2011 Fiscal Year Final Research Report
Development of new reaction by using bis(oxazoline) ligands.
| Project/Area Number |
21590026
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
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| Research Institution | Toho University |
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Principal Investigator |
KATO Keisuke 東邦大学, 薬学部, 教授 (80276609)
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| Co-Investigator(Renkei-kenkyūsha) |
FUJII Mikio 東邦大学, 薬学部, 講師 (20311996)
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| Research Collaborator |
MOCHIDA Tomoyuki 神戸大学, 大学院・理学研究科, 教授 (30280580)
KUSAKABE Taichi 東邦大学, 薬学部, 助教 (00600032)
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| Project Period (FY) |
2009 – 2011
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| Keywords | 有機化学 / パラジウム / ビスオキサゾリン / カルボニル化 |
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| Research Abstract |
We recently found that bis(oxazoline)(box) ligand enhances theπ-electrophilicity of palladium(II). We have developed some new reactions utilizing characteristic property of the box-Pd(II) complexes. As an application of this reaction, short step synthesis and stereochemical determination of some natural products were also achieved.
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