lere-Porte, A. Kumagai, N. Yoshimoto
    • Journal Title

      Optoelectronics and Advanced Materials-Rapid Communications

      Volume: 4 Pages: 699-704

    • Peer Reviewed
  • [Journal Article] Shelf-life time test of p-and n-type organic thin film transistors using copper phthalocyanines2010

    • Author(s)
      S. Nenon, D. Kanehira, N. Yoshimoto, F. Fages and C. Videlot-Ackermann
    • Journal Title

      Thin Solid Films, Thin Solid Films

      Volume: 518 Pages: 5593-5598

    • Peer Reviewed
  • [Journal Article] Comparison of p-channel transistors based on α,ω-hexyl-distyryl-bithiophene prepared using various film deposition methods2010

    • Author(s)
      Y. Didane, C. Martini, M. Barret, S. Sanaur, P. Collot, J. Ackermann, F. Fages, A. Suzuki, N. Yoshimoto, H. Brisset, C. Videlot-Ackermann
    • Journal Title

      Thin Solid Films

      Volume: 518 Pages: 5311-5320

    • Peer Reviewed
  • [Journal Article] Large and spatial magnetic field modulation using superconducting bulk magnet and silicon steel2010

    • Author(s)
      H. Fujishiro, D. Furuta, K. Yaegashi, T. Naito, N. Yoshimoto
    • Journal Title

      Physica C

      Volume: 470 Pages: 1856

    • Peer Reviewed
  • [Journal Article] In situ real-time x-ray diffraction during thin film growth of pentacene

    • Author(s)
      T. Watanabe, T. Hosokai, T. Koganezawa, N. Yoshimoto
    • Journal Title

      Mol. Cryst. Liq. Cryst

      Volume: (in press)

    • Peer Reviewed
  • [Journal Article] Two Dimensional Grazing Incidence X-ray Diffraction of TIPS-Pentacene Thin Films

    • Author(s)
      R. Kamiya, T. Hosokai, T. Watanabe, T. Koganezawa, M. Kikuchi, N. Yoshimoto
    • Journal Title

      Mol. Cryst. Liq. Cryst

      Volume: (in press)

    • Peer Reviewed
  • [Presentation] 有機半導体p-n共蒸着膜の2D-GIXDによる成長過程の観察2012

    • Author(s)
      齋藤正基、細貝拓也、小金澤智之、渡辺剛、菊池護、吉本則之
    • Organizer
      2012年春季第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京都)
    • Year and Date
      20120315-18
  • [Presentation] リアルタイム2D-GIXDでみるペンタセン蒸着膜成長の基板効果2012

    • Author(s)
      渡辺剛、細貝拓也、小金澤智之、齋藤正基、菊池護、広沢一郎、吉本則之
    • Organizer
      2012年春季第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京都)
    • Year and Date
      20120315-18
  • [Presentation] TIPS-pentacene薄膜の2D-GIXD2012

    • Author(s)
      神谷亮輔、細貝拓也、渡辺剛、小金澤智之、菊池護、吉本則之
    • Organizer
      2012年春季第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京都)
    • Year and Date
      20120315-18
  • [Presentation] In Situ Structural Study of Organic Semiconductor Thin Films2011

    • Author(s)
      Takuya Hosokai, Takeshi Watanabe, Tomoyuki Koganezawa, Jorg Ackermann, Hugues Brisset, Christine V. Ackermann, Noriyuki Yoshimoto
    • Organizer
      2011 MRS Fall Meeting, Boston (USA)
    • Year and Date
      20111127-1202
  • [Presentation] Noriyuki Yoshimoto Influence of air exposure on the structure of pentacene films2011

    • Author(s)
      Takuya Hosokai, Takeshi Watanabe, Tomoyuki Koganezawa, Kohei Tamura, Ryosuke Kamiya, Masaki Saito, Mamoru Kikuchi
    • Organizer
      KJF International Conference of Organic Materials for Electronics and Photonics 2011
    • Place of Presentation
      Gyeongju (Korea)
    • Year and Date
      20110918-18
  • [Presentation] In situ real-time X-ray diffraction during organic thin film growth2011

