2011 Fiscal Year Final Research Report
Development of[ 2. 2] paracyclophane-based catalyst
| Project/Area Number |
21590007
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
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| Research Institution | Kanazawa University |
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Principal Investigator |
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| Project Period (FY) |
2009 – 2011
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| Keywords | 有機化学 / パラシクロファン / 有機分子触媒 / 不斉配位子 / 面不斉 |
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| Research Abstract |
Some[ 2. 2] paracyclophane-based planar-chiral organocatalysts and ligands were synthesized and evaluated. Bisthiourea organocatalyst whose functionalities are directly connected with[ 2. 2] paracyclophane backbone, acid-base organocatalyst, in which phosphine unit is connected with a cyclopanol via a spacer benzene ring, and C_2-symmetric bis(oxazoline) ligand, both of whose functionalities are connected with[ 2. 2] paracyclophane via a spacer, were found to catalyze organic transformations with high enantiocontrol.
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[Journal Article] Chemistry of Allenic/Propargylic Anions Generated by Base Treatment of Sulfonylallenes : Synthesis of 1-Alkynyl-1-sulfonylcycloalkanes and Cycloalkanols2010
Author(s)
Kitagaki, S., Teramoto, S., Ohta, Y., Kobayashi, H., Takabe, M., Mukai, C.
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Journal Title
Tetrahedron
Volume: 66
Pages: 3687-3694
DOI
Peer Reviewed
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[Journal Article] Rhodium(I)-Catalyzed Intramolecular Carbonylative[ 2+2+1] Cycloadditionsand Cycloisomerizations of Bis(sulfonylallene) s2010
Author(s)
Kawamura, T., Inagaki, F., Narita, S., Takahashi, Y., Hirata, S., Kitagaki, S., Mukai, C.
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Journal Title
Chem. Eur. J.
Volume: 16
Pages: 5173-5183
DOI
Peer Reviewed
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