2011 Fiscal Year Final Research Report
Diblock Copolymer of Cellulose and Poly(methyl methacrylate) Induced by Mechano Chemical Polymerization and its Composite Material
| Project/Area Number |
21580208
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Wood science
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| Research Institution | University of Shizuoka |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
TAKESHI Ohura 名城大学, 農学部, 准教授 (60315851)
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| Project Period (FY) |
2009 – 2011
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| Keywords | 環境材料 / 複合材料 / ナノ粒子 / メカノケミカル反応 / セルロース |
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| Research Abstract |
The mechanical fracture of microcrystalline cellulose(MCC) in vacuum at 77 K resulted in the production of chain-end-type radicals of MCC(MCC mechano radicals), which were induced by scission of.-1, 4 glycosidic linkages and trapped on the MCC solid surface. A novel block copolymer of MCC and MMA(MCC-block-PMMA) was synthesized on the MCC surface initiated by the MCC mechano radicals. The chemically modified MCC nano particles covered with PMMA chains of MCC-block-PMMA was produced. The composite of chemically modified cellulose nano particles and PMMA improved its physical property. Furthermore, the transparent sheet of the chemically modified cellulose nano particles was obtained.
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Research Products
(14 results)