    • Author(s)
      Takeshi Watanabe, Takuya Hosokai, Tomoyuki Koganezawa, Noriyuki Yoshimoto
    • Organizer
      KJF International Conference of Organic Materials for Electronics and Photonics 2011
    • Place of Presentation
      Gyeongju (Korea)
    • Year and Date
      20110915-18
  • [Presentation] Noriyuki Yoshimoto Two Dimensional Grazing Incidence X-ray Diffraction of TIPS-Pentacene Vacuum-deposited Thin Films2011

    • Author(s)
      Ryosuke Kamiya, Takuya Hosokai, Takeshi Watanabe, Tomoyuki Koganezawa, Mamoru Kikuchi
    • Organizer
      KJF International Conference of Organic Materials for Electronics and Photonics 2011
    • Place of Presentation
      Gyeongju (Korea)
    • Year and Date
      20110915-18
  • [Presentation] ペンタセン蒸着膜の膜構造におよぼす大気暴露の効果2011

    • Author(s)
      渡辺剛、細貝拓也、小金澤智之、田村浩平、齋藤正基、神谷亮輔、菊池護、吉本則之
    • Organizer
      2011年秋季第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学(山形県)
    • Year and Date
      20110829-0902
  • [Presentation] Frank Schreiber有機半導体成膜中のX線反射率および光学スペクトルのその場同時測定2011

    • Author(s)
      細貝拓也、Alexander Gerlach, Alexander Hinderhofer, Christian Frank, Geobanni Ligorio, Ute Heinemeyer, Alexei Vorobiev,吉本則之
    • Organizer
      2011年秋季第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学(山形県)
    • Year and Date
      20110829-0902
  • [Presentation] リアルタイム2D-GIXDによるオリゴチオフェン蒸着膜の形成過程の観察2010

    • Author(s)
      渡辺剛,小金澤智之,広沢一郎,村岡宏樹,小川智,吉本則之
    • Organizer
      2010年秋季第71回応用物理学会学術講演会
    • Place of Presentation
      長崎大学(長崎県)
    • Year and Date
      20100914-17
  • [Presentation] 磁場による溶液変形を利用した有機半導体単結晶膜の作製法2010

    • Author(s)
      吉本則之,鈴木彰人,荒木俊行,藤代博之
    • Organizer
      第57回応用物理学関係連合講演会
    • Place of Presentation
      東海大学(神奈川県)
    • Year and Date
      20100317-20
  • [Presentation] 温度勾配法によるオリゴチオフェン薄膜の液成長制御2010

    • Author(s)
      安部俊輔,荒木俊行,吉本則之
    • Organizer
      第57回応用物理学関係連合講演会
    • Place of Presentation
      東海大(神奈川県)
    • Year and Date
      20100317-20
  • [Presentation] Solution Growth of Distyryl-oligobithiophene Thin-films by Temperature Gradient Method2009

    • Author(s)
      N. Yoshimoto, S. Abe, T. Araki, H. Muraoka H. Brisset, J. Ackermann, F. Fages and C. Videlot-Ackermann
    • Organizer
      MRS 2009 fall meeting
    • Place of Presentation
      Boston, USA
    • Year and Date
      20091130-1204
  • [Book] 有機デバイスのための塗布技術、竹谷純一監修2012

    • Author(s)
      吉本則之, 他多数
    • Total Pages
      59-67
    • Publisher
      シーエムシー出版
  • [Remarks]

    • URL

      http://crystal.mat.iwate-u.ac.jp

  • [Patent(Industrial Property Rights)] 磁場中有機半導体結晶薄膜作製法及び作製装置2010

    • Inventor(s)
      吉本則之、荒木俊行、藤代博之、小川智
    • Industrial Property Rights Holder
      国立大学法人岩手大学,独立行政法人科学技術振興機構
    • Industrial Property Number
      特許、特願2010-044727
    • Filing Date
      2010-03-01

URL: 

Published: 2013-07-31  

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